Repositorio de producción científica de la Universidad de Sevilla

A simple, general route to 2-pyridylidene transition metal complexes

 

Advanced Search
 
Opened Access A simple, general route to 2-pyridylidene transition metal complexes
Cites

Show item statistics
Icon
Export to
Author: Roselló Merino, Marta
Díez, Josefina
Conejero Iglesias, Salvador
Department: Universidad de Sevilla. Departamento de Química Inorgánica
Date: 2010-11-04
Document type: Article
Abstract: Pyridinium 2-carboxylates decompose thermally in the presence of a variety of late transition metal precursors to yield the corresponding 2-pyridylidene-like complexes. The mild reaction conditions and structural diversity that can be generated in the heterocyclic ring make this method an attractive alternative for the synthesis of 2-pyridylidene complexes. IR spectra of the Ir(I) carbonyl compounds [IrCl(NHC)(CO)2] indicate that these N-heterocyclic carbene ligands are among the strongest σ-electron donors.
Size: 118.9Kb
Format: PDF

URI: http://hdl.handle.net/11441/68072

DOI: 10.1039/C0CC03935G

See editor´s version

This work is under a Creative Commons License: 
Attribution-NonCommercial-NoDerivatives 4.0 Internacional

This item appears in the following Collection(s)