Artículo
Nickel-based cerium zirconate inorganic complex structures for CO2 valorisation via dry reforming of methane
Autor/es | Martín Espejo, Juan Luis
Merkouri, Loukia Pantzechroula Gándara Loe, Jesús Odriozola Gordón, José Antonio Ramírez Reina, Tomás Pastor Pérez, Laura |
Departamento | Universidad de Sevilla. Departamento de Química Inorgánica |
Fecha de publicación | 2023-01-16 |
Fecha de depósito | 2024-05-28 |
Publicado en |
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Resumen | The increasing anthropogenic emissions of greenhouse gases (GHG) is encouraging extensive research in CO2 utilisation. Dry reforming of methane (DRM) depicts a viable strategy
to convert both CO2 and CH4 into syngas, a ... The increasing anthropogenic emissions of greenhouse gases (GHG) is encouraging extensive research in CO2 utilisation. Dry reforming of methane (DRM) depicts a viable strategy to convert both CO2 and CH4 into syngas, a worthwhile chemical intermediate. Among the different active phases for DRM, the use of nickel as catalyst is economically favourable, but typically deactivates due to sintering and carbon deposition. The stabilisation of Ni at different loadings in cerium zirconate inorganic complex structures is investigated in this work as strategy to develop robust Ni-based DRM catalysts. XRD and TPR-H2 analyses confirmed the existence of different phases according to the Ni loading in these materials. Besides, superficial Ni is observed as well as the existence of a CeNiO3 perovskite structure. The catalytic activity was tested, proving that 10 wt.% Ni loading is the optimum which maximises conversion. This catalyst was also tested in long-term stability experiments at 600 and 800°C in order to study the potential deactivation issues at two different temperatures. At 600°C, carbon formation is the main cause of catalytic deactivation, whereas a robust stability is shown at 800°C, observing no sintering of the active phase evidencing the success of this strategy rendering a new family of economically appealing CO2 and biogas mixtures upgrading catalysts. |
Agencias financiadoras | Ministerio de Ciencia e Innovación (MICIN). España |
Identificador del proyecto | PID2019-108502RJ-I00
IJC2019-040560-I RYC2018-024387-I |
Cita | Martín Espejo, J.L., Merkouri, L.P., Gándara Loe, J., Odriozola Gordón, J.A., Ramírez Reina, T. y Pastor Pérez, L. (2023). Nickel-based cerium zirconate inorganic complex structures for CO2 valorisation via dry reforming of methane. Journal of Environmental Sciences-China, 140, 12-23. https://doi.org/10.1016/j.jes.2023.01.022. |
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Nickel-based cerium.pdf | 2.683Mb | [PDF] | Ver/ | |