Article
Selective reduction of carbon dioxide to bis(silyl)acetal catalyzed by a PBP-supported nickel complex
Author/s | Ríos Moreno, Pablo
Curado, Natalia López Serrano, Joaquín Rodríguez, Amor |
Publication Date | 2016 |
Deposit Date | 2018-07-17 |
Published in |
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Abstract | Selective reduction of CO2 to the formaldehyde level remains an important challenge and to date only a few catalysts have been developed for this reaction. Herein, we report an efficient catalyst that consists of a ... Selective reduction of CO2 to the formaldehyde level remains an important challenge and to date only a few catalysts have been developed for this reaction. Herein, we report an efficient catalyst that consists of a bis(phosphino)boryl nickel hydride complex in combination with B(C6F5)3, for the highly selective hydrosilation of CO2 to bis(silyl)acetal derivatives |
Funding agencies | Ministerio de Economía y Competitividad (MINECO). España Junta de Andalucía |
Citation | Ríos, P., Curado, N., López Serrano, J. y Rodríguez, A. (2016). Selective reduction of carbon dioxide to bis(silyl)acetal catalyzed by a PBP-supported nickel complex. Chemical Communications, 10 (52), 2114-2119. |
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