dc.creator | Ramírez-López, Pedro | es |
dc.creator | Ros, Abel | es |
dc.creator | Romero Arenas, Antonio | es |
dc.creator | Iglesias Sigüenza, Francisco Javier | es |
dc.creator | Fernández Fernández, Rosario Fátima | es |
dc.creator | Lassaletta, José M. | es |
dc.date.accessioned | 2018-06-20T08:39:21Z | |
dc.date.available | 2018-06-20T08:39:21Z | |
dc.date.issued | 2016 | |
dc.identifier.citation | Ramírez-López, P., Ros, A., Romero-Arenas, A., Iglesias Sigüenza, F.J., Fernández, R. y Lassaletta, J.M. (2016). Synthesis of IAN-type N,N-Ligands via Dynamic Kinetic Asymmetric Buchwald-Hartwig Amination. Journal of the American Chemical Society, 138 (37), 12053-12056. | |
dc.identifier.issn | 0002-7863 (impreso) | es |
dc.identifier.issn | 1520-5126 (electrónico) | es |
dc.identifier.uri | https://hdl.handle.net/11441/76328 | |
dc.description.abstract | The Pd-catalyzed coupling of racemic heterobiaryl bromides, triflates, or nonaflates with aryl/alkyl primary amines using QUINAP as the ligand provides the corresponding axially chiral heterobiaryl amines with excellent yields and enantioselectivities. Reactivity and structural studies of neutral and cationic oxidative addition intermediates support a dynamic kinetic asymmetric amination mechanism based on the labilization of the stereogenic axis in the latter and suggest that coordination of the amine to the Pd center is the stereodetermining step. | es |
dc.description.sponsorship | Ministerio de Ciencia e Innovación CTQ2013-48164-C2-1-P, CTQ2013-48164-C2-2-P, RYC-2013-12585 for A.R. | es |
dc.description.sponsorship | European FEDER Funds | es |
dc.description.sponsorship | Junta de Andalucía 2012/FQM 10787 | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | American Chemical Society | es |
dc.relation.ispartof | Journal of the American Chemical Society, 138 (37), 12053-12056. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Synthesis of IAN-type N,N-Ligands via Dynamic Kinetic Asymmetric Buchwald-Hartwig Amination | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/acceptedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Orgánica | es |
dc.relation.publisherversion | http://dx.doi.org/10.1021/jacs.6b07972 | es |
dc.identifier.doi | 10.1021/jacs.6b07972 | es |
idus.format.extent | 5 | es |
dc.journaltitle | Journal of the American Chemical Society | es |
dc.publication.volumen | 138 | es |
dc.publication.issue | 37 | es |
dc.publication.initialPage | 12053 | es |
dc.publication.endPage | 12056 | es |