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Understanding the color change of the solutions of Cp₂TiCl upon addition of water
dc.creator | Rosales Martínez, Antonio | es |
dc.creator | Enríquez Giraudo, Lourdes | es |
dc.creator | Jaraíz Maldonado, Martín | es |
dc.creator | Thiessen, Tanner | es |
dc.creator | Sidhu, Jaspreet | es |
dc.creator | McIndoe, J. Scott | es |
dc.creator | Rodríguez-García, Ignacio | es |
dc.date.accessioned | 2024-06-07T09:20:54Z | |
dc.date.available | 2024-06-07T09:20:54Z | |
dc.date.issued | 2023-02 | |
dc.identifier.issn | 0268-2605 | es |
dc.identifier.issn | 1099-0739 | es |
dc.identifier.uri | https://hdl.handle.net/11441/160015 | |
dc.description.abstract | Reduction of red bis (cyclopentadienyl)titanium (IV) dichloride (Cp₂TiCl₂) with manganese dust in dry THF produces a green solution that turns deep blue upon the addition of traces of water. Mass spectrometric analysis and DFT calculations have been performed to achieve a better understanding of the species that may be present after the interaction of water with reduced Cp₂TiCl₂. The deep blue solution provides a handy visual indicator for the qualitative determination of water in THF. | es |
dc.format | application/pdf | es |
dc.format.extent | 8 p. | es |
dc.language.iso | eng | es |
dc.publisher | Wiley | es |
dc.rights | Atribución 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | * |
dc.subject | Colorimetric indicator | es |
dc.subject | Hydrogen atom transfer reagent | es |
dc.subject | Radical chemistry | es |
dc.subject | Titanocene | es |
dc.title | Understanding the color change of the solutions of Cp₂TiCl upon addition of water | es |
dc.type | info:eu-repo/semantics/article | es |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Ingeniería Química | es |
dc.relation.projectID | USE2020/00001014 | es |
dc.relation.projectID | USE2021/00000422 | es |
dc.relation.publisherversion | https://onlinelibrary.wiley.com/doi/10.1002/aoc.6979 | es |
dc.identifier.doi | 10.1002/aoc.6979 | es |
dc.contributor.group | Universidad de Sevilla. RNM932: Química e Ingeniería Sostenibles | es |
dc.journaltitle | Applied Organometallic Chemistry | es |
dc.publication.volumen | 37 | es |
dc.publication.issue | 2 | es |
dc.publication.initialPage | e6979 | es |
dc.contributor.funder | Universidad de Sevilla | es |
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