Perfil del autor: López Serrano, Joaquín
Datos institucionales
| Nombre | López Serrano, Joaquín |
| Departamento | Química Inorgánica |
| Área de conocimiento | Química Inorgánica |
| Categoría profesional | Profesor Titular de Universidad |
| Correo electrónico | Solicitar |
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Estadísticas
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Nº publicaciones
45
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Nº visitas
3416
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Nº descargas
3800
| Publicaciones |
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Artículo
 Tuning the Inorganic Core of a reduced Ni2Ge2 Cluster
(Wiley, 2024)
Tetranuclear cores (M−E)2 of transition metals (M) and tetrylenes (EII=Si, Ge, Sn) are key motifs in homogeneous and ... |
Artículo
Broad-Scope Amination of Aryl Sulfamates Catalyzed by a Palladium Phosphine Complex
(American Chemical Society, 2023)
Among phenol-derived electrophiles, aryl sulfamates are attractive substrates since they can be employed as directing ... |
Tesis Doctoral
 Nuevos ligandos fosforados voluminosos y sus complejos mono- y dinucleares de platino: síntesis, propiedades y estudios computacionales
(2023)
Esta tesis doctoral tiene como hilo conductor los ligandos fosforados consustituyentes voluminosos, tratando de la síntesis ... |
Artículo
Biocatalytic Atroposelective Synthesis of Axially Chiral N-Arylindoles via Dynamic Kinetic Resolution
(American Chemical Society, 2022)
A highly enantioselective biocatalytic dynamic kinetic resolution (DKR) of configurationally labile N-arylindole aldehydes ... |
Artículo
Electrophilic activation of alkynes promoted by a cationic alkylidene complex of Pt(II)
(Royal Society of Chemistry, 2022)
Pt(II) alkylidene 1a has been reacted with terminal alkynes to afford ylide complexes 3a-d, resulting from electrophilic ... |
Artículo
Structural diversity and magnetic properties of copper(ii) quinaldinate compounds with amino alcohols
(Royal Society of Chemistry, 2022)
The reactions between [Cu(quin)2(H2O)] (quin− = the anionic form of quinoline-2-carboxylic acid) and a series of aliphatic ... |
Artículo
New Phosphonite Ligands with High Steric Demand and Low Basicity: Synthesis, Structural Properties and Cyclometalated Complexes of Pt(II)
(Multidisciplinary Digital Publishing Institute (MDPI), 2022)
Two phosphonite ligands bearing the highly sterically demanding 2,6-bis (2,6-dimethylphenyl)phenyl group (ArXyl2), ... |
Artículo
Selective, Base-Free Hydrogenation of Aldehydes Catalyzed by Ir Complexes Based on Proton-Responsive Lutidine-Derived CNP Ligands
(American Chemical Society, 2021)
Metal catalysts based on ligands containing proton-responsive sites have found widespread applications in the hydrogenation ... |
Artículo
Ammonia–Borane Dehydrogenation Catalyzed by Dual-Mode Proton-Responsive Ir-CNNH Complexes
(American Chemical Society, 2021)
Metal complexes incorporating proton-responsive ligands have been proved to be superior catalysts in reactions involving ... |
Artículo
Dehydrogenative Double C−H Bond Activation in a Germylene-Rhodium Complex
(Wiley, 2021)
Transition metal tetrylene complexes offer great opportunities for molecular cooperation due to the ambiphilic character ... |
Artículo
Structural Snapshots of π-Arene Bonding in a Gold Germylene Cation
(Wiley, 2020)
Heavier group 14 element cations exhibit a remarkable reactivity that has typically hampered their isolation. For the few ... |
Artículo
Tuning Activity and Selectivity during Alkyne Activation by Gold(I)/Platinum(0) Frustrated Lewis Pairs
(American Chemical Society, 2020)
Introducing transition metals into frustrated Lewis pair systems has attracted considerable attention in recent years. ... |
Artículo
Ir-Catalyzed Atroposelective Desymmetrization of Heterobiaryls: Hydroarylation of Vinyl Ethers and Bicycloalkenes
(American Chemical Society, 2020)
A highly regio-, diastereo-, and enantioselective, scalable Ir-catalyzed hydroarylation of electron-rich acyclic and ... |
Artículo
Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands
(Royal Society of Chemistry, 2020)
Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts ... |
Artículo
From cyclic amines and acetonitrile to amidine zinc(II) complexes
(Royal Society of Chemistry, 2020)
A seemingly simple combination of [Zn(quin)2(H2O)] (quin− = quinaldinate) and a selected secondary cyclic amine, piperidine ... |
Artículo
Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with Gold(I)/Platinum(0) Systems
(Wiley-Blackwell, 2020)
A joint experimental/computational effort to elucidate the mechanism of dihydrogen activation by a gold(I)/platinum(0) ... |
Artículo
Metalated Ir–CNP Complexes Containing Imidazolin-2-ylidene and Imidazolidin-2-ylidene Donors – Synthesis, Structure, Luminescence, and Metal–Ligand Cooperative Reactivity
(Wiley-Blackwell, 2020)
The iridium complex 1 based on a metalated CNP ligand containing an imidazolin-2-ylidene fragment has been prepared by ... |
Artículo
Metal-only Lewis Pairs of Rhodium with s, p and d-Block Metals
(Wiley, 2020)
Metal-only Lewis pairs (MOLPs) in which the two metal fragments are solely connected by a dative M→M bond represent ... |
| Tesis Doctoral |
Artículo
Evaluating stereoelectronic properties of bulky dialkylterphenyl phosphine ligands
(Elsevier, 2019)
The stereoelectronic properties of a series of sterically hindered phosphines containing a terphenyl substituent, PR2Ar’ ... |
Artículo
Base-Promoted, Remote C−H Activation at a Cationic (η5 ‑C5Me5)Ir(III) Center Involving Reversible C−C Bond Formation of Bound C5Me5
(American Chemical Society, 2019)
C-H bond activation at cationic [(η5-C5Me5)Ir(PMe2Ar')] centers is described, where PMe2Ar' are the terphenyl phosphine ... |
Artículo
Double asymmetric hydrogenation of conjugated dienes: a self-breeding chirality route for C2 symmetric 1,4-diols
(Royal Society of Chemistry, 2019)
The synthesis and double asymmetric hydrogenation of (Z,Z)-1,3- diene-1,4-diyl diacetates is described. In this reaction ... |
Artículo
Cationic (η5-C5Me4R)RhIII Complexes with Metalated Aryl Phosphines Featuring η4-Phosphorus plus Pseudo-Allylic Coordination
(American Chemical Society, 2018)
In this contribution we study experimentally and computationally some electrophilic cationic (η5-C5Me4R)RhIII complexes ... |
Artículo
Activation of Small Molecules by the Metal-Amido Bond of Rhodium(III) and Iridium(III) (η5-C5Me5)M-Aminopyridinate Complexes
(American Chemical Society, 2018)
We report the synthesis and structural characterization of five-coordinate complexes of rhodium and iridium of the type ... |
Artículo
Ligand Rearrangement and Hemilability in R hodium(I) and Iridium(I) Complexes Bearing Terphenyl Phosphines
(Wiley, 2018)
We describe the synthesis of a series of cationic rhodium(I) and iridium(I) compounds stabilized by sterically ... |
Artículo
Hydroboration of carbon dioxide with catechol- and pinacolborane using an Ir–CNP* pincer complex. Water influence on the catalytic activity
(Royal Society of Chemistry, 2018)
Iridium complexes based on deprotonated lutidine-derived CNP* pincers 2a/2b selectively catalyzed the hydroboration of CO2 ... |
Artículo
Hydrogenation of an iridium-coordinated imidazol-2-ylidene ligand fragment
(Royal Society of Chemistry, 2018)
An iridium complex featuring a metalated lutidine-derived CNP ligand reacts with KOt Bu to yield a dimeric species with ... |
Artículo
Selective catalytic synthesis of amino-silanes at part-per million catalyst loadings
(Royal Society of Chemistry, 2018)
Platinum(II) complex [Pt(It Bu0 )(It Bu)][BArF 4] (1a) is a highly active and selective catalyst in the dehydrocoupling ... |
Artículo
Reactivity of a trans-[H-Mo≣Mo-H] Unit Towards Alkenes and Alkynes. Bimetallic Migratory Insertion, H-Elimination and Other Reactions
(Royal Society of Chemistry, 2018)
Complex [Mo2(H)2{μ-HC(NDipp)2}2(THF)2], (1·THF), reacts with C2H4 and PhCH[double bond, length as m-dash]CH2 to afford ... |
Artículo
 Dynamic Kinetic Resolution of Hetero biaryl Ketones by Zinc- Catalyzed Asymmetr ic Hydrosil ylation
(Wiley, 2018)
Adiastereo- and highly enantioselective dynamic kinetic resolution (DKR) of configurationally labile hetero- biaryl ketones is ... |
Artículo
Following palladium catalyzed methoxycarbonylation by hyperpolarized NMR spectroscopy: a parahydrogen based investigation
(Royal Society of Chemistry, 2017)
Pd(OTf)2(bcope) is shown to react in methanol solution with diphenylacetylene, carbon monoxide and hydrogen to produce the ... |
Artículo
Rhodium(I) Complexes with Ligands Based on N-Heterocyclic Carbene and Hemilabile Pyridine Donors as Highly E Stereoselective Alkyne Hydrosilylation Catalysts
(American Chemical Society, 2017)
Cationic rhodium(I) complexes containing picolyl-NHC (NHC = N-heterocyclic carbene) ligands that differ in the substitution ... |
Artículo
A Cationic Unsaturated Platinum(II) Complex that Promotes the Tautomerization of Acetylene to Vinylidene
(Wiley-VCH, 2017)
Complex [PtMe(PMeAr)] (1), which contains a tethered terphenyl phosphine (Ar =2,6-(2,6-PrCH)CH), reacts with [H(EtO)]BAr ... |
Artículo
Cationic Platinum(II) σ-SiH Complexes in Carbon Dioxide Hydrosilation
(John Wiley & Sons, 2016)
The low-electron-count cationic platinum complex [Pt(ItBu’)(ItBu)][BAr], 1, interacts with primary and secondary silanes ... |
Artículo
Synthesis, properties, and some rhodium, iridium, and platinum complexes of a series of bulky m-terphenylphosphine ligands
(Elsevier, 2016)
A series of sterically demanding aryl phosphine ligands (L) bearing terphenyl substituents, PR2Ar′ (R = hydrocarbyl, Ar′ ... |
Artículo
Mechanistic Studies on the Selective Reduction of CO2 to the Aldehyde Level by a PBP-Supported Nickel Complex
(American Chemical Society, 2016)
This work describes a thorough investigation of the mechanism of a highly selective hydrosilylation of CO2 to the formaldehyde ... |
Artículo
Methyl Complexes of the Transition Metals
(John Wiley & Sons, 2016)
Organometallic chemistry can be considered as a wide area of knowledge that combines concepts of classic organic chemistry, ... |
Artículo
Selective reduction of carbon dioxide to bis(silyl)acetal catalyzed by a PBP-supported nickel complex
(American Chemical Society, 2016)
Selective reduction of CO2 to the formaldehyde level remains an important challenge and to date only a few catalysts have ... |
Artículo
Lithium Di-‐ and Trimethyl Dimolybdenum(II) Complexes with Mo-‐Mo Quadruple Bonds and Bridging Methyl Groups
(American Chemical Society, 2015)
New dimolybdenum complexes of composition [Mo2{μ-Me}2Li(S)}(μ- X)(μ-N^N)2] (3a−3c), where S = THF or Et2O and N^N represents ... |
Artículo
A Diels–Alder Reaction Triggered by a [4 + 3] Metallacycloaddition
(American Chemical Society, 2015)
The TpMe2Ir(III) complex 1-OH2 (TpMe2 = hydrotris(3,5-dimethylpyrazolyl)borate), which contains a labile molecule of water ... |
Artículo
Ruthenium(II) Complexes Containing Lutidine-derived Pincer CNC Ligands: Synthesis, Structure and Catalytic Hydrogenation of C=N bonds
(Wiley-Blackwell, 2015)
A series of Ru complexes containing lutidine‐derived pincer CNC ligands have been prepared by transmetalation with the ... |
Artículo
Boryl-assisted hydrogenolysis of a nickel–methyl bond
(Royal Society of Chemistry (Great Britain), 2014)
A stable Nickel(II) methyl complex containing a diphosphinoboryl (PBP) pincer ligand is described. Mechanistic studies on ... |
Artículo
Formation of C−X Bonds Through Stable Low-Electron Count Cationic Pt(IV) Alkyl Complexes Stabilized by N-Heterocyclic Carbenes
(American Chemical Society, 2014)
Cationic five-coordinate Pt(IV) alkyl complexes stabilized by bulky N-heterocyclic carbenes have been isolated and fully ... |
Artículo
Coupling of Aromatic Aldehydes with CO2Me-Substituted TpMe2Ir(III) Metallacyclopentadienes
(American Chemical Society, 2012)
The fully CO2Me substituted aquo-iridacyclopentadiene 1 reacts with a variety of aromatic aldehydes, at 90–120 °C, with ... |
Artículo
Quadruply bonded dimolybdenum complexes with highly unusual geometries and vacant coordination sites
(Royal Society of Chemistry (Great Britain), 2012)
New quadruply bonded dimolybdenum complexes of the terphenyl ligand Ar Xyl2 (Ar Xyl2 = C 6H 3-2,6-(C 6H 3-2,6-Me 2) 2) ... |