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Highly enantioselective hydrogenation of 1-alkylvinyl benzoates: A simple, nonenzymatic access to chiral 2-alkanols

dc.creatorKleman, Patryk Artures
dc.creatorGonzález Liste, Pedro J.es
dc.creatorGarcía Garrido, Sergio E.es
dc.creatorCadierno, Victorioes
dc.creatorPizzano Mancera, Antonioes
dc.date.accessioned2018-02-20T14:30:55Z
dc.date.available2018-02-20T14:30:55Z
dc.date.issued2013
dc.identifier.citationKleman, P.A., González Liste, P.J., García Garrido, S.E., Cadierno, V. y Pizzano Mancera, A. (2013). Highly enantioselective hydrogenation of 1-alkylvinyl benzoates: A simple, nonenzymatic access to chiral 2-alkanols. Chemistry - A European Journal, 19, 16209-16212.
dc.identifier.issn0947-6539es
dc.identifier.urihttps://hdl.handle.net/11441/70448
dc.description.abstractGoing chiral! Highly enantioselective catalytic hydrogenations of enol esters 1 by using a Rh catalyst bearing a POP ligand are described (see scheme; NBD=norbornadiene). The catalytic system has a broad scope and allows the preparation of a wide range of chiral esters 2 bearing diverse alkyls or a benzyl group with high enantioselectivities. These esters can easily be converted in highly enantioenriched 2-alkanols.es
dc.description.sponsorshipMinisterio de Ciencia e Innovación CTQ2009-11867, CTQ2010-14796, CSD2007-00006es
dc.description.sponsorshipJunta de Andalucía 2008/ FQM-3830, 2009/FQM-4832es
dc.formatapplication/pdfes
dc.language.isoenges
dc.publisherJohn Wiley & Sonses
dc.relation.ispartofChemistry - A European Journal, 19, 16209-16212.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectRhodiumes
dc.subjectEnantioselectivityes
dc.subjectAsymmetric hydrogenationes
dc.subjectAlcoholses
dc.subjectEsterses
dc.titleHighly enantioselective hydrogenation of 1-alkylvinyl benzoates: A simple, nonenzymatic access to chiral 2-alkanolses
dc.typeinfo:eu-repo/semantics/articlees
dc.type.versioninfo:eu-repo/semantics/submittedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.relation.projectIDCTQ2009-11867es
dc.relation.projectIDCTQ2010-14796es
dc.relation.projectIDCSD2007-00006es
dc.relation.projectID2008/ FQM-3830es
dc.relation.projectID2009/FQM-4832es
dc.relation.publisherversionhttp://dx.doi.org/10.1002/chem.201303500es
dc.identifier.doi10.1002/chem.201303500es
idus.format.extent13 p.es
dc.journaltitleChemistry - A European Journales
dc.publication.volumen19es
dc.publication.initialPage16209es
dc.publication.endPage16212es
dc.contributor.funderMinisterio de Ciencia e Innovación (MICIN). España
dc.contributor.funderJunta de Andalucía

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