Browsing Artículos (Química Inorgánica) by Title
Now showing items 1-20 of 474
-
Article
1,2,3-Triazoles from carbonyl azides and alkynes: filling the gap
(Royal Society of Chemistry, 2014)Electron deficient azides are challenging substrates in CuAAC reactions. Particularly, when N-carbonyl azides are applied ...
-
Article
5-Hydroxymethyl-2-Furfural Oxidation Over Au/CexZr1-xO2 Catalysts
(Frontiers Media, 2020)A series of gold catalysts supported on pure CeO2, ZrO2, and two different Ce-Zr mixed oxides have been prepared and ...
-
Article
A biradical oxo-molybdenum complex containing semiquinone and o-aminophenol benzoxazole-based ligands
(Royal Society of Chemistry, 2020)We report a new mononuclear molybdenum(IV) complex, MoOLBISLSQ, in which LSQ (2,4-di-tert-butyl o-semibenzoquinone ligand) ...
-
Article
A Cationic Unsaturated Platinum(II) Complex that Promotes the Tautomerization of Acetylene to Vinylidene
(Wiley-VCH, 2017)Complex [PtMe(PMeAr)] (1), which contains a tethered terphenyl phosphine (Ar =2,6-(2,6-PrCH)CH), reacts with [H(EtO)]BAr ...
-
Article
A dicoordinate gold(i)–ethylene complex
(Royal Society of Chemistry, 2021)The use of the exceptionally bulky tris-2-(4,40 -di-tert-butylbiphenylyl) phosphine ligand allows the isolation and ...
-
Article
A Diels–Alder Reaction Triggered by a [4 + 3] Metallacycloaddition
(American Chemical Society, 2015)The TpMe2Ir(III) complex 1-OH2 (TpMe2 = hydrotris(3,5-dimethylpyrazolyl)borate), which contains a labile molecule of water ...
-
Article
A direct in situ observation of water-enhanced proton conductivity of Eu-doped ZrO2: Effect on WGS reaction
(Elsevier, 2018)Eu-doped ZrO2 solid solutions have been synthesized in order to prepare proton conductors as water-enhancer additives for ...
-
Article
A full set of iridium(IV) pyridine-alkoxide stereoisomers: highly geometry-dependent redox properties
(Royal Society of Chemistry, 2017)We introduce and characterize the complete set of possible isomers of IrIV(pyalk)2Cl2 (pyalk ¼ 2-(pyridin-2-yl)propan-2-oate), ...
-
Article
A generalized interface reaction kinetic model for describing heterogeneous processes driven by contracting mechanisms
(Springer, 2024-01-30)The correct determination of the kinetic model and the kinetic parameters that describe a heterogeneous process is key ...
-
Article
A Genuine Germylene PGeP Pincer Ligand for Formic Acid Dehydrogenation with Iridium
(Royal Society of Chemistry, 2023)We report an iridium system constructed around a long-tethered PGeP ligand that facilitates access to the less common ...
-
Article
A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation
(Royal Society of Chemistry, 2022)A series of Au(I)/Pt(0) combinations that behave as bimetallic frustrated Lewis pairs activates dihydrogen in a cooperative ...
-
Article
A new model for the kinetic analysis of thermal degradation of polymers driven by random scission
(Elsevier, 2010)In this paper, a series of f(α) kinetic equations able to describe the random scission degradation of polymers is formulated ...
-
Article
A new model of the carbonator reactor in the Calcium Looping technology for post-combustion CO2 capture
(Elsevier, 2015)The Ca-Looping (CaL) process is considered as a promising technology for CO2 post-combustion capture in power generation ...
-
Article
A simple, general route to 2-pyridylidene transition metal complexes
(Royal Society of Chemistry (Great Britain), 2010-11-04)Pyridinium 2-carboxylates decompose thermally in the presence of a variety of late transition metal precursors to yield ...
-
Article
A versatile approach to access trimetallic complexes based on trisphosphinite ligands
(Multidisciplinary Digital Publishing Institute (MDPI), 2020)A straightforward method for the preparation of trisphosphinite ligands in one step, using only commercially available ...
-
Article
Ab initio x-ray absorption study of copper K -edge XANES spectra in Cu(II) compounds
(American Physical Society, 2005)This work reports a theoretical study of the x-ray absorption near-edge structure spectra at the Cu K edge in several ...
-
Article
Activation of Si-H and B-H bonds by Lewis acidic transition metals and p-block elements: same, but different
(Royal Society of Chemistry, 2022)In this Perspective we discuss the ability of transition metal complexes to activate and cleave the Si–H and B–H bonds of ...
-
Article
Activation of Small Molecules by the Metal-Amido Bond of Rhodium(III) and Iridium(III) (η5-C5Me5)M-Aminopyridinate Complexes
(American Chemical Society, 2018)We report the synthesis and structural characterization of five-coordinate complexes of rhodium and iridium of the type ...
-
Article
Adsorption behaviour of the binary mixtures of octane and nonane at sub-monolayer coverage on graphite
(2001)The behaviour of binary mixtures of octane and nonane adsorbed on graphite has been investigated with a combination of ...
-
Article
Advanced parametrisation of phase change materials through kinetic approach
(Elsevier, 2021)Phase change materials (PCM) have been widely investigated for heat storage and transfer applications. Numerous numerical ...