Article
A Genuine Germylene PGeP Pincer Ligand for Formic Acid Dehydrogenation with Iridium
Author/s | Fernández Buenestado, Marta
Somerville, Rosie J. López Serrano, Joaquín Campos, Jesús |
Department | Universidad de Sevilla. Departamento de Química Inorgánica |
Publication Date | 2023 |
Deposit Date | 2024-04-26 |
Published in |
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Abstract | We report an iridium system constructed around a long-tethered PGeP ligand that facilitates access to the less common germylene form, so far unreported for an ‘NHC-type’ Ge ligand. Its bonding is substantiated by computational ... We report an iridium system constructed around a long-tethered PGeP ligand that facilitates access to the less common germylene form, so far unreported for an ‘NHC-type’ Ge ligand. Its bonding is substantiated by computational studies and we have demonstrated its use for the catalytic dehydrogenation of formic acid, highlighting the potential of this underdeveloped type of ligand. |
Citation | Fernández Buenestado, M., Somerville, R.J., López Serrano, J. y Campos, J. (2023). A Genuine Germylene PGeP Pincer Ligand for Formic Acid Dehydrogenation with Iridium. Chemical Communications, 59 (57), 8826-8829. https://doi.org/10.1039/d3cc02447d. |
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