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Artículo
Total asymmetric synthesis of monosaccharides and analogues
dc.creator | Robina Ramírez, Inmaculada | es |
dc.creator | Carmona Asenjo, Ana Teresa | es |
dc.creator | Moreno Vargas, Antonio José | es |
dc.creator | Moreno Clavijo, Elena | es |
dc.date.accessioned | 2020-06-03T10:54:20Z | |
dc.date.available | 2020-06-03T10:54:20Z | |
dc.date.issued | 2011 | |
dc.identifier.citation | Robina Ramírez, I., Carmona Asenjo, A.T., Moreno Vargas, A.J. y Moreno Clavijo, E. (2011). Total asymmetric synthesis of monosaccharides and analogues. Chimia, 65 (1-2), 85-90. | |
dc.identifier.issn | 0009-4293 | es |
dc.identifier.uri | https://hdl.handle.net/11441/97391 | |
dc.description.abstract | Since the discovery of the 'formose reaction' by Butlerow,[1] total synthesis of carbohydrates has undergone rapid development. The most important methods for the asymmetric synthesis of monosaccharides and analogues of biological importance are presented. Nowadays any natural and non-natural monosaccharide can be prepared pure in both enantiomeric forms starting from inexpensive starting materials. Metal-based asymmetric catalysis and organocatalysis have been successfully applied, alone or in combination with chemoenzymatic methods. Alternative methods rely upon substrate- or reagent- controlled diastereo- and enantioselective reactions. Suitably protected carbohydrates have been prepared by total synthesis, thus allowing their direct use in the preparation of oligosaccharides and analogues. | es |
dc.format | application/pdf | es |
dc.format.extent | 6 p. | es |
dc.language.iso | eng | es |
dc.publisher | Schweizerische Chemische Gesellschaft (Swiss Chemistry Society) | es |
dc.relation.ispartof | Chimia, 65 (1-2), 85-90. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Aldolase | es |
dc.subject | Allylation | es |
dc.subject | Chain elongation | es |
dc.subject | Dihydroxylation | es |
dc.subject | Epoxidation | es |
dc.subject | Hetero-Diels-Alder | es |
dc.subject | Organocatalysis | es |
dc.title | Total asymmetric synthesis of monosaccharides and analogues | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química orgánica | es |
dc.relation.publisherversion | https://doi.org/10.2533/chimia.2011.85 | es |
dc.identifier.doi | 10.2533/chimia.2011.85 | es |
dc.journaltitle | Chimia | es |
dc.publication.volumen | 65 | es |
dc.publication.issue | 1-2 | es |
dc.publication.initialPage | 85 | es |
dc.publication.endPage | 90 | es |
Ficheros | Tamaño | Formato | Ver | Descripción |
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Total Asymmetric .pdf | 417.8Kb | [PDF] | Ver/ | |