dc.creator | Roselló Merino, Marta | es |
dc.creator | Díez, Josefina | es |
dc.creator | Conejero Iglesias, Salvador | es |
dc.date.accessioned | 2017-12-29T09:28:06Z | |
dc.date.available | 2017-12-29T09:28:06Z | |
dc.date.issued | 2010-11-04 | |
dc.identifier.citation | Roselló Merino, M., Díez, J. y Conejero Iglesias, S. (2010). A simple, general route to 2-pyridylidene transition metal complexes. Chemical Communications, 46 (48), 9247-9249. | |
dc.identifier.issn | 1359-7345 (impreso) | es |
dc.identifier.uri | http://hdl.handle.net/11441/68072 | |
dc.description.abstract | Pyridinium 2-carboxylates decompose thermally in the presence of a variety of late transition metal precursors to yield the corresponding 2-pyridylidene-like complexes. The mild reaction conditions and structural diversity that can be generated in the heterocyclic ring make this method an attractive alternative for the synthesis of 2-pyridylidene complexes. IR spectra of the Ir(I) carbonyl compounds [IrCl(NHC)(CO)2] indicate that these N-heterocyclic carbene ligands are among the strongest σ-electron donors. | es |
dc.description.sponsorship | Junta de Andalucía FQM-3151 | es |
dc.description.sponsorship | Ministerio de Ciencia e Innovación CTQ2007-62814, CONSOLIDER-INGENIO 2010 CSD2007-00006 | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Royal Society of Chemistry (Great Britain) | es |
dc.relation.ispartof | Chemical Communications, 46 (48), 9247-9249. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | N-heterocyclic carbenes | es |
dc.subject | Nitrogen | es |
dc.subject | C-H activation | es |
dc.subject | Pyridinium salts | es |
dc.subject | NMR spectroscopy | es |
dc.subject | X-ray crystallography | es |
dc.subject | Electron donors | es |
dc.title | A simple, general route to 2-pyridylidene transition metal complexes | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/acceptedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | FQM-3151 | es |
dc.relation.projectID | CTQ2007-62814 | es |
dc.relation.projectID | CSD2007-00006 | es |
dc.relation.publisherversion | http://dx.doi.org/10.1039/C0CC03935G | es |
dc.identifier.doi | 10.1039/C0CC03935G | es |
idus.format.extent | 3 p. | es |
dc.journaltitle | Chemical Communications | es |
dc.publication.volumen | 46 | es |
dc.publication.issue | 48 | es |
dc.publication.initialPage | 9247 | es |
dc.publication.endPage | 9249 | es |
dc.contributor.funder | Junta de Andalucía | |
dc.contributor.funder | Ministerio de Ciencia e Innovación (MICIN). España | |