Author profile: López Serrano, Joaquín
Data
| Name | López Serrano, Joaquín |
| Department | Química Inorgánica |
| Knowledge area | Química Inorgánica |
| Professional category | Profesor Titular de Universidad |
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Statistics
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Items
21
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Visits
1912
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1816
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Article
 From cyclic amines and acetonitrile to amidine zinc(II) complexes
(Royal Society of Chemistry, 2020-01-01)
A seemingly simple combination of [Zn(quin)2(H2O)] (quin− = quinaldinate) and a selected secondary cyclic amine, piperidine ... |
| PhD Thesis |
Article
Base-Promoted, Remote C−H Activation at a Cationic (η5 ‑C5Me5)Ir(III) Center Involving Reversible C−C Bond Formation of Bound C5Me5
(American Chemical Society, 2019-01-01)
C-H bond activation at cationic [(η5-C5Me5)Ir(PMe2Ar')] centers is described, where PMe2Ar' are the terphenyl phosphine ... |
Article
Ligand Rearrangement and Hemilability in R hodium(I) and Iridium(I) Complexes Bearing Terphenyl Phosphines
(Wiley, 2018-01-01)
We describe the synthesis of a series of cationic rhodium(I) and iridium(I) compounds stabilized by sterically ... |
Article
 Dynamic Kinetic Resolution of Hetero biaryl Ketones by Zinc- Catalyzed Asymmetr ic Hydrosil ylation
(Wiley, 2018-01-01)
Adiastereo- and highly enantioselective dynamic kinetic resolution (DKR) of configurationally labile hetero- biaryl ketones is ... |
Article
Activation of Small Molecules by the Metal-Amido Bond of Rhodium(III) and Iridium(III) (η5-C5Me5)M-Aminopyridinate Complexes
(American Chemical Society, 2018-01-01)
We report the synthesis and structural characterization of five-coordinate complexes of rhodium and iridium of the type ... |
Article
Reactivity of a trans-[H-Mo≣Mo-H] Unit Towards Alkenes and Alkynes. Bimetallic Migratory Insertion, H-Elimination and Other Reactions
(Royal Society of Chemistry, 2018-01-01)
Complex [Mo2(H)2{μ-HC(NDipp)2}2(THF)2], (1·THF), reacts with C2H4 and PhCH[double bond, length as m-dash]CH2 to afford ... |
Article
Cationic (η5-C5Me4R)RhIII Complexes with Metalated Aryl Phosphines Featuring η4-Phosphorus plus Pseudo-Allylic Coordination
(American Chemical Society, 2018-01-01)
In this contribution we study experimentally and computationally some electrophilic cationic (η5-C5Me4R)RhIII complexes ... |
Article
A Cationic Unsaturated Platinum(II) Complex that Promotes the Tautomerization of Acetylene to Vinylidene
(Wiley-VCH, 2017-01-01)
Complex [PtMe(PMeAr)] (1), which contains a tethered terphenyl phosphine (Ar =2,6-(2,6-PrCH)CH), reacts with [H(EtO)]BAr ... |
Article
Methyl Complexes of the Transition Metals
(John Wiley & Sons, 2016-01-01)
Organometallic chemistry can be considered as a wide area of knowledge that combines concepts of classic organic chemistry, ... |
Article
Synthesis, properties, and some rhodium, iridium, and platinum complexes of a series of bulky m-terphenylphosphine ligands
(Elsevier, 2016-01-01)
A series of sterically demanding aryl phosphine ligands (L) bearing terphenyl substituents, PR2Ar′ (R = hydrocarbyl, Ar′ ... |
Article
Mechanistic Studies on the Selective Reduction of CO2 to the Aldehyde Level by a PBP-Supported Nickel Complex
(American Chemical Society, 2016-01-01)
This work describes a thorough investigation of the mechanism of a highly selective hydrosilylation of CO2 to the formaldehyde ... |
Article
Cationic Platinum(II) σ-SiH Complexes in Carbon Dioxide Hydrosilation
(John Wiley & Sons, 2016-01-01)
The low-electron-count cationic platinum complex [Pt(ItBu’)(ItBu)][BAr], 1, interacts with primary and secondary silanes ... |
Article
Selective reduction of carbon dioxide to bis(silyl)acetal catalyzed by a PBP-supported nickel complex
(American Chemical Society, 2016-01-01)
Selective reduction of CO2 to the formaldehyde level remains an important challenge and to date only a few catalysts have ... |
Article
Lithium Di-‐ and Trimethyl Dimolybdenum(II) Complexes with Mo-‐Mo Quadruple Bonds and Bridging Methyl Groups
(American Chemical Society, 2015-01-01)
New dimolybdenum complexes of composition [Mo2{μ-Me}2Li(S)}(μ- X)(μ-N^N)2] (3a−3c), where S = THF or Et2O and N^N represents ... |
Article
A Diels–Alder Reaction Triggered by a [4 + 3] Metallacycloaddition
(American Chemical Society, 2015-01-01)
The TpMe2Ir(III) complex 1-OH2 (TpMe2 = hydrotris(3,5-dimethylpyrazolyl)borate), which contains a labile molecule of water ... |
Article
Ruthenium(II) Complexes Containing Lutidine-derived Pincer CNC Ligands: Synthesis, Structure and Catalytic Hydrogenation of C=N bonds
(Wiley-Blackwell, 2015-01-01)
A series of Ru complexes containing lutidine‐derived pincer CNC ligands have been prepared by transmetalation with the ... |
Article
Boryl-assisted hydrogenolysis of a nickel–methyl bond
(Royal Society of Chemistry (Great Britain), 2014-01-01)
A stable Nickel(II) methyl complex containing a diphosphinoboryl (PBP) pincer ligand is described. Mechanistic studies on ... |
Article
Formation of C−X Bonds Through Stable Low-Electron Count Cationic Pt(IV) Alkyl Complexes Stabilized by N-Heterocyclic Carbenes
(American Chemical Society, 2014-01-01)
Cationic five-coordinate Pt(IV) alkyl complexes stabilized by bulky N-heterocyclic carbenes have been isolated and fully ... |
Article
Quadruply bonded dimolybdenum complexes with highly unusual geometries and vacant coordination sites
(Royal Society of Chemistry (Great Britain), 2012-01-01)
New quadruply bonded dimolybdenum complexes of the terphenyl ligand Ar Xyl2 (Ar Xyl2 = C 6H 3-2,6-(C 6H 3-2,6-Me 2) 2) ... |
Article
Coupling of Aromatic Aldehydes with CO2Me-Substituted TpMe2Ir(III) Metallacyclopentadienes
(American Chemical Society, 2012-01-01)
The fully CO2Me substituted aquo-iridacyclopentadiene 1 reacts with a variety of aromatic aldehydes, at 90–120 °C, with ... |