dc.creator | Miranda Pizarro, Juan | es |
dc.creator | González Alférez, Macarena | es |
dc.creator | Fernández Martínez, María Dolores | es |
dc.creator | Álvarez González, Eleuterio | es |
dc.creator | Maya Díaz, Celia María | es |
dc.creator | Campos Manzano, Jesús | es |
dc.date.accessioned | 2020-06-22T15:49:30Z | |
dc.date.available | 2020-06-22T15:49:30Z | |
dc.date.issued | 2020 | |
dc.identifier.citation | Miranda Pizarro, J., González Alférez, M., Fernández Martínez, M.D., Álvarez González, E., Maya Díaz, C.M. y Campos Manzano, J. (2020). A versatile approach to access trimetallic complexes based on trisphosphinite ligands. Molecules, 25 (3), 593. | |
dc.identifier.issn | 1420-3049 | es |
dc.identifier.uri | https://hdl.handle.net/11441/98114 | |
dc.description.abstract | A straightforward method for the preparation of trisphosphinite ligands in one step, using only commercially available reagents (1,1,1-tris(4-hydroxyphenyl)ethane and chlorophosphines) is described. We have made use of this approach to prepare a small family of four trisphosphinite ligands of formula [CH3C{(C6H4OR2)3], where R stands for Ph (1a), Xyl (1b, Xyl = 2,6-Me2-C6H3), iPr (1c), and Cy (1d). These polyfunctional phosphinites allowed us to investigate their coordination chemistry towards a range of late transition metal precursors. As such, we report here the isolation and full characterization of a number of Au(I), Ag(I), Cu(I), Ir(III), Rh(III) and Ru(II) homotrimetallic complexes, including the structural characterization by X-ray diffraction studies of six of these compounds. We have observed that the flexibility of these trisphosphinites enables a variety of conformations for the different trimetallic species. | es |
dc.description.sponsorship | European Research Council 756575 | es |
dc.description.sponsorship | Ministerio de Ciencia, Innovación y Universidades CTQ2017-92622-EXP | es |
dc.format | application/pdf | es |
dc.format.extent | 16 p. | es |
dc.language.iso | eng | es |
dc.publisher | Multidisciplinary Digital Publishing Institute (MDPI) | es |
dc.relation.ispartof | Molecules, 25 (3), 593. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Coordination polymer | es |
dc.subject | Multidentate ligands | es |
dc.subject | Phosphinite | es |
dc.subject | Polymetallic | es |
dc.subject | Supramolecular chemistry | es |
dc.subject | Trimetallic | es |
dc.title | A versatile approach to access trimetallic complexes based on trisphosphinite ligands | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | 756575 | es |
dc.relation.projectID | CTQ2017-92622-EXP | es |
dc.relation.publisherversion | https://doi.org/10.3390/molecules25030593 | es |
dc.identifier.doi | 10.3390/molecules25030593 | es |
dc.journaltitle | Molecules | es |
dc.publication.volumen | 25 | es |
dc.publication.issue | 3 | es |
dc.publication.initialPage | 593 | es |