dc.creator | Kleman, Patryk Artur | es |
dc.creator | Vaquero Gutiérrez, Mónica | es |
dc.creator | Arribas Nieto, Inmaculada | es |
dc.creator | Suárez Escobar, Andrés Luis | es |
dc.creator | Álvarez González, Eleuterio | es |
dc.creator | Pizzano Mancera, Antonio | es |
dc.date.accessioned | 2018-02-06T15:49:54Z | |
dc.date.available | 2018-02-06T15:49:54Z | |
dc.date.issued | 2014 | |
dc.identifier.citation | Kleman, P.A., Vaquero Gutiérrez, M., Arribas Nieto, I., Suárez Escobar, A.L., Álvarez González, E. y Pizzano Mancera, A. (2014). Asymmetric hydrogenation reactions with Rh and Ru complexes bearing phosphine-phosphites with an oxymethylene backbone. Tetrahedron Asymmetry, 25, 744-749. | |
dc.identifier.citation | Kleman, P.A., Vaquero Gutiérrez, M., Arribas Nieto, I., Suárez Escobar, A.L., Álvarez González, E. y Pizzano Mancera, A. (2014). Asymmetric hydrogenation reactions with Rh and Ru complexes bearing phosphine-phosphites with an oxymethylene backbone. Tetrahedron Asymmetry, 25, 744-749. | |
dc.identifier.issn | 1362-511X | es |
dc.identifier.uri | https://hdl.handle.net/11441/70039 | |
dc.description.abstract | Phosphine-phosphites 3a and 3b, derived from diphenylhydroxymethyl phosphine have been prepared. From these ligands [Rh(COD)(3a)]BF4 5a and RuCl2(3b)[(S,S)-DPEN] 6b (DPEN = 1,2-diphenylethylenediamine) were synthesized and their structure determined by X-ray diffraction. Ligands 3 are characterized by a small bite angle of 83°. In addition, 5a led to an active catalyst for the hydrogenation of olefins, giving enantioselectivities of up to 96% ee. Likewise, compound 6b showed good activity and enantioselectivity in the hydrogenation of N-1-phenyl ethylidene aniline and a completed reaction at S/C = 500 in 24 h with 83% ee. | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Pergamon Press | es |
dc.relation.ispartof | Tetrahedron Asymmetry, 25, 744-749. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Asymmetric hydrogenation reactions with Rh and Ru complexes bearing phosphine-phosphites with an oxymethylene backbone | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/submittedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.relation.publisherversion | http://dx.doi.org/10.1016/j.tetasy.2014.04.001 | es |
dc.identifier.doi | 10.1016/j.tetasy.2014.04.001 | es |
idus.format.extent | 23 p. | es |
dc.journaltitle | Tetrahedron Asymmetry | es |
dc.publication.volumen | 25 | es |
dc.publication.initialPage | 744 | es |
dc.publication.endPage | 749 | es |