Data

NameLópez Serrano, Joaquín
DepartmentQuímica Inorgánica
Knowledge areaQuímica Inorgánica
Professional categoryProfesor Titular de Universidad
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  Statistics

  • Items

    21

  • Visits

    1912

  • Downloads

    1816

  Publications

 

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From cyclic amines and acetonitrile to amidine zinc(II) complexes

Podjed, Nina; Modec, Barbara; Alcaide, María M.; López Serrano, Joaquín (Royal Society of Chemistry, 2020-01-01)
A seemingly simple combination of [Zn(quin)2(H2O)] (quin− = quinaldinate) and a selected secondary cyclic amine, piperidine ...
PhD Thesis
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Synthesis, reactivity and computational studies of ir complexes bearing terphenyl phosphine ligands.

Campos Manzano, Jesús; Carmona Guzmán, Ernesto; López Serrano, Joaquín; Moreno Díaz, Juan José (2019-02-08)
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Base-Promoted, Remote C−H Activation at a Cationic (η5 ‑C5Me5)Ir(III) Center Involving Reversible C−C Bond Formation of Bound C5Me5

Moreno Díaz, Juan José; Fernández Espada-Pastor, María; Campos Manzano, Jesús; López Serrano, Joaquín; Macgregor, Stuart A.; Carmona Guzmán, Ernesto (American Chemical Society, 2019-01-01)
C-H bond activation at cationic [(η5-C5Me5)Ir(PMe2Ar')] centers is described, where PMe2Ar' are the terphenyl phosphine ...
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Ligand Rearrangement and Hemilability in R hodium(I) and Iridium(I) Complexes Bearing Terphenyl Phosphines

Moreno Díaz, Juan José; Fernández Espada, María; Krüger, Eric; López Serrano, Joaquín; Campos, Jesús; Carmona Guzmán, Ernesto (Wiley, 2018-01-01)
We describe the synthesis of a series of cationic rhodium(I) and iridium(I) compounds stabilized by sterically ...
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Dynamic Kinetic Resolution of Hetero biaryl Ketones by Zinc- Catalyzed Asymmetr ic Hydrosil ylation

Hornillos, Valentín; Carmona, José A.; Ros Lao, Abel; Iglesias Sigüenza, Francisco Javier; López Serrano, Joaquín; Fernández Fernández, Rosario Fátima; Lassaletta, José M. (Wiley, 2018-01-01)
Adiastereo- and highly enantioselective dynamic kinetic resolution (DKR) of configurationally labile hetero- biaryl ketones is ...
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Activation of Small Molecules by the Metal-Amido Bond of Rhodium(III) and Iridium(III) (η5-C5Me5)M-Aminopyridinate Complexes

Zamorano Márquez, Ana; Rendón Márquez, Nuria; López Serrano, Joaquín; Álvarez González, Eleuterio; Carmona Guzmán, Ernesto (American Chemical Society, 2018-01-01)
We report the synthesis and structural characterization of five-coordinate complexes of rhodium and iridium of the type ...
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Reactivity of a trans-[H-Mo≣Mo-H] Unit Towards Alkenes and Alkynes. Bimetallic Migratory Insertion, H-Elimination and Other Reactions

Pérez Jiménez, Marina; Campos Manzano, Jesús; López Serrano, Joaquín; Carmona Guzmán, Ernesto (Royal Society of Chemistry, 2018-01-01)
Complex [Mo2(H)2{μ-HC(NDipp)2}2(THF)2], (1·THF), reacts with C2H4 and PhCH[double bond, length as m-dash]CH2 to afford ...
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Cationic (η5-C5Me4R)RhIII Complexes with Metalated Aryl Phosphines Featuring η4-Phosphorus plus Pseudo-Allylic Coordination

Fernández Espada, María; Esqueda Oliva, Ana Cristina; Campos Manzano, Jesús; Rubio Moreno, Miguel; López Serrano, Joaquín; Maya Díaz, Celia María; Carmona Guzmán, Ernesto (American Chemical Society, 2018-01-01)
In this contribution we study experimentally and computationally some electrophilic cationic (η5-C5Me4R)RhIII complexes ...
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A Cationic Unsaturated Platinum(II) Complex that Promotes the Tautomerization of Acetylene to Vinylidene

Ortega Moreno, Laura; Peloso, Riccardo; López Serrano, Joaquín; Iglesias Sigüenza, Francisco Javier; Maya Díaz, Celia María; Carmona Guzmán, Ernesto (Wiley-VCH, 2017-01-01)
Complex [PtMe(PMeAr)] (1), which contains a tethered terphenyl phosphine (Ar =2,6-(2,6-PrCH)CH), reacts with [H(EtO)]BAr ...
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Methyl Complexes of the Transition Metals

Campos, Jesús; López Serrano, Joaquín; Peloso, Riccardo; Carmona Guzmán, Ernesto (John Wiley & Sons, 2016-01-01)
Organometallic chemistry can be considered as a wide area of knowledge that combines concepts of classic organic chemistry, ...
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Synthesis, properties, and some rhodium, iridium, and platinum complexes of a series of bulky m-terphenylphosphine ligands

Ortega Moreno, Laura; Fernández Espada, María; Moreno Díaz, Juan José; Navarro Gilabert, Carlos; Campos Manzano, Jesús; Conejero Iglesias, Salvador; López Serrano, Joaquín; Maya Díaz, Celia María; Peloso, Riccardo; Carmona Guzmán, Ernesto (Elsevier, 2016-01-01)
A series of sterically demanding aryl phosphine ligands (L) bearing terphenyl substituents, PR2Ar′ (R = hydrocarbyl, Ar′ ...
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Mechanistic Studies on the Selective Reduction of CO2 to the Aldehyde Level by a PBP-Supported Nickel Complex

Ríos Moreno, Pablo; Rodríguez, Amor; López Serrano, Joaquín (American Chemical Society, 2016-01-01)
This work describes a thorough investigation of the mechanism of a highly selective hydrosilylation of CO2 to the formaldehyde ...
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Cationic Platinum(II) σ-SiH Complexes in Carbon Dioxide Hydrosilation

Ríos Moreno, Pablo; Díez, Josefina; López Serrano, Joaquín; Rodríguez, Amor; Conejero, Salvador (John Wiley & Sons, 2016-01-01)
The low-electron-count cationic platinum complex [Pt(ItBu’)(ItBu)][BAr], 1, interacts with primary and secondary silanes ...
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Selective reduction of carbon dioxide to bis(silyl)acetal catalyzed by a PBP-supported nickel complex

Ríos Moreno, Pablo; Curado, Natalia; López Serrano, Joaquín; Rodríguez, Amor (American Chemical Society, 2016-01-01)
Selective reduction of CO2 to the formaldehyde level remains an important challenge and to date only a few catalysts have ...
Article
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Lithium Di-­‐ and Trimethyl Dimolybdenum(II) Complexes with Mo-­‐Mo Quadruple Bonds and Bridging Methyl Groups

Curado, Natalia; Carrasco, Mario; Álvarez González, Eleuterio; Maya Díaz, Celia María; Peloso, Riccardo; Rodríguez, Amor; López Serrano, Joaquín; Carmona Guzmán, Ernesto (American Chemical Society, 2015-01-01)
New dimolybdenum complexes of composition [Mo2{μ-Me}2Li(S)}(μ- X)(μ-N^N)2] (3a−3c), where S = THF or Et2O and N^N represents ...
Article
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A Diels–Alder Reaction Triggered by a [4 + 3] Metallacycloaddition

Vivancos, Ángela; Vattier Lagarrigue, María Florencia; López Serrano, Joaquín; Paneque Sosa, Margarita; Poveda, Manuel L.; Álvarez González, Eleuterio (American Chemical Society, 2015-01-01)
The TpMe2Ir(III) complex 1-OH2 (TpMe2 = hydrotris(3,5-dimethylpyrazolyl)borate), which contains a labile molecule of water ...
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Ruthenium(II) Complexes Containing Lutidine-derived Pincer CNC Ligands: Synthesis, Structure and Catalytic Hydrogenation of C=N bonds

Hernández Juárez, M.; López Serrano, Joaquín; Lara Muñoz, Patricia; Morales Cerón, Judith; Vaquero, Mónica; Álvarez González, Eleuterio; Salazar, Verónica; Suárez, Andrés (Wiley-Blackwell, 2015-01-01)
A series of Ru complexes containing lutidine‐derived pincer CNC ligands have been prepared by transmetalation with the ...
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Boryl-assisted hydrogenolysis of a nickel–methyl bond

Curado Dianez, Natalia; Maya Díaz, Celia María; López Serrano, Joaquín; Rodríguez Iglesias, María Amor (Royal Society of Chemistry (Great Britain), 2014-01-01)
A stable Nickel(II) methyl complex containing a diphosphinoboryl (PBP) pincer ligand is described. Mechanistic studies on ...
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Formation of C−X Bonds Through Stable Low-Electron Count Cationic Pt(IV) Alkyl Complexes Stabilized by N-Heterocyclic Carbenes

Rivada Wheelaghan, Orestes; Roselló Merino, Marta; Díez, Josefina; Maya Díaz, Celia María; López Serrano, Joaquín; Conejero, Salvador (American Chemical Society, 2014-01-01)
Cationic five-coordinate Pt(IV) alkyl complexes stabilized by bulky N-heterocyclic carbenes have been isolated and fully ...
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Quadruply bonded dimolybdenum complexes with highly unusual geometries and vacant coordination sites

Carrasco, Mario; Faust, Michelle; Peloso, Riccardo; Rodríguez Iglesias, María Amor; López Serrano, Joaquín; Álvarez González, Eleuterio; Maya Díaz, Celia María; Power, Philip P.; Carmona Guzmán, Ernesto (Royal Society of Chemistry (Great Britain), 2012-01-01)
New quadruply bonded dimolybdenum complexes of the terphenyl ligand Ar Xyl2 (Ar Xyl2 = C 6H 3-2,6-(C 6H 3-2,6-Me 2) 2) ...
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Coupling of Aromatic Aldehydes with CO2Me-Substituted TpMe2Ir(III) Metallacyclopentadienes

Roa, Arián E.; Salazar, Verónica; López Serrano, Joaquín; Oñate, Enrique; Alvarado Rodrı́guez, José G.; Paneque Sosa, Margarita; Poveda, Manuel L. (American Chemical Society, 2012-01-01)
The fully CO2Me substituted aquo-iridacyclopentadiene 1 reacts with a variety of aromatic aldehydes, at 90–120 °C, with ...