Ver ítem 

Mostrar el registro sencillo del ítem

Artículo

Opened Access
Dynamic kinetic resolution of 2-(Quinolin-8-yl)benzaldehydes: atroposelective iridium-catalyzed transfer hydrogenative allylation

dc.creatorCarmona, José A.es
dc.creatorRodríguez Salamanca, Patriciaes
dc.creatorFernández Fernández, Rosario Fátimaes
dc.creatorLassaletta, José M.es
dc.creatorHornillos, Valentínes
dc.date.accessioned2024-05-22T09:06:33Z
dc.date.available2024-05-22T09:06:33Z
dc.date.issued2023-06-30
dc.identifier.citationCarmona, J.A., Rodríguez-Salamanca, P., Fernández Fernández, R.F., Lassaletta, J.M. y Hornillos, V. (2023). Dynamic kinetic resolution of 2-(Quinolin-8-yl)benzaldehydes: atroposelective iridium-catalyzed transfer hydrogenative allylation. Angewandte Chemie - International Edition, 62 (35), e202306981. https://doi.org/10.1002/anie.202306981.
dc.identifier.issn1521-3773es
dc.identifier.issn1433-7851es
dc.identifier.urihttps://hdl.handle.net/11441/158792
dc.description.abstractAn atroposelective Ir-catalyzed dynamic kinetic resolution (DKR) of 2-(quinolin-8- yl)benzaldehydes/1-naphthaldehydes by transfer hydrogenative coupling of allyl acetate is disclosed. The allylation reaction takes place with simultaneous installation of central and axial chirality, reaching high diastereoselectivities and excellent enantiomeric excesses when ortho-cyclometalated iridium-DM-BINAP is used as the catalyst. The racemization of the substrates occurs through a designed transient Lewis acid-base interaction between the quinoline nitrogen atom and the aldehyde carbonyl group.es
dc.description.sponsorshipSpanish Ministerio de Ciencia e Innovación PID2019-106358GB-C21, PID2019-106358GB-C22, RYC-2017-22294 BES-2017-081561 P. R-Ses
dc.description.sponsorshipEuropean funding (ERDF)es
dc.description.sponsorshipJunta de Andalucía P18-FR-3531, P18-FR-644, US-1262867, US-1260906es
dc.formatapplication/pdfes
dc.format.extent6es
dc.language.isoenges
dc.publisherWiley-V C H Verlag GMBHes
dc.relation.ispartofAngewandte Chemie - International Edition, 62 (35), e202306981.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectAllylationes
dc.subjectAsymmetric Catalysises
dc.subjectAxial Chiralityes
dc.subjectIridium Catalysises
dc.subjectQuinolineses
dc.titleDynamic kinetic resolution of 2-(Quinolin-8-yl)benzaldehydes: atroposelective iridium-catalyzed transfer hydrogenative allylationes
dc.typeinfo:eu-repo/semantics/articlees
dc.type.versioninfo:eu-repo/semantics/publishedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Química orgánicaes
dc.relation.projectIDPID2019-106358GB-C21es
dc.relation.projectIDPID2019-106358GB-C22es
dc.relation.projectIDRYC-2017-22294es
dc.relation.projectIDBES-2017-081561 P. R-Ses
dc.relation.projectIDP18-FR-3531es
dc.relation.projectIDP18-FR-644es
dc.relation.projectIDUS-1262867es
dc.relation.projectIDUS-1260906es
dc.relation.publisherversionhttps://doi.org/10.1002/anie.202306981es
dc.identifier.doi10.1002/anie.202306981es
dc.journaltitleAngewandte Chemie - International Editiones
dc.publication.volumen62es
dc.publication.issue35es
dc.publication.initialPagee202306981es
dc.contributor.funderMinisterio de Ciencia e Innovación (MICIN). Españaes
dc.contributor.funderFondo Europeo de Desarrollo Regional (FEDER)es
dc.contributor.funderJunta de Andalucíaes

FicherosTamañoFormatoVerDescripción
Angew Chem Int Ed - 2023 - Carmona ...7.819MbIcon   [PDF] Ver/Abrir  

Este registro aparece en las siguientes colecciones

Mostrar el registro sencillo del ítem

Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Excepto si se señala otra cosa, la licencia del ítem se describe como: Attribution-NonCommercial-NoDerivatives 4.0 Internacional