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1,2,3-Triazoles from carbonyl azides and alkynes: filling the gap

 

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Author: Haldón, Estela
Álvarez González, Eleuterio
Nicasio Jaramillo, María del Carmen
Pérez, Pedro J.
Department: Universidad de Sevilla. Departamento de Química Inorgánica
Date: 2014
Published in: Chemical Communications, 50, 8978-8981.
Document type: Article
Abstract: Electron deficient azides are challenging substrates in CuAAC reactions. Particularly, when N-carbonyl azides are applied the formation of N-carbonyl triazoles has not yet been observed. We report herein the first example of this class of reaction, with a copper-based system that efficiently enables the synthesis of N-carbamoyl 1,2,3-triazoles by [3+2] cycloaddition of N-carbamoyl azides and alkynes
Cite: Haldón, E., Álvarez, E., Nicasio, M.C. y Pérez, P.J. (2014). 1,2,3-Triazoles from carbonyl azides and alkynes: filling the gap. Chemical Communications, 50, 8978-8981.
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URI: http://hdl.handle.net/11441/64411

DOI: 10.1039/c4cc03614j

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