dc.creator | Carmona, José A. | es |
dc.creator | Rodríguez Franco, Carlos | es |
dc.creator | Fernández Fernández, Rosario Fátima | es |
dc.creator | Hornillos, Valentín | es |
dc.creator | Lassaletta, José M. | es |
dc.date.accessioned | 2022-04-20T10:58:57Z | |
dc.date.available | 2022-04-20T10:58:57Z | |
dc.date.issued | 2021 | |
dc.identifier.citation | Carmona, J.A., Rodríguez Franco, C., Fernández Fernández, R.F., Hornillos, V. y Lassaletta, J.M. (2021). Atroposelective transformation of axially chiral (hetero)biaryls. From desymmetrization to modern resolution strategies. Chemical Society Reviews, 50 (5), 2968-2983. | |
dc.identifier.issn | 0306-0012 | es |
dc.identifier.issn | 1460-4744 | es |
dc.identifier.uri | https://hdl.handle.net/11441/132236 | |
dc.description.abstract | This tutorial review provides a systematic overview of the available methodologies for the
atroposelective transformation of (heterobiaryl)biaryl precursors toward the synthesis of enantiomerically
enriched products and the conceptual aspects associated to each type of transformation. Depending on
the presence or absence of symmetry in the starting material and the participation of racemization or
dynamization events along the process, several strategies have been developed, including
desymmetrization, classical kinetic resolution (KR), dynamic kinetic resolution (DKR) and dynamic kinetic
asymmetric transformation (DYKAT). Seminal contributions and a handful of selected examples are
discussed to illustrate the potential of these synthetic tools. | es |
dc.description.sponsorship | Fondos FEDER de la Unión Europea y Junta de Andalucía. P18-FR-3531, P18-FR-644, US-1262867 y US-1260906 | es |
dc.format | application/pdf | es |
dc.format.extent | 16 p. | es |
dc.language.iso | eng | es |
dc.publisher | Royal Society of Chemistry | es |
dc.relation.ispartof | Chemical Society Reviews, 50 (5), 2968-2983. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Atroposelective transformation of axially chiral (hetero)biaryls. From desymmetrization to modern resolution strategies | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química orgánica | es |
dc.relation.projectID | P18-FR-3531 | es |
dc.relation.projectID | P18-FR-644 | es |
dc.relation.projectID | US-1262867 | es |
dc.relation.projectID | US-1260906 | es |
dc.relation.publisherversion | https://doi.org/10.1039/D0CS00870B | es |
dc.identifier.doi | 10.1039/D0CS00870B | es |
dc.journaltitle | Chemical Society Reviews | es |
dc.publication.volumen | 50 | es |
dc.publication.issue | 5 | es |
dc.publication.initialPage | 2968 | es |
dc.publication.endPage | 2983 | es |
dc.contributor.funder | European Commission (EC). Fondo Europeo de Desarrollo Regional (FEDER) | es |
dc.contributor.funder | Junta de Andalucía | es |