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Alkoxyamine-cyanoborane adducts: Efficient cyanoborane transfer agents

dc.creatorMárquez, José M.es
dc.creatorMartínez Castro, Elisaes
dc.creatorGabrielli, Serenaes
dc.creatorLópez López, Óscares
dc.creatorMaya Castilla, Inéses
dc.creatorAngulo, Manueles
dc.creatorÁlvarez, Eleuterioes
dc.creatorFernández-Bolaños Guzmán, José Maríaes
dc.date.accessioned2022-11-14T15:49:33Z
dc.date.available2022-11-14T15:49:33Z
dc.date.issued2011
dc.identifier.citationMárquez, J.M., Martínez Castro, E., Gabrielli, S., López López, Ó., Maya Castilla, I., Angulo, M.,...,Fernández-Bolaños Guzmán, J.M. (2011). Alkoxyamine-cyanoborane adducts: Efficient cyanoborane transfer agents. Chemical Communications, 47 (19), 5617-5619. https://doi.org/0.1039/c1cc11345c.
dc.identifier.issn1359-7345es
dc.identifier.issn1364-548Xes
dc.identifier.urihttps://hdl.handle.net/11441/139406
dc.description.abstractWe report the synthesis of the hitherto unknown zwitterionic alkoxyamino cyanoboranes by reduction of O-alkyloximes with sodium cyanoborohydride; unprecedented cyanoboronated N-alkoxyformamidines were also isolated as by-products. Boronated alkoxyamines were found to be efficient cyanoborane transfer agents towards more basic amines, including aminosugars; they were also successfully transformed into neoglycoconjugates by the neoglycorandomization reaction with reducing sugars.es
dc.description.sponsorshipDirección General de Investigación CTQ2008 02813, HI-2006-0131es
dc.description.sponsorshipJunta de Andalucía FQM 134es
dc.formatapplication/pdfes
dc.format.extent3 p.es
dc.language.isoenges
dc.publisherRoyal Society of Chemistryes
dc.relation.ispartofChemical Communications, 47 (19), 5617-5619.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.titleAlkoxyamine-cyanoborane adducts: Efficient cyanoborane transfer agentses
dc.typeinfo:eu-repo/semantics/articlees
dc.type.versioninfo:eu-repo/semantics/acceptedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Química orgánicaes
dc.relation.projectIDCTQ2008 02813es
dc.relation.projectIDHI-2006-0131es
dc.relation.projectIDFQM 134es
dc.relation.publisherversionhttps://dx.doi.org/10.1039/c1cc11345ces
dc.identifier.doi10.1039/c1cc11345ces
dc.journaltitleChemical Communicationses
dc.publication.volumen47es
dc.publication.issue19es
dc.publication.initialPage5617es
dc.publication.endPage5619es
dc.contributor.funderDirección General de Investigación (DGI). Españaes
dc.contributor.funderJunta de Andalucíaes

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