Listar Artículos (Instituto de Investigaciones Químicas (IIQ) – CIC Cartuja) por título
Mostrando ítems 22-41 de 284
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Antioxidant activity of alkyl gallates and glycosyl alkyl gallates in fish oil in water emulsions: Relevance of their surface active properties and of the type of emulsifier
(Elsevier, 2015)The antioxidant activity of gallic acid and a series of alkyl gallates (C4-C18) and glycosylated alkyl gallates (C4-C18) ...
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ARL15 modulates magnesium homeostasis through N-glycosylation of CNNMs
(Springer, 2021)Cyclin M (CNNM1-4) proteins maintain cellular and body magnesium (Mg2+) homeostasis. Using various biochemical approaches, ...
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Asymmetric Hydrogenation of 1-alkyl and 1-aryl vinyl benzoates: a broad scope procedure for the highly enantioselective synthesis of 1-substituted ethyl benzoates
(2014)The enantioselective hydrogenation of enol esters of formula CH2=C(OBz)R with rhodium catalysts based on phosphine-phosphite ...
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Asymmetric hydrogenation reactions with Rh and Ru complexes bearing phosphine-phosphites with an oxymethylene backbone
(Pergamon Press, 2014)Phosphine-phosphites 3a and 3b, derived from diphenylhydroxymethyl phosphine have been prepared. From these ligands ...
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Asymmetric organocatalytic Strecker-type reactions of aliphatic N,N-dialkylhydrazones
(Royal Society of Chemistry (Great Britain), 2013)The enantioselective organocatalytic Strecker-type reaction of aliphatic N,N-dialkylhydrazones is presented. Using ...
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Asymmetric Organocatalytic Synthesis of Fluorinated β-Hydroxy Diazenes
(Wiley-Blackwell, 2019)The nucleophilic addition of formaldehyde tert-butyl hydrazone to fluoromethyl ketones provides a valuable tool for the ...
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Asymmetric organocatalytic synthesis of tertiary azomethyl alcohols: key intermediates towards azoxy compounds and α-hydroxy-β-amino esters
(Royal Society of Chemistry (Great Britain), 2017)A series of peracylated glycosamine-derived thioureas have been synthesized and their behavior as bifunctional organocatalysts ...
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Atroposelective Synthesis of 2-(Quinolin-8-yl)benzyl Alcohols by Biocatalytic Dynamic Kinetic Resolutions
(Wiley, 2023-12-22)A highly enantioselective biocatalytic dynamic kinetic resolution (DKR) of 2-(quinoline-8-yl) 3-methylbenzaldehydes and ...
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AuI-Catalyzed Haloalkynylation of Alkenes
(Wiley-Blackwell, 2020)The formal insertion of alkenes into aromatic chloro- and bromoalkynes takes place under cationic gold catalysis. This ...
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AuI-Catalyzed Hydroalkynylation of Haloalkynes
(American Chemical Society, 2020)The AuI-catalyzed reaction between terminal alkynes and aromatic haloalkynes proceeds through divergent pathways depending ...
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Axially Chiral Triazoloisoquinolin-3-ylidene Ligands in Gold(I)-catalyzed Asymmetric Intermolecular (4 + 2) Cycloadditions of Allenamides and Dienes
(American Chemical Society, 2012)The first highly enantioselective intermolecular (4 + 2) cycloaddition between allenes and dienes is reported. The reaction ...
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Base-Promoted, Remote C−H Activation at a Cationic (η5 ‑C5Me5)Ir(III) Center Involving Reversible C−C Bond Formation of Bound C5Me5
(American Chemical Society, 2019)C-H bond activation at cationic [(η5-C5Me5)Ir(PMe2Ar')] centers is described, where PMe2Ar' are the terphenyl phosphine ...
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Bifunctional Squaramide Organocatalysts for the Asymmetric Addition of Formaldehyde tert-Butylhydrazone to Simple Aldehydes
(Wiley-Blackwell, 2018)The nucleophilic addition of formaldehyde tert-butylhydrazone to simple aldehydes (a formal hetero-carbonyl–ene reaction) ...
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Biodegradable particles for protein delivery: estimation of the release kinetics inside cells
(Elsevier, 2022-08)A methodology to quantify the efficiency of the protein loading and in-vitro delivery for biodegradable capsules with ...
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Biological Evaluation of Carbohydrate-based Aprepitant Analogs for Neuroblastoma Treatment
(Elsevier, 2024)Different studies using Aprepitant, a NK1R antagonist currently used as a clinical drug for treating chemotherapy-related ...
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Biophysics and protein corona analysis of Janus cyclodextrin-DNA nanocomplexes. Efficient cellular transfection on cancer cells
(Elsevier, 2017)The self-assembling processes underlining the capabilities of facially differentiated (¿Janus¿) polycationic amphiphilic ...
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Bonding Situation of σ-E−H Complexes in Transition Metal and Main Group Compounds
(Wiley-Blackwell, 2022)The ambiguous bonding situation of σ-E−H (E=Si, B) complexes in transition metal compounds has been rationalized by means ...
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Boryl-assisted hydrogenolysis of a nickel–methyl bond
(Royal Society of Chemistry (Great Britain), 2014)A stable Nickel(II) methyl complex containing a diphosphinoboryl (PBP) pincer ligand is described. Mechanistic studies on ...
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Broad Scope Synthesis of Ester Precursors of Nonfunctionalized Chiral Alcohols Based on the Asymmetric Hydrogenation of α,β-Dialkyl-, α,β-Diaryl-, and α-Alkyl-β-aryl-vinyl Esters
(American Chemical Society, 2017)The catalytic asymmetric hydrogenation of trisubstituted enol esters using Rh catalysts bearing chiral phosphine-phosphite ...
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Catalytic amine-borane dehydrogenation by a PCP-pincer palladium complex: A combined experimental and DFT analysis of the reaction mechanism
(Royal Society of Chemistry (Great Britain), 2013)Catalytic dehydrogenation of ammonia-borane (NH3·BH 3, AB) and dimethylamine borane (NHMe2·BH 3, DMAB) by the PdII complex ...