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dc.creatorGonzalo Calvo, Gonzalo dees
dc.creatorAlcántara, Andrés R.es
dc.date.accessioned2022-10-19T17:24:39Z
dc.date.available2022-10-19T17:24:39Z
dc.date.issued2021
dc.identifier.citationGonzalo Calvo, G.d. y Alcántara, A.R. (2021). Multienzymatic processes involving baeyer–villiger monooxygenases. Catalysts, 11 (5), 605. https://doi.org/10.3390/catal11050605.
dc.identifier.issn2073-4344es
dc.identifier.urihttps://hdl.handle.net/11441/138144
dc.description.abstractBaeyer–Villiger monooxygenases (BVMOs) are flavin-dependent oxidative enzymes capable of catalyzing the insertion of an oxygen atom between a carbonylic Csp2 and the Csp3 at the alpha position, therefore transforming linear and cyclic ketones into esters and lactones. These enzymes are dependent on nicotinamides (NAD(P)H) for the flavin reduction and subsequent reaction with molecular oxygen. BVMOs can be included in cascade reactions, coupled to other redox enzymes, such as alcohol dehydrogenases (ADHs) or ene-reductases (EREDs), so that the direct conversion of alcohols or α,β-unsaturated carbonylic compounds to the corresponding esters can be achieved. In the present review, the different synthetic methodologies that have been performed by employing multienzymatic strategies with BVMOs combining whole cells or isolated enzymes, through sequential or parallel methods, are described, with the aim of highlighting the advantages of performing multienzymatic systems, and show the recent advances for overcoming the drawbacks of using BVMOs in these techniques.es
dc.description.sponsorshipMinisterio de Ciencia e Innovación PID2019-105337RB-C22es
dc.description.sponsorshipBanco Santander-UCM PR87/19-22676es
dc.formatapplication/pdfes
dc.format.extent25 p.es
dc.language.isoenges
dc.publisherMultidisciplinary Digital Publishing Institute (MDPI)es
dc.relation.ispartofCatalysts, 11 (5), 605.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectBaeyer– Villiger alcohol dehydrogenaseses
dc.subjectBiocatalysises
dc.subjectCascade reactionses
dc.subjectEne-reductaseses
dc.subjectMonooxygenaseses
dc.subjectRedox enzymeses
dc.subjectWhole cellses
dc.titleMultienzymatic processes involving baeyer–villiger monooxygenaseses
dc.typeinfo:eu-repo/semantics/articlees
dcterms.identifierhttps://ror.org/03yxnpp24
dc.type.versioninfo:eu-repo/semantics/publishedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Química orgánicaes
dc.relation.projectIDPID2019-105337RB-C22es
dc.relation.projectIDPR87/19-22676es
dc.relation.publisherversionhttps://doi.org/10.3390/catal11050605es
dc.identifier.doi10.3390/catal11050605es
dc.journaltitleCatalystses
dc.publication.volumen11es
dc.publication.issue5es
dc.publication.initialPage605es
dc.contributor.funderMinisterio de Ciencia e Innovación (MICIN). Españaes
dc.contributor.funderBanco Santander-UCMes

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