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dc.creatorMiranda Pizarro, Juanes
dc.creatorGonzález Alférez, Macarenaes
dc.creatorFernández Martínez, María Doloreses
dc.creatorÁlvarez González, Eleuterioes
dc.creatorMaya Díaz, Celia Maríaes
dc.creatorCampos Manzano, Jesúses
dc.date.accessioned2020-06-22T15:49:30Z
dc.date.available2020-06-22T15:49:30Z
dc.date.issued2020
dc.identifier.citationMiranda Pizarro, J., González Alférez, M., Fernández Martínez, M.D., Álvarez González, E., Maya Díaz, C.M. y Campos Manzano, J. (2020). A versatile approach to access trimetallic complexes based on trisphosphinite ligands. Molecules, 25 (3), 593.
dc.identifier.issn1420-3049es
dc.identifier.urihttps://hdl.handle.net/11441/98114
dc.description.abstractA straightforward method for the preparation of trisphosphinite ligands in one step, using only commercially available reagents (1,1,1-tris(4-hydroxyphenyl)ethane and chlorophosphines) is described. We have made use of this approach to prepare a small family of four trisphosphinite ligands of formula [CH3C{(C6H4OR2)3], where R stands for Ph (1a), Xyl (1b, Xyl = 2,6-Me2-C6H3), iPr (1c), and Cy (1d). These polyfunctional phosphinites allowed us to investigate their coordination chemistry towards a range of late transition metal precursors. As such, we report here the isolation and full characterization of a number of Au(I), Ag(I), Cu(I), Ir(III), Rh(III) and Ru(II) homotrimetallic complexes, including the structural characterization by X-ray diffraction studies of six of these compounds. We have observed that the flexibility of these trisphosphinites enables a variety of conformations for the different trimetallic species.es
dc.description.sponsorshipEuropean Research Council 756575es
dc.description.sponsorshipMinisterio de Ciencia, Innovación y Universidades CTQ2017-92622-EXPes
dc.formatapplication/pdfes
dc.format.extent16 p.es
dc.language.isoenges
dc.publisherMultidisciplinary Digital Publishing Institute (MDPI)es
dc.relation.ispartofMolecules, 25 (3), 593.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectCoordination polymeres
dc.subjectMultidentate ligandses
dc.subjectPhosphinitees
dc.subjectPolymetallices
dc.subjectSupramolecular chemistryes
dc.subjectTrimetallices
dc.titleA versatile approach to access trimetallic complexes based on trisphosphinite ligandses
dc.typeinfo:eu-repo/semantics/articlees
dcterms.identifierhttps://ror.org/03yxnpp24
dc.type.versioninfo:eu-repo/semantics/publishedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Química Inorgánicaes
dc.relation.projectID756575es
dc.relation.projectIDCTQ2017-92622-EXPes
dc.relation.publisherversionhttps://doi.org/10.3390/molecules25030593es
dc.identifier.doi10.3390/molecules25030593es
dc.journaltitleMoleculeses
dc.publication.volumen25es
dc.publication.issue3es
dc.publication.initialPage593es

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