NameCaballero Martínez, Alfonso
DepartmentQuímica Inorgánica
Knowledge areaQuímica Inorgánica
Professional categoryCatedrático de Universidad
E-mailRequest
           
  • No. publications

    29

  • No. visits

    2729

  • No. downloads

    3250


 

Article
Icon

Surface Defect Engineered Nano-Cu/TiO2 Photocatalysts for Hydrogen Production

Liccardo, Letizia; Moras, Paolo; Sheverdyaeva, Polina M.; Vomiero, Alberto; Caballero Martínez, Alfonso; Colón, Gerardo (Wiley-V C H Verlag GMBH, 2023)
Surface defects engineered nano-Cu/TiO2 photocatalysts are synthesized through an easy and cost-effective microwave-assisted ...
PhD Thesis
Icon

Optimización de sistemas catalíticos de co activos para la síntesis de Fischer-Tropsch: efecto de la adición de un segundo metal, la estructuración del soporte y el anclaje del metal a la superficie

Platero Moreno, Francisco Jesús; Caballero Martínez, Alfonso; Colón Ibáñez, Gerardo (2023)
La actual situación energética mundial se encuentra en una clara etapa de transición. Actualmente el petróleo sigue siendo ...
Article
Icon

Catalytic performance of cobalt supported onto APTES functionalized TiO2 for Fischer-Tropsch reaction

Platero Moreno, Francisco Jesús; Caballero Martínez, Alfonso; Colón Ibáñez, Gerardo (Science, 2023)
Cobalt supported TiO2 catalysts have been prepared by wet-impregnation and by immobilization over APTES (3-aminopropyl ...
Article
Icon

Methanation of CO2 over High Surface Nickel/Aluminates Compounds Prepared by a Self-Generated Carbon Template

Roudane, Sarra; Bettahar, Noureddin; Caballero Martínez, Alfonso; Holgado, Juan Pedro (Multidisciplinary Digital Publishing Institute (MDPI), 2023)
Catalytic gas-phase hydrogenation of CO2 into CH4 was tested under three different nickel/aluminate catalysts obtained ...
Article
Icon

Cobalt Stabilization through Mesopore Confinement on TiO2 Support for Fischer−Tropsch Reaction

Platero Moreno, Francisco Jesús; Todorova, S.; Aoudjera, L.; Michelin, L.; Lebeau, B.; Blin, J. L.; Holgado, J.P.; Caballero Martínez, Alfonso; Colón, G. (American Chemical Society, 2023)
Cobalt supported on mesostructured TiO2 catalysts has been prepared by a wet-impregnation method. The Co/TiO2 catalytic ...
PhD Thesis
Article
Icon

Characterization of Re-Mo/ZSM-5 Catalysts: How Re Improves the Performance of Mo in the Methane Dehydroaromatization Reaction

López Martín, Angeles María; Sini, M. F.; Cutrufello, M. G.; Caballero Martínez, Alfonso; Colón, G. (Elsevier, 2022)
In this study, the promoting effect of rhenium addition as a co-dopant on Mo/ZSM-5 catalysts system has been analysed. ...
Article
Icon

Unraveling the Mo/HZSM-5 Reduction Pre-treatment Effect on Methane Dehydroaromatization Reaction

López Martín, Ángeles María; Caballero Martínez, Alfonso; Colón, Gerardo (Elsevier, 2022)
Reduction pre-treatment at different temperatures were performed over Mo/HZSM-5 system before methane dehydroaromatiztion ...
Article
Icon

Tuning the co-catalyst loading for the optimization of thermo-photocatalytic hydrogen production over Cu/TiO2

Platero Moreno, Francisco Jesús; Caballero Martínez, Alfonso; Colón Ibáñez, Gerardo (Elsevier, 2022)
We have optimized the H2 production by methanol thermo-photocatalytic reforming in the gas phase using Cu/TiO2 catalyst ...
Article
Icon

Elucidating the Promotional Effect of Cerium in the Dry Reforming of Methane

Rodríguez Gómez, Alberto; López Martín, Ángeles; Ramírez, Adrián; Gascón, Jorge; Caballero Martínez, Alfonso (Wiley-Blackwell, 2021)
A series of Ni-Ce catalysts supported on SBA-15 has been prepared by co-impregnation, extensively characterized and evaluated ...
Article
Icon

Support Effects on NiO-based Catalysts for the Oxidative Dehydrogenation (ODH) of Ethane

Delgado, D.; Sanchís, R.; Cecilia, J. A.; Caballero Martínez, Alfonso; Solsona, B.; López Nieto, J. M. (Elsevier, 2019)
We report on the effect of NiO-support interactions on the chemical nature of Ni species in a series of supported NiO ...
PhD Thesis
Icon

Desarrollo de sistemas catalíticos mesoporosos nanoestructurados para la producción de hidrógeno y la síntesis directa de agua oxigenada.

Rodríguez Gómez, Alberto; Caballero Martínez, Alfonso; Pereñíguez Rodríguez, Rosa María (2018)
En las últimas décadas, el desarrollo de sistemas nanoparticulados y su uso como catalizadores ha supuesto un gran avance ...
Article
Icon

Revealing the substitution mechanism in Eu3+:CaMoO4 and Eu3+,Na+:CaMoO4 phosphors

Becerro Nieto, Ana Isabel; Allix, Mathieu; Laguna Moreno, Mariano; González Mancebo, Daniel; Genevois, Cecile; Caballero Martínez, Alfonso; Lozano Suárez, Juan Gabriel; Núñez Álvarez, Nuria Ofelia; Ocaña Jurado, Manuel (Royal Society of Chemistry, 2018)
Eu3+-Doped calcium molybdate is an excellent phosphor for lighting and display devices due to the very intense pure red ...
Article
Icon

Nickel Particles Selectively Confined in the Mesoporous Channels of SBA-15 Yielding a Very Stable Catalyst for DRM Reaction

Rodríguez Gómez, Alberto; Pereñíguez Rodríguez, Rosa María; Caballero Martínez, Alfonso (American Chemical Society, 2018)
A series of four Ni catalysts supported on SBA-15 and on a high SiO2 surface area have been prepared by modified impregnation ...
Article
Icon

Bimetallic Ni-Co/SBA-15 catalysts for reforming of ethanol: How cobalt modifies the nickel metal phase and product distribution

Rodríguez Gómez, Alberto; Caballero Martínez, Alfonso (Elsevier, 2018)
In this study, five mono and bimetallic xNi-(10-x)Co/SBA-15 catalysts (x = 10, 8, 5, 2 and 0, with a total metallic content ...
Article
Icon

Preferential oxidation of CO on a La-Co-Ru perovskite-type oxide catalyst

Pereñíguez Rodríguez, Rosa María; Caballero Martínez, Alfonso; Ferri, Davide (Elsevier, 2017)
A Ru-containing perovskite-type oxide La(Co,Ru)O3 of nominal composition LaCo0.8Ru0.2O3 was prepared by ultrasonic spray ...
Article
Icon

Understanding the differences in catalytic performance for hydrogen production of Ni and Co supported on mesoporous SBA-15

Rodríguez Gómez, Alberto; Pereñíguez Rodríguez, Rosa María; Caballero Martínez, Alfonso (Elsevier, 2017)
Three mono and bimetallic Nix Co1−x /SBA-15 catalysts (x = 1, 0.5 and 0) with a total metallic content of 10 wt% have been ...
Article
Icon

Structural and chemical reactivity modifications of a cobalt perovskite induced by Sr-substitution. An in situ XAS study

Hueso Martos, José Luis; Holgado Vázquez, Juan Pedro; Pereñíguez Rodríguez, Rosa María; González de la Cruz, Víctor Manuel; Caballero Martínez, Alfonso (Elsevier, 2015)
LaCoO3 and La0.5Sr0.5CoO3-δ perovskites have been studied by in situ Co K-edge XAS. Although the partial substitution of ...
Article
Icon

Preparation of nanostructured nickel aluminate spinel powder from spent NiO/Al2O3 catalyst by mechano-chemical synthesis

Nazemi, M. K.; Sheibani, S.; Rashchi, F.; González de la Cruz, Víctor Manuel; Caballero Martínez, Alfonso (Brill Academic Publishers, 2012)
In this paper, the possibility of mechano-chemical synthesis, as a single step process for preparation of nanostructured ...
Article
Icon

Influence of Al2O3 reinforcement on precipitation kinetic of Cu-Cr nanocomposite

Sheibani, S.; Ataie, A.; Heshmati-Manesh, S.; Caballero Martínez, Alfonso; Criado Luque, José Manuel (Elsevier, 2011)
In this paper, the kinetic of precipitation process in mechanically alloyed Cu-1 wt.% Cr and Cu-1 wt.% Cr/3 wt.% Al2O3 ...
Article
Icon

Effect of thermal treatments on the catalytic behaviour in the CO preferential oxidation of a CuO-CeO2-ZrO2 catalyst with a flower-like morphology

Moretti, Elisa; Storaro, Loretta; Talon, Aldo; Lenarda, Maurizio; Riello, Piero; Frattini, Romana; Martínez de Yuso, María del Valle; Jiménez López, Antonio; Rodríguez Castellón, Enrique; Ternero Fernández, Fátima; Caballero Martínez, Alfonso; Holgado Vázquez, Juan Pedro (Elsevier, 2011)
A Ce-Zr-Cu oxide system with a flower-like morphology was prepared by a slow co-precipitation method in the absence of any ...
Article
Icon

Room-temperature reaction of oxygen with gold: An in situ ambient-pressure x-ray photoelectron spectroscopy investigation

Jiang, Peng; Porsgaard, Soeren; Borondics, Ferenc; Kober, Mariana; Caballero Martínez, Alfonso; Bluhm, Hendrik; Besenbacher, Flemming; Salmeron, Miquel (American Chemical Society, 2010)
(Figure Presented) The interaction of O2 with gold foil and gold nanoparticles grown by thermal deposition on TiO2(110) ...
Article
Icon

In situ spectroscopic detection of SMSI effect in a Ni/CeO2 system: Hydrogen-induced burial and dig out of metallic nickel

Caballero Martínez, Alfonso; Holgado, Juan Pedro; González de la Cruz, Víctor M.; Habas, Susan E.; Herranz, Tirma; Salmeron, Miquel (Royal Society of Chemistry, 2010)
In situ APPES technique demonstrates that the strong metal support interaction effect (SMSI) in the Ni-ceria system is ...
Article
Icon

Operando XAS and Raman study on the structure of a supported vanadium oxide catalyst during the oxidation of H2S to sulphur

Holgado Vázquez, Juan Pedro; Soriano, M. D.; Jiménez-Jiménez, J.; Concepción, P.; Jiménez-López, A.; Caballero Martínez, Alfonso; Rodríguez-Castellón, E.; López Nieto, J.M. (Elsevier, 2010)
The modification of crystalline phases of a vanadium oxide supported on mesoporous zirconium phosphate during the partial ...
Article
Icon

Near-ambient X-ray photoemission spectroscopy and kinetic approach to the mechanism of carbon monoxide oxidation over lanthanum substituted cobaltites

Hueso Martos, José Luis; Martínez Martínez, D.; Caballero Martínez, Alfonso; Rodríguez González-Elipe, Agustín; Mun, B. S.; Salmeron, Miquel (Elsevier, 2009)
We have studied the oxidation of carbon monoxide over a lanthanum substituted perovskite (La0.5Sr0.5CoO3-d) catalyst ...
PhD Thesis
Icon

Estudio de sistemas catalíticos basados en zro2, para la reducción catalítica selectiva de nox, usando hidrocarburos como agentes reductores

Cordón Rodríguez, Ana María; Caballero Martínez, Alfonso; Holgado Vázquez, Juan Pedro (2006)
PhD Thesis
IconIcon

Estudio del sistema CuOx/ZrO2 en procesos de eliminación catalítica de óxidos de nitrógeno

Morales Domingo, José Jorge; Caballero Martínez, Alfonso; Espinós Manzorro, Juan Pedro (2005)
En el presente capítulo se ha intentado reflejar el amplio marco de técnicas y procesos químicos existentes para el ...
Article
Icon

Reforming of ethanol in a microwave surface-wave plasma discharge

Yanguas Gil, Alejandro; Hueso Martos, José Luis; Cotrino Bautista, José; Caballero Martínez, Alfonso; Rodríguez González-Elipe, Agustín (American Institute of Physics, 2004)
Hydrogen production through plasma reforming of ethanol at room temperature and moderate pressure has been carried out in ...
PhD Thesis
Icon

Efecto del Cloro en la formación de fases mixtas PtRe en catalizadores de reformado PtRe/Al2O3

Caballero Martínez, Alfonso; Munuera Contreras, Guillermo; Malet Maenner, María Pilar (1991)
El presente estudio se ha centrado, fundamentalmente, en la caracterización de las fases existentes en diversos caralizadores ...