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dc.creatorKleman, Patryk Artures
dc.creatorVaquero Gutiérrez, Mónicaes
dc.creatorArribas Nieto, Inmaculadaes
dc.creatorSuárez Escobar, Andrés Luises
dc.creatorÁlvarez González, Eleuterioes
dc.creatorPizzano Mancera, Antonioes
dc.date.accessioned2018-02-06T15:49:54Z
dc.date.available2018-02-06T15:49:54Z
dc.date.issued2014
dc.identifier.citationKleman, P.A., Vaquero Gutiérrez, M., Arribas Nieto, I., Suárez Escobar, A.L., Álvarez González, E. y Pizzano Mancera, A. (2014). Asymmetric hydrogenation reactions with Rh and Ru complexes bearing phosphine-phosphites with an oxymethylene backbone. Tetrahedron Asymmetry, 25, 744-749.
dc.identifier.citationKleman, P.A., Vaquero Gutiérrez, M., Arribas Nieto, I., Suárez Escobar, A.L., Álvarez González, E. y Pizzano Mancera, A. (2014). Asymmetric hydrogenation reactions with Rh and Ru complexes bearing phosphine-phosphites with an oxymethylene backbone. Tetrahedron Asymmetry, 25, 744-749.
dc.identifier.issn1362-511Xes
dc.identifier.urihttps://hdl.handle.net/11441/70039
dc.description.abstractPhosphine-phosphites 3a and 3b, derived from diphenylhydroxymethyl phosphine have been prepared. From these ligands [Rh(COD)(3a)]BF4 5a and RuCl2(3b)[(S,S)-DPEN] 6b (DPEN = 1,2-diphenylethylenediamine) were synthesized and their structure determined by X-ray diffraction. Ligands 3 are characterized by a small bite angle of 83°. In addition, 5a led to an active catalyst for the hydrogenation of olefins, giving enantioselectivities of up to 96% ee. Likewise, compound 6b showed good activity and enantioselectivity in the hydrogenation of N-1-phenyl ethylidene aniline and a completed reaction at S/C = 500 in 24 h with 83% ee.es
dc.formatapplication/pdfes
dc.language.isoenges
dc.publisherPergamon Presses
dc.relation.ispartofTetrahedron Asymmetry, 25, 744-749.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.titleAsymmetric hydrogenation reactions with Rh and Ru complexes bearing phosphine-phosphites with an oxymethylene backbonees
dc.typeinfo:eu-repo/semantics/articlees
dcterms.identifierhttps://ror.org/03yxnpp24
dc.type.versioninfo:eu-repo/semantics/submittedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.tetasy.2014.04.001es
dc.identifier.doi10.1016/j.tetasy.2014.04.001es
idus.format.extent23 p.es
dc.journaltitleTetrahedron Asymmetryes
dc.publication.volumen25es
dc.publication.initialPage744es
dc.publication.endPage749es

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