dc.creator | Benítez Jiménez, José Jesús | es |
dc.creator | Ramírez-Pozo, María del Carmen | es |
dc.creator | Durán-Barrantes, María de la Montaña | es |
dc.creator | Heredia, Antonio | es |
dc.creator | Tedeschi, G. | es |
dc.creator | Ceseracciu, L. | es |
dc.creator | Guzmán-Puyol, Susana | es |
dc.creator | Marrero-López, David | es |
dc.creator | Becci, Alessandro | es |
dc.creator | Amato, Alessia | es |
dc.creator | Heredia Guerrero, José A. | es |
dc.date.accessioned | 2023-01-09T14:30:17Z | |
dc.date.available | 2023-01-09T14:30:17Z | |
dc.date.issued | 2023-02 | |
dc.identifier.citation | Benítez Jiménez, J.J., Ramírez-Pozo, M.d.C., Durán-Barrantes, M.d.l.M., Heredia, A., Tedeschi, G., Ceseracciu, L.,...,Heredia Guerrero, J.A. (2023). Bio-based lacquers from industrially processed tomato pomace for sustainable metal food packaging. Journal of Cleaner Production, 386 (135836). https://doi.org/10.1016/j.jclepro.2022.135836. | |
dc.identifier.issn | 0959-6526 | es |
dc.identifier.uri | https://hdl.handle.net/11441/141044 | |
dc.description.abstract | Bio-based lacquers prepared from an underutilized tomato processing residue such as pomace have been
investigated as sustainable alternatives to bisphenol A (BPA)-based coatings for metal food packaging. The
fabrication methodology consisted of a two-step process: spray-coating of a paste of the lipid fraction of tomato
pomace with a mixture ethanol:H2O (3:1, v:v) on common metal substrates, used for food canning, such as
aluminum (Al), chromium-coated tin-free steel (TFS), and electrochemically tin-plated steel (ETP), followed by
the self melt-polycondensation of such lipid fraction. The polymerization reaction was conducted at 200 ◦C for
different times (10, 20, 30, 40, 50, and 60 min) and was monitored by specular infrared spectroscopy, resulting
in maximum degrees of esterification of ~92% for Al and ~85% for TFS and ETP substrates. The anticorrosion
performance of the coatings was studied by electrochemical impedance spectroscopy at different immersion
times (time intervals of 2–5 h during an overall stability test up to 170 h) in an aqueous solution of 1 wt% NaCl.
The degree of polymerization and the physical properties of the coatings showed a strong dependence on the
metal substrate used. In general, the best results were found for tomato pomace-based lacquers applied on
aluminum, achieving higher mechanical strength (critical load of 1739 ± 198 mN for Al, 1078 ± 31 mN for ETP,
and 852 ± 206 mN for TFS), hydrophobicity (water contact angle ~95◦ for Al, ~91◦ for ETP, and ~88◦ for TFS),
and improved anticorrosion performance (coating resistance of 0.7 MΩcm2 after 170 h of immersion for Al, 0.7
MΩcm2 after 70 h of immersion for TFS, and negligible coating resistance for ETP). In view of the technical
innovation proposed in the present paper, the estimation of the environmental sustainability of the process has
been considered relevant to fit the circular economy target. For this purpose, a life cycle analysis (LCA) was
applied to the overall process, revealing multiple advantages for both the environment and human health. | es |
dc.format | application/pdf | es |
dc.format.extent | 13 p. | es |
dc.language.iso | eng | es |
dc.publisher | Elsevier | es |
dc.relation.ispartof | Journal of Cleaner Production, 386 (135836). | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Bio-based lacquer | es |
dc.subject | Food canning | es |
dc.subject | Tomato pomace | es |
dc.subject | Circular bioeconomy | es |
dc.subject | Life cycle analysis | es |
dc.subject | Metal packaging | es |
dc.title | Bio-based lacquers from industrially processed tomato pomace for sustainable metal food packaging | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Ingeniería Química | es |
dc.relation.publisherversion | https://www.sciencedirect.com/science/article/pii/S0959652622054105 | es |
dc.identifier.doi | 10.1016/j.jclepro.2022.135836 | es |
dc.contributor.group | Universidad de Sevilla. AGR155: Obtención de Biocombustibles | es |
dc.journaltitle | Journal of Cleaner Production | es |
dc.publication.volumen | 386 | es |
dc.publication.issue | 135836 | es |