dc.creator | Louis, Farida F. | es |
dc.creator | García Moreno, M. Isabel | es |
dc.creator | Balbuena Oliva, Patricia | es |
dc.creator | Ortiz Mellet, Carmen | es |
dc.creator | García Fernández, José Manuel | es |
dc.date.accessioned | 2018-02-14T15:56:41Z | |
dc.date.available | 2018-02-14T15:56:41Z | |
dc.date.issued | 2007 | |
dc.identifier.citation | Louis, F.F., García Moreno, M.I., Balbuena Oliva, P., Ortiz Mellet, C. y García Fernández, J.M. (2007). Spacer-mediated synthesis of bis-spiroketal disaccharides: Nonsymmetrical furanose-pyranose difructose dianhydrides. Synlett, 17, 2738-2742. | |
dc.identifier.issn | 0936-5214 | es |
dc.identifier.uri | https://hdl.handle.net/11441/70295 | |
dc.description.abstract | The stereochemical outcome of the dimerization reaction of D-fructose, leading to tricyclic bis-spiroketal systems, can be tuned by inserting a xylylene template between the reacting moieties. Spirocyclization becomes then an intramolecular process, the available conformational space depending on the nature of the tether. The methodology is here illustrated by the stereoselective synthesis of two nonsymmetrical di-D-fructose dianhydrides present in commercial caramel | es |
dc.description.sponsorship | Ministerio de Educación y Ciencia CTQ2004-05854/BQU, CTQ2006-15515-C02-01/ BQU | es |
dc.description.sponsorship | Junta de Andalucía P06-AGR-02115 | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.relation.ispartof | Synlett, 17, 2738-2742. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Acetals | es |
dc.subject | Difructose dianhydrides | es |
dc.subject | Oligosaccharides | es |
dc.subject | Spiro compounds | es |
dc.subject | Spiroacetals | es |
dc.title | Spacer-mediated synthesis of bis-spiroketal disaccharides: Nonsymmetrical furanose-pyranose difructose dianhydrides | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química orgánica | es |
dc.relation.publisherversion | http://dx.doi.org/10.1055/s-2007-991055 | es |
dc.identifier.doi | 10.1055/s-2007-991055 | es |
idus.format.extent | 5 | es |
dc.journaltitle | Synlett | es |
dc.publication.issue | 17 | es |
dc.publication.initialPage | 2738 | es |
dc.publication.endPage | 2742 | es |
dc.contributor.funder | Ministerio de Educación y Ciencia (MEC). España | |
dc.contributor.funder | Junta de Andalucía | |