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A Dynamic Kinetic Asymmetric Heck Reaction for the Simultaneous Generation of Central and Axial Chirality

 

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Opened Access A Dynamic Kinetic Asymmetric Heck Reaction for the Simultaneous Generation of Central and Axial Chirality
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Author: Carmona, José A.
Hornillos, Valentín
Ramírez López, Pedro
Ros Lao, Abel
Iglesias Sigüenza, Francisco Javier
Gómez-Bengoa, Enrique
Fernández Fernández, Rosario Fátima
Lassaletta, José M.
Department: Universidad de Sevilla. Departamento de Química orgánica
Date: 2018
Published in: Journal of the American Chemical Society, 140 (35), 11067-11075.
Document type: Article
Abstract: A highly diastereo- and enantioselective, scalable Pd-catalyzed dynamic kinetic asymmetric Heck reaction of heterobiaryl sulfonates with electron-rich olefins is described. The coupling of 2,3-dihydrofuran or N-boc protected 2,3-dihydropyrrole with ...
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Cite: Carmona, J.A., Hornillos, V., Ramírez López, P., Ros Lao, A., Iglesias Sigüenza, F.J., Gómez-Bengoa, E.,...,Lassaletta, J.M. (2018). A Dynamic Kinetic Asymmetric Heck Reaction for the Simultaneous Generation of Central and Axial Chirality. Journal of the American Chemical Society, 140 (35), 11067-11075.
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URI: https://hdl.handle.net/11441/82335

DOI: 10.1021/jacs.8b05819

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