Article
Organocatalysis and Biocatalysis Hand in Hand: Combining Catalysts in One-Pot Procedures
Author/s | Bisogno, Fabricio R.
López-Vidal, Martín G. Gonzalo Calvo, Gonzalo de ![]() ![]() ![]() ![]() ![]() ![]() ![]() |
Department | Universidad de Sevilla. Departamento de Química orgánica |
Publication Date | 2017 |
Deposit Date | 2024-02-07 |
Published in |
|
Abstract | Multi-step processes catalysed by several catalysts working concurrently have been developed in nature, thus improving reaction efficiency. The quest for novel and improved catalytic systems has led to the development of ... Multi-step processes catalysed by several catalysts working concurrently have been developed in nature, thus improving reaction efficiency. The quest for novel and improved catalytic systems has led to the development of biocatalytic and later to organocatalytic procedures as very valuable tools in asymmetric synthesis while using mild reaction conditions in the absence of metal catalysts. As a timeless challenge, chemists are facing the need for process designs in which different sorts of catalysts can operate successfully in a one-pot concurrent fashion. Likewise, such designs bring about the best of each catalyst and, in certain cases, enable us to improve problematic issues, such as reactivity, selectivity, solubility, inhibition, etc. Specifically, to combine these two types of catalysts in one-pot, achieving high yields and selectivity, is a fascinating aspect of catalysis. This review covers representative advances in this field, in particular those in which biocatalysts and organocatalysts are employed either in sequential reactions or in simultaneous processes. |
Citation | Bisogno, F.R., López-Vidal, M.G. y Gonzalo Calvo, G.d. (2017). Organocatalysis and Biocatalysis Hand in Hand: Combining Catalysts in One-Pot Procedures. Advanced Synthesis & Catalysis, 359 (12), 2026-2049. https://doi.org/10.1002/adsc.201700158. |
Files | Size | Format | View | Description |
---|---|---|---|---|
10.1002_adsc.201700158.pdf | 2.095Mb | ![]() | View/ | Versión aceptada |
This item appears in the following collection(s)
This document is protected by intellectual and industrial property rights. Without prejudice to existing legal exemptions, its reproduction, distribution, public communication or transformation is prohibited without the authorization of the rights holder, unless otherwise indicated.