dc.creator | Theulier, Cyril A. | es |
dc.creator | Bajo Velázquez, Sonia | es |
dc.creator | López Serrano, Joaquín | es |
dc.creator | Campos, Jesús | es |
dc.date.accessioned | 2024-04-24T07:38:05Z | |
dc.date.available | 2024-04-24T07:38:05Z | |
dc.date.issued | 2024-04 | |
dc.identifier.citation | Theulier, C.A., Bajo Velázquez, S., López Serrano, J. y Campos, J. (2024). Tuning the Inorganic Core of a reduced Ni2Ge2 Cluster. Chemistry - A European Journal, 30, e202400049. https://doi.org/10.1002/chem.202400049. | |
dc.identifier.issn | 0947-6539 | es |
dc.identifier.issn | 1521-3765 | es |
dc.identifier.uri | https://hdl.handle.net/11441/157065 | |
dc.description.abstract | Tetranuclear cores (M−E)2 of transition metals (M) and tetrylenes (EII=Si, Ge, Sn) are key motifs in homogeneous and heterogeneous catalysis. They exhibit a continuum of M−M and E−E bonding within the inorganic core that leads to a variety of structures for which there are no specific synthetic methods. Herein, we report a series of highly reduced [Ni0GeII]2 squares solely stabilized by bulky terphenyl (C6H3−2,6-Ar2) ligands, for which we provide complementary and high-yielding syntheses. Reactivity studies with common Lewis bases (carbene and CO) evince that the structure of the (M−E)2 core can be transformed. We have investigated this core modification by computational means, offering a rationale to better understand the continuum of bonding across these clusters. | es |
dc.description.sponsorship | European Research Council (ERC Starting Grant, CoopCat, 756575) | es |
dc.description.sponsorship | MCIN/AEI/ 10.13039/501100011033(PID2019-110856GA-I00) | es |
dc.description.sponsorship | PID2022139782 NB-I00/AEI/10.13039/501100011033/FEDER, UE | es |
dc.format | application/pdf | es |
dc.format.extent | 7 p. | es |
dc.language.iso | eng | es |
dc.publisher | Wiley | es |
dc.relation.ispartof | Chemistry - A European Journal, 30, e202400049. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Tuning the Inorganic Core of a reduced Ni2Ge2 Cluster | es |
dc.type | info:eu-repo/semantics/article | es |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | 756575 | es |
dc.relation.projectID | PID2019-110856GA-I00 | es |
dc.relation.projectID | PID2022-139782NB-I00 | es |
dc.relation.publisherversion | https://dx.doi.org/10.1002/chem.202400049 | es |
dc.identifier.doi | 10.1002/chem.202400049 | es |
dc.journaltitle | Chemistry - A European Journal | es |
dc.publication.volumen | 30 | es |
dc.publication.initialPage | e202400049 | es |
dc.contributor.funder | European Research Council (ERC) | es |
dc.contributor.funder | Ministerio de Ciencia e Innovación (MICIN). España | es |
dc.contributor.funder | Agencia Estatal de Investigación. España | es |
dc.contributor.funder | European Commission (EC). Fondo Europeo de Desarrollo Regional (FEDER) | es |