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Visible and NIR Light Assistance of the N2 Reduction to NH3 Catalyzed by Cs-promoted Ru Nanoparticles Supported on Strontium Titanate

dc.creatorPeng, Yonges
dc.creatorAlbero, Josepes
dc.creatorFranconetti García, Antonioes
dc.creatorConcepción, Patriciaes
dc.creatorGarcía, Hermenegildoes
dc.date.accessioned2022-06-08T10:05:09Z
dc.date.available2022-06-08T10:05:09Z
dc.date.issued2022
dc.identifier.citationPeng, Y., Albero, J., Franconetti García, A., Concepción, P. y García, H. (2022). Visible and NIR Light Assistance of the N2 Reduction to NH3 Catalyzed by Cs-promoted Ru Nanoparticles Supported on Strontium Titanate. ACS Catalysis, 12 (9), 4938-4946. https://doi.org/10.1021/acscatal.2c00509.
dc.identifier.issn2155-5435es
dc.identifier.urihttps://hdl.handle.net/11441/134205
dc.description.abstractNH3 production accounts for more than 1% of the total CO2 emissions and is considered one of the most energy-intensive industrial processes currently (T > 400 °C and P > 80 bars). The development of atmospheric-pressure N2 fixation to NH3 under mild conditions is attracting much attention, especially using additional renewable energy sources. Herein, efficient photothermal NH3 evolution in continuous flow upon visible and NIR light irradiation at near 1 Sun power using Cs-decorated strontium titanate-supported Ru nanoparticles is reported. Notably, for the optimal photocatalytic composition, a constant NH3 rate near 3500 μmolNH3 gcatalyst–1 h–1 was achieved for 120 h reactions, being among the highest values reported at atmospheric pressure under 1 Sun irradiation.es
dc.description.sponsorshipSpanish Ministry of Science and Innovation (Severo Ochoa and RTI2018-98237-CO2-1)es
dc.description.sponsorshipGeneralitat Valenciana (Prometeo 2017-083)es
dc.description.sponsorshipEuropean Union’s Horizon 2020 research and innovation programme under grant agreement no. 862453es
dc.formatapplication/pdfes
dc.language.isoenges
dc.publisherAmerican Chemical Societyes
dc.relation.ispartofACS Catalysis, 12 (9), 4938-4946.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectphotothermales
dc.subjectammonia synthesises
dc.subjectCs promoteres
dc.subjecttitanium perovskitees
dc.subjectRu nanoparticleses
dc.titleVisible and NIR Light Assistance of the N2 Reduction to NH3 Catalyzed by Cs-promoted Ru Nanoparticles Supported on Strontium Titanatees
dc.typeinfo:eu-repo/semantics/articlees
dcterms.identifierhttps://ror.org/03yxnpp24
dc.type.versioninfo:eu-repo/semantics/publishedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Química orgánicaes
dc.relation.projectIDRTI2018-98237-CO2-1es
dc.relation.projectIDPrometeo 2017-083)es
dc.relation.projectID862453es
dc.relation.publisherversionhttps://dx.doi.org/10.1021/acscatal.2c00509es
dc.identifier.doi10.1021/acscatal.2c00509es
dc.journaltitleACS Catalysises
dc.publication.volumen12es
dc.publication.issue9es
dc.publication.initialPage4938es
dc.publication.endPage4946es
dc.contributor.funderMinisterio de Ciencia e Innovación (MICIN). Españaes
dc.contributor.funderGeneralitat Valencianaes
dc.contributor.funderEuropean Union (UE). H2020es

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