Instituto de Investigaciones Químicas (IIQ) – CIC Cartuja: Envíos recientes
Mostrando ítems 101-120 de 282
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Neutral Bis(imino)-1,4-dihydropyridinate and Cationic Bis(imino)pyridine σ-Alkylzinc(II) Complexes as Hydride Exchange Systems: Classic Organometallic Chemistry Meets Ligand-Centered, Biomimetic Reactivity
(American Chemical Society, 2018)The 1,4-dihydropyridinate complex [(4-BnHBIP)Zn(Bn)], readily available through the highly selective reaction of a ...
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Double asymmetric hydrogenation of conjugated dienes: a self-breeding chirality route for C2 symmetric 1,4-diols
(Royal Society of Chemistry, 2019)The synthesis and double asymmetric hydrogenation of (Z,Z)-1,3- diene-1,4-diyl diacetates is described. In this reaction ...
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Monomeric alkoxide and alkylcarbonate complexes of nickel and palladium stabilized with the iPrPCP pincer ligand: a model for the catalytic carboxylation of alcohols to alkyl carbonates
(Royal Society of Chemistry, 2019)Monomeric alkoxo complexes of the type [(iPrPCP)M-OR] (M = Ni or Pd; R = Me, Et, CH2CH2OH; iPrPCP = 2,6-bis(diisopropylphosphino)phenyl) ...
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Following palladium catalyzed methoxycarbonylation by hyperpolarized NMR spectroscopy: a parahydrogen based investigation
(Royal Society of Chemistry, 2017)Pd(OTf)2(bcope) is shown to react in methanol solution with diphenylacetylene, carbon monoxide and hydrogen to produce the ...
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Aluminium(iii) dialkyl 2,6-bisimino-4R-dihydropyridinates(−1): selective synthesis, structure and controlled dimerization
(Royal Society of Chemistry, 2019)A family of stable and otherwise selectively unachievable 2,6-bisimino-4-R-1,4-dihydropyridinate aluminium (III) dialkyl ...
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σ-Silane Platinum(II) Complexes as Intermediates in C−Si Bond-Coupling Processes
(Wiley, 2019)Platinum complexes [Pt(NHC’)(NHC)][BArF] (NHC’ denotes the cyclometallated N-heterocyclic carbene ligand, NHC) react ...
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Phosphane-decorated Platinum Nanoparticles as Efficient Catalysts for H2 Generation from Ammonia Borane and Methanol
(Wiley, 2019)A series of narrowly dispersed Pt nanoparticles of 1.5-2.2 nm in size stabilized by bulky terphenylphosphane ligands has ...
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Functionalization of 3-Iridacyclopentenes
(Wiley, 2017)Members of a series of iridacyclopentenes of composition [TpMe2Ir(k2-C,C-CH2CR′=CRCH2)(CO)] (TpMe2=hydrotris(3,5-dimethylpyrazolyl)borate; ...
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Selective catalytic synthesis of amino-silanes at part-per million catalyst loadings
(Royal Society of Chemistry, 2018)Platinum(II) complex [Pt(It Bu0 )(It Bu)][BArF 4] (1a) is a highly active and selective catalyst in the dehydrocoupling ...
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Epimerization of glucose over ionic liquid/phosphomolybdate hybrids: structure-activity relationship
(Royal Society of Chemistry, 2018)The influence of the crystal structure and chemical nature of some ionic liquid/phosphomolybdate hybrids on their catalytic ...
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Structural diversity and magnetic properties of copper(ii) quinaldinate compounds with amino alcohols
(Royal Society of Chemistry, 2022)The reactions between [Cu(quin)2(H2O)] (quin− = the anionic form of quinoline-2-carboxylic acid) and a series of aliphatic ...
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Metal-only Lewis Pairs of Rhodium with s, p and d-Block Metals
(Wiley, 2020)Metal-only Lewis pairs (MOLPs) in which the two metal fragments are solely connected by a dative M→M bond represent ...
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Reactivity of [Pt(PtBu3)2] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn–Zn Bond Cleavage, and Cooperative Reactivity
(American Chemical Society, 2021)Metal-only Lewis pairs (MOLPs) based on zinc electrophiles are particularly interesting due to their relevance to Negishi ...
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Enhanced catalytic activity and stability of nanoshaped Ni/CeO2 for CO2 methanation in micro-monoliths
(Elsevier, 2022)Coupling inherently fluctuating renewable feedstocks to highly exothermic catalytic processes, such as CO2 methanation, ...
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Unravelling the Inflammatory Processes in the Early Stages of Diabetic Nephropathy and the Potential Effect of (Ss)-DS-ONJ
(Multidisciplinary Digital Publishing Institute (MDPI), 2022)Inflammatory processes play a central role in the pathogenesis of diabetic nephropathy (DN) in the early stages of the ...
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PP2A is activated by cytochrome c upon formation of a diffuse encounter complex with SET/TAF-Iβ
(Research Network of Computational and Structural Biotechnology, 2022)Intrinsic protein flexibility is of overwhelming relevance for intermolecular recognition and adaptability of highly dynamic ...
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Chirality influence on the cytotoxic properties of anionic chiral bis(N-heterocyclic carbene)silver complexes
(Elsevier, 2022)Complexes Na3[Ag(NHCR)2], 2a-e and 2b’-c’, where NHCR is a N-heterocyclic carbene of the 2,2′-(1H-2λ3,3λ4-imidazole-1,3-diyl)dicarboxylate ...
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Thinking up an original scientific research project
(Turk Biyokimya Dernegi, 2022)Writing a research proposal is not a simple task if we wish-and we do usually wish!-to succeed in putting our project into ...
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Regulation of TIA-1 Condensates: Zn2+ and RGG Motifs Promote Nucleic Acid Driven LLPS and Inhibit Irreversible Aggregation
(Frontiers Media S.A., 2022)Stress granules are non-membrane bound RNA-protein granules essential for survival during acute cellular stress. TIA-1 is ...
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Overlooked pitfalls in CaO carbonation kinetics studies nearby equilibrium: Instrumental effects on calculated kinetic rate constants
(Elsevier, 2022)Due to its technological applications, such as CO2 capture, CaO carbonation kinetics has been extensively studied using a ...