NameLópez Serrano, Joaquín
DepartmentQuímica Inorgánica
Knowledge areaQuímica Inorgánica
Professional categoryProfesor Titular de Universidad
E-mailRequest
           
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Broad-Scope Amination of Aryl Sulfamates Catalyzed by a Palladium Phosphine Complex

Monti, Andrea; López Serrano, Joaquín; Prieto Cárdenas, María Auxiliadora; Nicasio Jaramillo, María del Carmen (American Chemical Society, 2023)
Among phenol-derived electrophiles, aryl sulfamates are attractive substrates since they can be employed as directing ...
PhD Thesis
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Nuevos ligandos fosforados voluminosos y sus complejos mono- y dinucleares de platino: síntesis, propiedades y estudios computacionales

Moreno Alcaide, María; López Serrano, Joaquín; Peloso, Riccardo (2023)
Esta tesis doctoral tiene como hilo conductor los ligandos fosforados consustituyentes voluminosos, tratando de la síntesis ...
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Biocatalytic Atroposelective Synthesis of Axially Chiral N-Arylindoles via Dynamic Kinetic Resolution

Rodríguez Salamanca, Patricia; Gonzalo Calvo, Gonzalo de; Carmona, José A.; López Serrano, Joaquín; Iglesias Sigüenza, Francisco Javier; Fernández Fernández, Rosario Fátima; Lassaletta, José M.; Hornillos, Valentín (American Chemical Society, 2022)
A highly enantioselective biocatalytic dynamic kinetic resolution (DKR) of configurationally labile N-arylindole aldehydes ...
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Electrophilic activation of alkynes promoted by a cationic alkylidene complex of Pt(II)

Alcaide, María M.; Sánchez Mellado, Práxedes; Álvarez, Eleuterio; Maya Díaz, Celia María; López Serrano, Joaquín; Peloso, Riccardo (Royal Society of Chemistry, 2022)
Pt(II) alkylidene 1a has been reacted with terminal alkynes to afford ylide complexes 3a-d, resulting from electrophilic ...
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Structural diversity and magnetic properties of copper(ii) quinaldinate compounds with amino alcohols

Podjed, Nina; Modec, Barbara; Clérac, Rodolphe; Rouzières, Mathieu; Alcaide, María M.; López Serrano, Joaquín (Royal Society of Chemistry, 2022)
The reactions between [Cu(quin)2(H2O)] (quin− = the anionic form of quinoline-2-carboxylic acid) and a series of aliphatic ...
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New Phosphonite Ligands with High Steric Demand and Low Basicity: Synthesis, Structural Properties and Cyclometalated Complexes of Pt(II)

Alcaide, María M.; Pugliesi, Matteo; Álvarez, Eleuterio; López Serrano, Joaquín; Peloso, Riccardo (Multidisciplinary Digital Publishing Institute (MDPI), 2022)
Two phosphonite ligands bearing the highly sterically demanding 2,6-bis (2,6-dimethylphenyl)phenyl group (ArXyl2), ...
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Ammonia–Borane Dehydrogenation Catalyzed by Dual-Mode Proton-Responsive Ir-CNNH Complexes

Ortega Lepe, Isabel; Rossin, Andrea; Sánchez Mellado, Práxedes; López Santos, Laura; Rendón Márquez, Nuria; Álvarez González, Eleuterio; López Serrano, Joaquín; Suárez Escobar, Andrés Luis (American Chemical Society, 2021)
Metal complexes incorporating proton-responsive ligands have been proved to be superior catalysts in reactions involving ...
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Dehydrogenative Double C−H Bond Activation in a Germylene-Rhodium Complex

Bajo Velázquez, Sonia; Alcaide, María M.; López Serrano, Joaquín; Campos, Jesús (Wiley, 2021)
Transition metal tetrylene complexes offer great opportunities for molecular cooperation due to the ambiphilic character ...
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Selective, Base-Free Hydrogenation of Aldehydes Catalyzed by Ir Complexes Based on Proton-Responsive Lutidine-Derived CNP Ligands

Sánchez Mellado, Práxedes; Hernández Juárez, Martín; Rendón Márquez, Nuria; López Serrano, Joaquín; Álvarez González, Eleuterio; Paneque Sosa, Margarita; Suárez Escobar, Andrés Luis (American Chemical Society, 2021)
Metal catalysts based on ligands containing proton-responsive sites have found widespread applications in the hydrogenation ...
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From cyclic amines and acetonitrile to amidine zinc(II) complexes

Podjed, Nina; Modec, Barbara; Alcaide, María M.; López Serrano, Joaquín (Royal Society of Chemistry, 2020)
A seemingly simple combination of [Zn(quin)2(H2O)] (quin− = quinaldinate) and a selected secondary cyclic amine, piperidine ...
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Structural Snapshots of π-Arene Bonding in a Gold Germylene Cation

Bajo Velázquez, Sonia; Alcaide, María M.; López Serrano, Joaquín; Campos, Jesús (Wiley, 2020)
Heavier group 14 element cations exhibit a remarkable reactivity that has typically hampered their isolation. For the few ...
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Metal-only Lewis Pairs of Rhodium with s, p and d-Block Metals

Bajo Velázquez, Sonia; González Alférez, Macarena; Moreno Alcaide, María; López Serrano, Joaquín; Campos, Jesús (Wiley, 2020)
Metal-only Lewis pairs (MOLPs) in which the two metal fragments are solely connected by a dative M→M bond represent ...
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Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with Gold(I)/Platinum(0) Systems

Hidalgo, Nereida; Moreno Díaz, Juan José; Pérez Jiménez, Marina; Maya Díaz, Celia María; López Serrano, Joaquín; Campos Manzano, Jesús (Wiley-Blackwell, 2020)
A joint experimental/computational effort to elucidate the mechanism of dihydrogen activation by a gold(I)/platinum(0) ...
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Ir-Catalyzed Atroposelective Desymmetrization of Heterobiaryls: Hydroarylation of Vinyl Ethers and Bicycloalkenes

Romero Arenas, Antonio; Hornillos, Valentín; Iglesias Sigüenza, Francisco Javier; Fernández Fernández, Rosario Fátima; López Serrano, Joaquín; Ros, Abel; Lassaletta, José M. (American Chemical Society, 2020)
A highly regio-, diastereo-, and enantioselective, scalable Ir-catalyzed hydroarylation of electron-rich acyclic and ...
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Tuning Activity and Selectivity during Alkyne Activation by Gold(I)/Platinum(0) Frustrated Lewis Pairs

Hidalgo, Nereida; Moreno Díaz, Juan José; Pérez Jiménez, Marina; Maya Díaz, Celia María; López Serrano, Joaquín; Campos, Jesús (American Chemical Society, 2020)
Introducing transition metals into frustrated Lewis pair systems has attracted considerable attention in recent years. ...
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Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands

Sánchez Mellado, Práxedes; Hernández Juárez, Martín; Rendón Márquez, Nuria; López Serrano, Joaquín; López Santos, Laura; Álvarez González, Eleuterio; Paneque Sosa, Margarita; Suárez Escobar, Andrés Luis (Royal Society of Chemistry, 2020)
Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts ...
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Metalated Ir–CNP Complexes Containing Imidazolin-2-ylidene and Imidazolidin-2-ylidene Donors – Synthesis, Structure, Luminescence, and Metal–Ligand Cooperative Reactivity

Hernández Juárez, Martín; Sánchez, Práxedes; López Serrano, Joaquín; Lara Muñoz, Patricia; González Herrero, Pablo; Rendón Márquez, Nuria; Álvarez, Eleuterio; Paneque, Margarita; Suárez, Andrés (Wiley-Blackwell, 2020)
The iridium complex 1 based on a metalated CNP ligand containing an imidazolin-2-ylidene fragment has been prepared by ...
PhD Thesis
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Synthesis, reactivity and computational studies of ir complexes bearing terphenyl phosphine ligands.

Moreno Díaz, Juan José; Campos Manzano, Jesús; Carmona Guzmán, Ernesto; López Serrano, Joaquín (2019)
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Double asymmetric hydrogenation of conjugated dienes: a self-breeding chirality route for C2 symmetric 1,4-diols

León García, Félix; Francos, Javier; López Serrano, Joaquín; García Garrido, Sergio E.; Cadierno, Victorio; Pizzano, Antonio (Royal Society of Chemistry, 2019)
The synthesis and double asymmetric hydrogenation of (Z,Z)-1,3- diene-1,4-diyl diacetates is described. In this reaction ...
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Base-Promoted, Remote C−H Activation at a Cationic (η5 ‑C5Me5)Ir(III) Center Involving Reversible C−C Bond Formation of Bound C5Me5

Moreno Díaz, Juan José; Fernández Espada-Pastor, María; Campos Manzano, Jesús; López Serrano, Joaquín; Macgregor, Stuart A.; Carmona Guzmán, Ernesto (American Chemical Society, 2019)
C-H bond activation at cationic [(η5-C5Me5)Ir(PMe2Ar')] centers is described, where PMe2Ar' are the terphenyl phosphine ...
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Evaluating stereoelectronic properties of bulky dialkylterphenyl phosphine ligands

Marín Gómez, Mario; Moreno Díaz, Juan José; Alcaide, María M.; Álvarez González, Eleuterio; López Serrano, Joaquín; Campos Manzano, Jesús; Nicasio Jaramillo, María del Carmen; Carmona Guzmán, Ernesto (Elsevier, 2019)
The stereoelectronic properties of a series of sterically hindered phosphines containing a terphenyl substituent, PR2Ar’ ...
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Cationic (η5-C5Me4R)RhIII Complexes with Metalated Aryl Phosphines Featuring η4-Phosphorus plus Pseudo-Allylic Coordination

Fernández Espada, María; Esqueda Oliva, Ana Cristina; Campos Manzano, Jesús; Rubio Moreno, Miguel; López Serrano, Joaquín; Maya Díaz, Celia María; Carmona Guzmán, Ernesto (American Chemical Society, 2018)
In this contribution we study experimentally and computationally some electrophilic cationic (η5-C5Me4R)RhIII complexes ...
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Activation of Small Molecules by the Metal-Amido Bond of Rhodium(III) and Iridium(III) (η5-C5Me5)M-Aminopyridinate Complexes

Zamorano Márquez, Ana; Rendón Márquez, Nuria; López Serrano, Joaquín; Álvarez González, Eleuterio; Carmona Guzmán, Ernesto (American Chemical Society, 2018)
We report the synthesis and structural characterization of five-coordinate complexes of rhodium and iridium of the type ...
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Hydrogenation of an iridium-coordinated imidazol-2-ylidene ligand fragment

Hernández Juárez, Martín; López Serrano, Joaquín; González Herrero, P.; Rendón Márquez, Nuria; Álvarez González, Eleuterio; Paneque Sosa, Margarita; Suárez Escobar, Andrés Luis (Royal Society of Chemistry, 2018)
An iridium complex featuring a metalated lutidine-derived CNP ligand reacts with KOt Bu to yield a dimeric species with ...
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Hydroboration of carbon dioxide with catechol- and pinacolborane using an Ir–CNP* pincer complex. Water influence on the catalytic activity

Sánchez Mellado, Práxedes; Hernández Juárez, Martín; Rendón Márquez, Nuria; López Serrano, Joaquín; Álvarez González, Eleuterio; Paneque Sosa, Margarita; Suárez Escobar, Andrés Luis (Royal Society of Chemistry, 2018)
Iridium complexes based on deprotonated lutidine-derived CNP* pincers 2a/2b selectively catalyzed the hydroboration of CO2 ...
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Ligand Rearrangement and Hemilability in R hodium(I) and Iridium(I) Complexes Bearing Terphenyl Phosphines

Moreno Díaz, Juan José; Fernández Espada, María; Krüger, Eric; López Serrano, Joaquín; Campos, Jesús; Carmona Guzmán, Ernesto (Wiley, 2018)
We describe the synthesis of a series of cationic rhodium(I) and iridium(I) compounds stabilized by sterically ...
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Selective catalytic synthesis of amino-silanes at part-per million catalyst loadings

Ríos Moreno, Pablo; Roselló Merino, Marta; Rivada Wheelaghan, Orestes; Borge, Javier; López Serrano, Joaquín; Conejero Iglesias, Salvador (Royal Society of Chemistry, 2018)
Platinum(II) complex [Pt(It Bu0 )(It Bu)][BArF 4] (1a) is a highly active and selective catalyst in the dehydrocoupling ...
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Dynamic Kinetic Resolution of Hetero biaryl Ketones by Zinc- Catalyzed Asymmetr ic Hydrosil ylation

Hornillos, Valentín; Carmona, José A.; Ros Lao, Abel; Iglesias Sigüenza, Francisco Javier; López Serrano, Joaquín; Fernández Fernández, Rosario Fátima; Lassaletta, José M. (Wiley, 2018)
Adiastereo- and highly enantioselective dynamic kinetic resolution (DKR) of configurationally labile hetero- biaryl ketones is ...
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Reactivity of a trans-[H-Mo≣Mo-H] Unit Towards Alkenes and Alkynes. Bimetallic Migratory Insertion, H-Elimination and Other Reactions

Pérez Jiménez, Marina; Campos Manzano, Jesús; López Serrano, Joaquín; Carmona Guzmán, Ernesto (Royal Society of Chemistry, 2018)
Complex [Mo2(H)2{μ-HC(NDipp)2}2(THF)2], (1·THF), reacts with C2H4 and PhCH[double bond, length as m-dash]CH2 to afford ...
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Rhodium(I) Complexes with Ligands Based on N-Heterocyclic Carbene and Hemilabile Pyridine Donors as Highly E Stereoselective Alkyne Hydrosilylation Catalysts

Morales Cerón, Judith; Lara Muñoz, Patricia; López Serrano, Joaquín; López Santos, Laura; Salazar Pereda, Verónica; Álvarez González, Eleuterio; Suárez Escobar, Andrés Luis (American Chemical Society, 2017)
Cationic rhodium(I) complexes containing picolyl-NHC (NHC = N-heterocyclic carbene) ligands that differ in the substitution ...
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A Cationic Unsaturated Platinum(II) Complex that Promotes the Tautomerization of Acetylene to Vinylidene

Ortega Moreno, Laura; Peloso, Riccardo; López Serrano, Joaquín; Iglesias Sigüenza, Francisco Javier; Maya Díaz, Celia María; Carmona Guzmán, Ernesto (Wiley-VCH, 2017)
Complex [PtMe(PMeAr)] (1), which contains a tethered terphenyl phosphine (Ar =2,6-(2,6-PrCH)CH), reacts with [H(EtO)]BAr ...
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Following palladium catalyzed methoxycarbonylation by hyperpolarized NMR spectroscopy: a parahydrogen based investigation

Guan, Dexin; Holmes, A. Jonathan; López Serrano, Joaquín; Duckett, Simon B (Royal Society of Chemistry, 2017)
Pd(OTf)2(bcope) is shown to react in methanol solution with diphenylacetylene, carbon monoxide and hydrogen to produce the ...
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Synthesis, properties, and some rhodium, iridium, and platinum complexes of a series of bulky m-terphenylphosphine ligands

Ortega Moreno, Laura; Fernández Espada, María; Moreno Díaz, Juan José; Navarro Gilabert, Carlos; Campos Manzano, Jesús; Conejero Iglesias, Salvador; López Serrano, Joaquín; Maya Díaz, Celia María; Peloso, Riccardo; Carmona Guzmán, Ernesto (Elsevier, 2016)
A series of sterically demanding aryl phosphine ligands (L) bearing terphenyl substituents, PR2Ar′ (R = hydrocarbyl, Ar′ ...
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Mechanistic Studies on the Selective Reduction of CO2 to the Aldehyde Level by a PBP-Supported Nickel Complex

Ríos Moreno, Pablo; Rodríguez, Amor; López Serrano, Joaquín (American Chemical Society, 2016)
This work describes a thorough investigation of the mechanism of a highly selective hydrosilylation of CO2 to the formaldehyde ...
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Cationic Platinum(II) σ-SiH Complexes in Carbon Dioxide Hydrosilation

Ríos Moreno, Pablo; Díez, Josefina; López Serrano, Joaquín; Rodríguez, Amor; Conejero, Salvador (John Wiley & Sons, 2016)
The low-electron-count cationic platinum complex [Pt(ItBu’)(ItBu)][BAr], 1, interacts with primary and secondary silanes ...
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Methyl Complexes of the Transition Metals

Campos, Jesús; López Serrano, Joaquín; Peloso, Riccardo; Carmona Guzmán, Ernesto (John Wiley & Sons, 2016)
Organometallic chemistry can be considered as a wide area of knowledge that combines concepts of classic organic chemistry, ...
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Selective reduction of carbon dioxide to bis(silyl)acetal catalyzed by a PBP-supported nickel complex

Ríos Moreno, Pablo; Curado, Natalia; López Serrano, Joaquín; Rodríguez, Amor (American Chemical Society, 2016)
Selective reduction of CO2 to the formaldehyde level remains an important challenge and to date only a few catalysts have ...
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Ruthenium(II) Complexes Containing Lutidine-derived Pincer CNC Ligands: Synthesis, Structure and Catalytic Hydrogenation of C=N bonds

Hernández Juárez, Martín; López Serrano, Joaquín; Lara Muñoz, Patricia; Morales Cerón, Judith; Vaquero Gutiérrez, Mónica; Álvarez González, Eleuterio; Salazar Pereda, Verónica; Suárez Escobar, Andrés Luis (Wiley-Blackwell, 2015)
A series of Ru complexes containing lutidine‐derived pincer CNC ligands have been prepared by transmetalation with the ...
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Lithium Di-­‐ and Trimethyl Dimolybdenum(II) Complexes with Mo-­‐Mo Quadruple Bonds and Bridging Methyl Groups

Curado, Natalia; Carrasco, Mario; Álvarez González, Eleuterio; Maya Díaz, Celia María; Peloso, Riccardo; Rodríguez, Amor; López Serrano, Joaquín; Carmona Guzmán, Ernesto (American Chemical Society, 2015)
New dimolybdenum complexes of composition [Mo2{μ-Me}2Li(S)}(μ- X)(μ-N^N)2] (3a−3c), where S = THF or Et2O and N^N represents ...
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A Diels–Alder Reaction Triggered by a [4 + 3] Metallacycloaddition

Vivancos Ureña, Ángela; Vattier Lagarrigue, María Florencia; López Serrano, Joaquín; Paneque Sosa, Margarita; López Poveda, Manuel; Álvarez González, Eleuterio (American Chemical Society, 2015)
The TpMe2Ir(III) complex 1-OH2 (TpMe2 = hydrotris(3,5-dimethylpyrazolyl)borate), which contains a labile molecule of water ...
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Boryl-assisted hydrogenolysis of a nickel–methyl bond

Curado Dianez, Natalia; Maya Díaz, Celia María; López Serrano, Joaquín; Rodríguez Iglesias, María Amor (Royal Society of Chemistry (Great Britain), 2014)
A stable Nickel(II) methyl complex containing a diphosphinoboryl (PBP) pincer ligand is described. Mechanistic studies on ...
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Formation of C−X Bonds Through Stable Low-Electron Count Cationic Pt(IV) Alkyl Complexes Stabilized by N-Heterocyclic Carbenes

Rivada Wheelaghan, Orestes; Roselló Merino, Marta; Díez, Josefina; Maya Díaz, Celia María; López Serrano, Joaquín; Conejero, Salvador (American Chemical Society, 2014)
Cationic five-coordinate Pt(IV) alkyl complexes stabilized by bulky N-heterocyclic carbenes have been isolated and fully ...
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Coupling of Aromatic Aldehydes with CO2Me-Substituted TpMe2Ir(III) Metallacyclopentadienes

Espinosa-Roa, Arián; Salazar Pereda, Verónica; López Serrano, Joaquín; Oñate Rodríguez, Enrique; Alvarado Rodrı́guez, José G.; Paneque Sosa, Margarita; López Poveda, Manuel (American Chemical Society, 2012)
The fully CO2Me substituted aquo-iridacyclopentadiene 1 reacts with a variety of aromatic aldehydes, at 90–120 °C, with ...
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Quadruply bonded dimolybdenum complexes with highly unusual geometries and vacant coordination sites

Carrasco, Mario; Faust, Michelle; Peloso, Riccardo; Rodríguez Iglesias, María Amor; López Serrano, Joaquín; Álvarez González, Eleuterio; Maya Díaz, Celia María; Power, Philip P.; Carmona Guzmán, Ernesto (Royal Society of Chemistry (Great Britain), 2012)
New quadruply bonded dimolybdenum complexes of the terphenyl ligand Ar Xyl2 (Ar Xyl2 = C 6H 3-2,6-(C 6H 3-2,6-Me 2) 2) ...