Artículo
Tuning the Inorganic Core of a reduced Ni2Ge2 Cluster
Autor/es | Theulier, Cyril A.
Bajo Velázquez, Sonia ![]() ![]() ![]() ![]() ![]() ![]() ![]() López Serrano, Joaquín ![]() ![]() ![]() ![]() ![]() ![]() ![]() Campos, Jesús |
Departamento | Universidad de Sevilla. Departamento de Química Inorgánica |
Fecha de publicación | 2024-04 |
Fecha de depósito | 2024-04-24 |
Publicado en |
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Resumen | Tetranuclear cores (M−E)2 of transition metals (M) and tetrylenes (EII=Si, Ge, Sn) are key motifs in homogeneous and heterogeneous catalysis. They exhibit a continuum of M−M and E−E bonding within the inorganic core that ... Tetranuclear cores (M−E)2 of transition metals (M) and tetrylenes (EII=Si, Ge, Sn) are key motifs in homogeneous and heterogeneous catalysis. They exhibit a continuum of M−M and E−E bonding within the inorganic core that leads to a variety of structures for which there are no specific synthetic methods. Herein, we report a series of highly reduced [Ni0GeII]2 squares solely stabilized by bulky terphenyl (C6H3−2,6-Ar2) ligands, for which we provide complementary and high-yielding syntheses. Reactivity studies with common Lewis bases (carbene and CO) evince that the structure of the (M−E)2 core can be transformed. We have investigated this core modification by computational means, offering a rationale to better understand the continuum of bonding across these clusters. |
Agencias financiadoras | European Research Council (ERC) Ministerio de Ciencia e Innovación (MICIN). España Agencia Estatal de Investigación. España European Commission (EC). Fondo Europeo de Desarrollo Regional (FEDER) |
Identificador del proyecto | 756575
![]() PID2019-110856GA-I00 ![]() PID2022-139782NB-I00 ![]() |
Cita | Theulier, C.A., Bajo Velázquez, S., López Serrano, J. y Campos, J. (2024). Tuning the Inorganic Core of a reduced Ni2Ge2 Cluster. Chemistry - A European Journal, 30, e202400049. https://doi.org/10.1002/chem.202400049. |
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