Article
Effect of thermal treatments on the catalytic behaviour in the CO preferential oxidation of a CuO-CeO2-ZrO2 catalyst with a flower-like morphology
Author/s | Moretti, Elisa
Storaro, Loretta Talon, Aldo Lenarda, Maurizio Riello, Piero Frattini, Romana Martínez de Yuso, María del Valle Jiménez López, Antonio Rodríguez Castellón, Enrique Ternero Fernández, Fátima ![]() ![]() ![]() ![]() ![]() ![]() ![]() Caballero Martínez, Alfonso ![]() ![]() ![]() ![]() ![]() ![]() ![]() Holgado Vázquez, Juan Pedro |
Department | Universidad de Sevilla. Departamento de Química Inorgánica Universidad de Sevilla. Departamento de Ingeniería y Ciencia de los Materiales y del Transporte |
Publication Date | 2011 |
Deposit Date | 2019-02-11 |
Published in |
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Abstract | A Ce-Zr-Cu oxide system with a flower-like morphology was prepared by a slow co-precipitation method in the absence of any structure directing agent. Four portions of the oxide were thermally treated at four different ... A Ce-Zr-Cu oxide system with a flower-like morphology was prepared by a slow co-precipitation method in the absence of any structure directing agent. Four portions of the oxide were thermally treated at four different temperatures (350°C, 450°C, 550°C, 650°C). The resulting materials samples were characterized by quantitative XRD, adsorption-desorption of N2 at-196°C, SEM and TEM microscopy, -H2-TPR, XPS and Operando-XANES. All samples were tested in the preferential CO oxidation (CO-PROX) in the 40-190°C temperature range. Thermal treatments were found to induce slight structural changes without altering the starting morphology of the samples. The samples treated at higher temperature 550-650°C showed a quite interesting CO-PROX activity and selectivity in a temperature range suitable for a practical use within the FEMFC technology. |
Citation | Moretti, E., Storaro, L., Talon, A., Lenarda, M., Riello, P., Frattini, R.,...,Holgado Vázquez, J.P. (2011). Effect of thermal treatments on the catalytic behaviour in the CO preferential oxidation of a CuO-CeO2-ZrO2 catalyst with a flower-like morphology. Applied Catalysis B: Environmental, 102, 627-637. |
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