Article
Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands
Author/s | Sánchez Mellado, Práxedes
Hernández Juárez, Martín Rendón Márquez, Nuria López Serrano, Joaquín López Santos, Laura Álvarez González, Eleuterio Paneque Sosa, Margarita Suárez Escobar, Andrés Luis |
Department | Universidad de Sevilla. Departamento de Química Inorgánica |
Publication Date | 2020 |
Deposit Date | 2022-09-13 |
Published in |
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Abstract | Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts in the hydrogenation and dehydrogenation of N-heterocycles. Reaction of a Ru-CNN(H) complex with ... Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts in the hydrogenation and dehydrogenation of N-heterocycles. Reaction of a Ru-CNN(H) complex with an excess of base produces the formation of a Ru(0) derivative, which is observed under catalytic conditions. |
Funding agencies | European Commission (EC). Fondo Europeo de Desarrollo Regional (FEDER) Ministerio de Ciencia e Innovación (MICIN). España Junta de Andalucía |
Project ID. | CTQ2016-80814-R
PY18-3208 |
Citation | Sánchez Mellado, P., Hernández Juárez, M., Rendón Márquez, N., López Serrano, J., López Santos, L., Álvarez González, E.,...,Suárez Escobar, A.L. (2020). Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands. Dalton Transactions, 49 (28), 9583-9587. https://10.1039/d0dt02326d. |
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