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Highly enantioselective hydrogenation of 1-alkylvinyl benzoates: A simple, nonenzymatic access to chiral 2-alkanols

 

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Opened Access Highly enantioselective hydrogenation of 1-alkylvinyl benzoates: A simple, nonenzymatic access to chiral 2-alkanols
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Author: Kleman, Patryk Artur
González Liste, Pedro J.
García Garrido, Sergio E.
Cadierno, Victorio
Pizzano Mancera, Antonio
Date: 2013
Published in: Chemistry - A European Journal, 19, 16209-16212.
Document type: Article
Abstract: Going chiral! Highly enantioselective catalytic hydrogenations of enol esters 1 by using a Rh catalyst bearing a POP ligand are described (see scheme; NBD=norbornadiene). The catalytic system has a broad scope and allows the preparation of a wide range of chiral esters 2 bearing diverse alkyls or a benzyl group with high enantioselectivities. These esters can easily be converted in highly enantioenriched 2-alkanols.
Cite: Kleman, P.A., González Liste, P.J., García Garrido, S.E., Cadierno, V. y Pizzano Mancera, A. (2013). Highly enantioselective hydrogenation of 1-alkylvinyl benzoates: A simple, nonenzymatic access to chiral 2-alkanols. Chemistry - A European Journal, 19, 16209-16212.
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URI: https://hdl.handle.net/11441/70448

DOI: 10.1002/chem.201303500

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