Repositorio de producción científica de la Universidad de Sevilla

Synthesis, characterisation and crystal structure of a three-dimensional network of an h-bonded Ni (II) Hexametylenetetramine complex

 

Advanced Search
 

Show simple item record

dc.creator Agwara, Moise O.
dc.creator Ndifon, Peter T.
dc.creator Yufanyi, Mbom D.
dc.creator Tendo, Josepha N. Foba
dc.creator Atamba, Moses A.
dc.creator Awawou, Paboudam G.
dc.creator Galindo del Pozo, Agustín
dc.creator Álvarez González, Eleuterio
dc.date.accessioned 2015-08-31T07:04:21Z
dc.date.available 2015-08-31T07:04:21Z
dc.date.issued 2010
dc.identifier.issn 0974-1496 es
dc.identifier.other RJCABP
dc.identifier.uri http://hdl.handle.net/11441/28098
dc.description.abstract A three-dimensional network of H-bonding nickel (II) hexamethylenetetramine complex has been synthesized and characterised and its structure determined by single crystal X-ray diffraction studies which show that [Ni(H2O)6](HMTA)2Cl32.4H2O crystallizes in the triclinic crystal system with space group PĪ, a = 9.2955(4), b = 9.3187(2), c = 9.3996 Ǻ, α = 119.4160(10), β = 94.4940(10), ɣ = 100.8680(10)º, V =682.47(4) Å3 and z = 1. The nickel atoms are each bonded to six aquo ligands giving an octahedral geometry. The ligand hexamethylenetetramine (HMTA) and chloride ions are bonded to water molecules through hydrogen bonding. Thermal studies show a decomposition pattern corresponding to the loss of the coordinated and uncoordinated water molecules, chloride ions and HMTA ligand in the form of a mixture of gases. es
dc.format application/pdf es
dc.language.iso eng es
dc.publisher Royal Society of Chemistry es
dc.relation.ispartof Rasayan Journal of Chemistry, 3(2), 207-213 es
dc.rights Attribution-NonCommercial-NoDerivatives 4.0 Internacional *
dc.rights.uri http://creativecommons.org/licenses/by-nc-nd/4.0/ *
dc.subject Nickel es
dc.subject Hexamethylenetetramine es
dc.subject Chloride es
dc.subject Complexes es
dc.subject X-ray es
dc.subject Structure es
dc.subject Thermal es
dc.subject Spectroscopy studies es
dc.title Synthesis, characterisation and crystal structure of a three-dimensional network of an h-bonded Ni (II) Hexametylenetetramine complex es
dc.type info:eu-repo/semantics/article es
dc.type.version info:eu-repo/semantics/publishedVersion
dc.rights.accessrights info:eu-repo/semantics/openAccess es
dc.contributor.affiliation Universidad de Sevilla. Departamento de Química Inorgánica es
dc.contributor.affiliation Universidad de Sevilla. Departamento de Química Orgánica es
dc.relation.publisherversion http://rasayanjournal.co.in/vol-3/issue-2/2.pdf es
dc.identifier.idus https://idus.us.es/xmlui/handle/11441/28098
Size: 409.4Kb
Format: PDF

This item appears in the following Collection(s)

Show simple item record