NameRamírez Reina, Tomás
DepartmentQuímica Inorgánica
Knowledge areaQuímica Inorgánica
Professional categoryProfesor Titular de Universidad
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Water-assisted HDO of biomass model compounds enabled by Ru-based catalysts

Carrasco Ruiz, Sergio; Parrilla Lahoz, Silvia; Santos, José Luis; Penkova, Anna Dimitrova; Odriozola Gordón, José Antonio; Ramírez Reina, Tomás; Pastor Pérez, Laura (Elsevier Ltd., 2023)
Biofuels upgrading gathering momentum in view of the gradual depletion of fossil fuels and the pursuit of renewable energy ...
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H2-rich syngas production from biogas reforming: overcoming coking and sintering using bimetallic Ni-based catalysts

Carrasco Ruiz, Sergio; Zhang, Qi; Gándara Loe, Jesús; Pastor Pérez, Laura; Odriozola Gordón, José Antonio; Ramírez Reina, Tomás; Bobadilla Baladrón, Luis Francisco (Elsevier Ltd, 2023)
Dry reforming of methane is a very appealing catalytic route biogas (mainly composed by greenhouse gases: carbon dioxide ...
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Flexible NiRu Systems for CO2 Methanation: From Efficient Catalysts to Advanced Dual-Function Materials

Merkouri, Loukia Pantzechroula; Martín Espejo, Juan Luis; Bobadilla Baladrón, Luis Francisco; Odriozola Gordón, José Antonio; Duyar, Melis Seher; Ramírez Reina, Tomás (Multidisciplinary Digital Publishing Institute (MDPI), 2023)
CO2 emissions in the atmosphere have been increasing rapidly in recent years, causing global warming. CO2 methanation ...
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Multicomponent Graphene Based Catalysts for Guaiacol Upgrading in Hydrothermal Conditions: Exploring "H2-free" Alternatives for Bio-compounds Hydrodeoxygenation

Parrilla Lahoz, Silvia; Jin, W.; Pastor Pérez, Laura; Duyar, M. S.; Martínez Quintana, Laura; Dongil, A. B.; Ramírez Reina, Tomás (Elsevier, 2023)
Catalytic hydrodeoxygenation (HDO) is a critical technique for upgrading biomass derivatives to deoxygenated fuels or other ...
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Hydrogen production from landfill biogas: Profitability analysis of a real case study

Vidal Barrero, Fernando; Baena Moreno, Francisco Manuel; Preciado-Cárdenas, Christian; Villanueva Perales, Ángel Luis; Ramírez Reina, Tomás (Elsevier, 2022)
Hydrogen is not only considered as a cornerstone within renewable energy portfolio but it is also a key enabler for CO2 ...
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Recent advances on gas-phase CO2 conversion: Catalysis design and chemical processes to close the carbon cycle

Torres Sempere, Guillermo; Pastor Pérez, Laura; Odriozola Gordón, José Antonio; Durán Olivencia, Francisco José; Bobadilla Baladrón, Luis Francisco; Ramírez Reina, Tomás (Elsevier, 2022)
Chemical CO2 recycling in the gas phase constitutes a straightforward approach for effective CO2 conversion to added-value ...
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Biogas upgrading to biomethane as a local source of renewable energy to power light marine transport: Profitability analysis for the county of Cornwall

González Arias, Judith; Baena-Moreno, Francisco M.; Pastor Pérez, Laura; Sebastia Saez, Daniel; Gallego Fernández, Luz Marina; Ramírez Reina, Tomás (Elsevier, 2022)
In this work, the use of biomethane produced from local biogas plants is proposed as renewable fuel for light marine ...
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Insights on Guerbet Reaction: Production of Biobutanol From Bioethanol Over a Mg–Al Spinel Catalyst

Portillo Crespo, María de los Ángeles; Vidal Barrero, Fernando; Azancot Luque, Lola de las Aguas; Ramírez Reina, Tomás; Campoy Naranjo, Manuel (Frontiers, 2022)
The production of biobutanol from bioethanol by the Guerbet reaction is an alternative pathway to renewable sources. The ...
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Sustainable routes for acetic acid production: Traditional processes vs a low-carbon, biogas-based strategy

Martín Espejo, Juan Luis; Gandara Loe, Jesús; Odriozola Gordón, José Antonio; Ramírez Reina, Tomás; Pastor Pérez, Laura (Elsevier, 2022)
The conversion of biogas, mainly formed of CO2 and CH4, into high-value platform chemicals is increasing attention in a ...
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Catalytic Upgrading of Biomass-Gasification Mixtures Using Ni-Fe/MgAl2O4 as a Bifunctional Catalyst

Tarifa, Pilar; Ramírez Reina, Tomás; González Castaño, Míriam; Arellano García, Harvey (American Chemical Society, 2022)
Biomass gasification streams typically contain a mixture of CO, H2, CH4, and CO2 as the majority components and frequently ...
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Emerging natural and tailored perovskite-type mixed oxides–based catalysts for CO2 conversions

Wu, Jun; Ye, Runping; Xu, Dong-Jie; Wan, Lingzhong; Ramírez Reina, Tomás; Sun, Hui (Frontiers Media, 2022)
The rapid economic and societal development have led to unprecedented energy demand and consumption resulting in the harmful ...
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Analysis of Dry Reforming as direct route for gas phase CO2 conversion. The past, the present and future of catalytic DRM technologies

Le Saché, Estelle; Ramírez Reina, Tomás (Elsevier, 2022)
Transition to low carbon societies requires advanced catalysis and reaction engineering to pursue green routes for fuels ...
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Electrocatalytic CO2 conversion to C2 products: catalysts design, market perspectives and techno-economic aspects

Ruiz López, Estela; Gándara Loe, Jesús; Baena Moreno, Francisco Manuel; Ramírez Reina, Tomás; Odriozola Gordón, José Antonio (Elsevier, 2022)
The energy crisis caused by the incessant growth in global energy demand joint to its associated greenhouse emissions ...
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Feasibility of switchable dual function materials as a flexible technology for CO2 capture and utilisation and evidence of passive direct air capture

Merkouri, Loukia Pantzechroula; Ramírez Reina, Tomás; Duyar, Melis Seher (Royal Society of Chemistry, 2022)
The feasibility of a Dual Function Material (DFM) with a versatile catalyst offering switchable chemical synthesis from ...
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Ni-Phosphide catalysts as versatile systems for gas-phase CO2 conversion: Impact of the support and evidences of structure-sensitivity

Zhang, Qiang; Pastor Pérez, Laura; Villora Pico, J. J.; Joyce, M.; Sepúlveda Escribano, Antonio; Duyar, Melis S.; Ramírez Reina, Tomás (Elsevier, 2022)
We report for the first time the support dependent activity and selectivity of Ni-rich nickel phosphide catalysts for CO2 ...
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Materials challenges and opportunities to address growing micro/nanoplastics pollution: a review of thermochemical upcycling

Parrilla Lahoz, Silvia; Mahebadevan, S.; Kauta, M.; Zambrano, Marielis C.; Pawlak, Joel J.; Venditti, Richard A.; Ramírez Reina, Tomás; Duyar, Melis Seher (Elsevier, 2022)
Micro/nanoplastics have sparked attention in recent years due to their widespread presence in the environment. Currently, ...
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Editorial: Catalysis in Iberoamerica: Recent Trends

Arcelus Arrillaga, Pedro; Ramírez Reina, Tomás; Álvarez Moreno, Andrea; Ivanova, Svetlana (Frontiers Media, 2022)
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Versatile Ni-Ru catalysts for gas phase CO2 conversion: Bringing closer dry reforming, reverse water gas shift and methanation to enable end-products flexibility

Merkouri, Loukia Pantzechroula; Le Saché, Estelle; Pastor Pérez, Laura; Duyar, Melis S.; Ramírez Reina, Tomás (Elsevier, 2022)
Advanced catalytic materials able to catalyse more than one reaction efficiently are needed within the CO2 utilisation ...
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Development of Power-to-X Catalytic Processes for CO2 Valorisation: From the Molecular Level to the Reactor Architecture

Bobadilla Baladrón, Luis Francisco; Azancot Luque, Lola de las Aguas; Luque Álvarez, Ligia Amelia; Torres Sempere, Guillermo; González Castaño, Míriam; Pastor Pérez, Laura; Ramírez Reina, Tomás; Ivanova, Svetlana; Odriozola Gordón, José Antonio (Multidisciplinary Digital Publishing Institute (MDPI), 2022)
Nowadays, global climate change is likely the most compelling problem mankind is facing. In this scenario, decarbonisation ...
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Catalytic Converters for Vehicle Exhaust: Fundamental Aspects and Technology Overview for Newcomers to the Field

Kritsanaviparkporn, Emmy; Baena-Moreno, Francisco M.; Ramírez Reina, Tomás (MDPI, 2021)
This works aims to provide an understanding on basic chemical kinetics pertaining to three-way catalytic (TWC) converters ...
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From biogas upgrading to CO2 utilization and waste recycling: A novel circular economy approach

Baena Moreno, Francisco Manuel; Le Saché, Estelle; Price, Cameron A. H.; Ramírez Reina, Tomás; Navarrete Rubia, Benito (Elsevier, 2021)
Herein a novel process to synergize biogas upgrading, CO2 utilization and waste recycling is proposed. Our study emerges ...
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Synergizing carbon capture and utilization in a biogas upgrading plant based on calcium chloride: Scaling-up and profitability analysis

Baena-Moreno, Francisco M.; Ramírez Reina, Tomás; Rodríguez Galán, Mónica; Navarrete Rubia, Benito; Vilches Arenas, Luis Francisco (Elsevier, 2021)
Herein we analyze the profitability of a novel regenerative process to synergize biogas upgrading and carbon dioxide ...
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K-Promoted Ni-Based Catalysts for Gas-Phase CO2 Conversion: Catalysts Design and Process Modelling Validation

Gandara Loe, Jesús; Portillo Estévez, Esmeralda; Odriozola Gordón, José Antonio; Ramírez Reina, Tomás; Pastor Pérez, Laura (Frontiers Media, 2021)
The exponential growth of greenhouse gas emissions and their associated climate change problems have motivated the development ...
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Biogas Conversion to Syngas Using Advanced Ni-Promoted Pyrochlore Catalysts: Effect of the CH4/CO2 Ratio

Le Saché, Estelle; Alvarez Moreno, Andrea; Ramírez Reina, Tomás (Frontiers Media, 2021)
Biogas is defined as the mixture of CH4 and CO2 produced by the anaerobic digestion of biomass. This particular mixture ...
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In-situ HDO of guaiacol over nitrogen-doped activated carbon supported nickel nanoparticles

Jin, Wei; Pastor Pérez, Laura; Villora Picó, Juan J.; Pastor Blas, M. Mercedes; Odriozola Gordón, José Antonio; Sepúlveda Escribano, Antonio; Ramírez Reina, Tomás (Elsevier, 2021)
In-situ hydrodeoxygenation of guaiacol over Ni-based nitrogen-doped activated carbon supported catalysts is presented in ...
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Bimetallic Ni–Ru and Ni–Re Catalysts for Dry Reforming of Methane: Understanding the Synergies of the Selected Promoters

Álvarez Moreno, Andrea; Ramírez Reina, Tomás; Ivanova, Svetlana; Roger, Anne Cécile; Centeno Gallego, Miguel Ángel; Odriozola Gordón, José Antonio (Frontiers Media, 2021)
Designing an economically viable catalyst that maintains high catalytic activity and stability is the key to unlock dry ...
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Analysis of the potential for biogas upgrading to syngas via catalytic reforming in the United Kingdom

Baena-Moreno, Francisco M.; Sebastia Saez, Daniel; Pastor Pérez, Laura; Ramírez Reina, Tomás (Elsevier Ltd, 2021)
The UK faces unprecedented environmental challenges which require urgent action. The promotion of renewable energy sources ...
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Cost-effective routes for catalytic biomass upgrading

Jin, W.; Pastor Pérez, Laura; Yu, Jie; Odriozola Gordón, José Antonio; Gu, S.; Ramírez Reina, Tomás (Elsevier B.V., 2020)
Catalytic hydrodeoxygenation (HDO) is a fundamental and promising route for bio-oil upgrading to produce petroleum-like ...
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Flexible syngas production using a La2Zr2-xNixO7-δ pyrochlore-double perovskite catalyst: Towards a direct route for gas phase CO2 recycling

Le Saché, Estelle; Pastor Pérez, Laura; Garcilaso, Victoria; Watson, D. J.; Centeno Gallego, Miguel Ángel; Odriozola Gordón, José Antonio; Ramírez Reina, Tomás (Elsevier, 2020)
The bi-reforming of methane (BRM) has the advantage of utilising greenhouse gases and producing H2 rich syngas. In this ...
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Editorial: Catalysis by Gold for Gas & Liquid Phase Reactions: A Golden Future for Environmental Catalysis

Ramírez Reina, Tomás; Liu, Jian; Ivanova, Svetlana (Frontiers Media, 2020)
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Dry reforming of ethanol and glycerol: Mini-review

Yu, Jie; Odriozola Gordón, José Antonio; Ramírez Reina, Tomás (Multidisciplinary Digital Publishing Institute (MDPI), 2019)
Dry reforming of ethanol and glycerol using CO2 are promising technologies for H2 production while mitigating CO2 emission. ...
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Au/CeO2-ZnO/Al2O3 as Versatile Catalysts for Oxidation Reactions: Application in Gas/Liquid Environmental Processes

Megías Sayago, Cristina; Ramírez Reina, Tomás; Ivanova, Svetlana; Odriozola Gordón, José Antonio (Frontiers Media, 2019)
The present work showcases the versatility of nanogold systems supported on Zn-doped ceria when applied in two important ...
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Carbon Supported Gold Nanoparticles for the Catalytic Reduction of 4-Nitrophenol

Rodríguez Molina, Hugo; Santos Muñoz, José Luis; Domínguez Leal, María Isabel; Ramírez Reina, Tomás; Ivanova, Svetlana; Centeno Gallego, Miguel Ángel; Odriozola Gordón, José Antonio (Frontiers Media, 2019)
This work is a detailed study on how to optimize gold colloids preparation and their deposition to very different in nature ...
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Physicochemical comparison of precipitated calcium carbonate for different configurations of a biogas upgrading unit

Baena Moreno, Francisco Manuel; Price, Cameron A. H.; Le Saché, Estelle; Pastor Pérez, Laura; Sebastiá Sáez, Daniel; Ramírez Reina, Tomás (Wiley, 2019)
BACKGROUND:Thispaperpresentsaphysicochemicalcomparisonofthesolidproductsobtainedfromtwoalternativeprocessesthatrecyclewa ...
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The Success Story of Gold-Based Catalysts for Gas- and Liquid-Phase Reactions: A Brief Perspective and Beyond

Price, Cameron A. H.; Pastor Pérez, Laura; Ivanova, Svetlana; Ramírez Reina, Tomás; Liu, Jian (Frontiers Media, 2019)
Gold has long held the fascination of mankind. For millennia it has found use in art, cosmetic metallurgy and architecture; ...
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Chemical CO2 recycling via dry and bi reforming of methane using Ni-Sn/ Al2O3 and Ni-Sn/CeO2-Al2O3 catalysts

Stroud, T.; Smith, T.J.; Santos Muñoz, José Luis; Centeno Gallego, Miguel Ángel; Ramírez Reina, Tomás (Elsevier, 2018)
Carbon formation and sintering remain the main culprits regarding catalyst deactivation in the dry and bireforming of ...
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Multicomponent Ni-CeO2 nanocatalysts for syngas production from CO2/CH4 mixtures

Le Saché, Estelle; Santos Muñoz, José Luis; Smith, T.J.; Centeno Gallego, Miguel Ángel; Arellano García, H.; Odriozola Gordón, José Antonio; Ramírez Reina, Tomás (Elsevier, 2018)
The dry reforming of methane with CO2 is a common route to transform CO2/CH4 mixtures into added value syngas. Ni based ...
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Regeneration of Sodium Hydroxide from a Biogas Upgrading Unit through the Synthesis of Precipitated Calcium Carbonate: An Experimental Influence Study of Reaction Parameters

Baena-Moreno, Francisco M.; Rodríguez Galán, Mónica; Vega Borrero, Fernando; Ramírez Reina, Tomás; Vilches Arenas, Luis Francisco; Navarrete Rubia, Benito (MDPI, 2018)
This article presents a regeneration method of a sodium hydroxide (NaOH) solution from a biogas upgrading unit through ...
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Multicomponent Au/Cu-ZnO-Al2O3 catalysts: Robust materials for clean hydrogen production

Santos Muñoz, José Luis; Ramírez Reina, Tomás; Ivanov, I.; Penkova, Anna Dimitrova; Ivanova, Svetlana; Tabakova, T.; Centeno Gallego, Miguel Ángel; Idakiev, Vasko; Odriozola Gordón, José Antonio (Elsevier, 2018)
Clean hydrogen production via WGS is a key step in the development of hydrogen fuel processors. Herein, we have designed ...
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Au/CeO2 catalysts: structure and CO oxidation activity

Centeno Gallego, Miguel Ángel; Ramírez Reina, Tomás; Ivanova, Svetlana; Laguna Espitia, Oscar Hernando; Odriozola Gordón, José Antonio (Multidisciplinary Digital Publishing Institute (MDPI), 2016)
In this comprehensive review, the main aspects of using Au/CeO2 catalysts in oxidation reactions are considered. The ...
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O2-assisted Water Gas Shift reaction over structured Au and Pt catalysts

González Castaño, Míriam; Ramírez Reina, Tomás; Ivanova, Svetlana; Martínez Tejada, Leidy Marcela; Centeno Gallego, Miguel Ángel; Odriozola Gordón, José Antonio (Elsevier, 2016)
Platinum and gold structured catalysts were compared as active phases in classical and O2-assisted Water Gas Shift (WGS) ...
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Nanogold mesoporous iron promoted ceria catalysts for total and preferential CO oxidation reactions

Odriozola Gordón, José Antonio; Zhong-Yong Yuan; Qing-Fang Deng; Centeno Gallego, Miguel Ángel; Tobacova, Tatyana; Idakiev, Vasko; Ivanova, Svetlana; Ramírez Reina, Tomás (Elsevier, 2016)
Herein, a series of highly efficient gold based catalysts supported on mesoporous CeO2-Fe2O3 mixed oxides for CO elimination ...
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WGS and CO-PrOx reactions using gold promoted copper-ceria catalysts: “bulk CuO-CeO2 vs. CuO-CeO2/Al2O3 with low mixed oxide content”

Ramírez Reina, Tomás; Ivanova, Svetlana; Laguna Espitia, Oscar Hernando; Centeno Gallego, Miguel Ángel; Odriozola Gordón, José Antonio (Elsevier, 2016)
A copper-ceria bulk catalyst has been compared to a series of catalysts designed according to the as called “supported ...
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The role of Au, Cu & CeO2 and their interactions for an enhanced WGS performance

Ramírez Reina, Tomás; Ivanova, Svetlana; Centeno Gallego, Miguel Ángel; Odriozola Gordón, José Antonio (Elsevier, 2016)
The WGS reaction over multicomponent Au/Ce1-xCuxO2/Al2O3 catalysts is studied in this work. The systems are carefully ...
Chapter of Book
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Development of robust mixed-conducting membranes with high permeability and stability

Ramírez Reina, Tomás; Santos, José Luis; García Moncada, Nuria; Ivanova, Svetlana; Odriozola Gordón, José Antonio; Granger, Pascual (Wiley, 2015)
This chapter presents an illustration of the current state of the art in the development of mechanically and chemically ...
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H2 oxidation as criterion for PrOx catalyst selection: Examples based on Au-CoOx-supported systems

Ramírez Reina, Tomás; Megías Sayago, Cristina; Pérez Flórez, Alejandro; Ivanova, Svetlana; Centeno Gallego, Miguel Ángel; Odriozola Gordón, José Antonio (Elsevier, 2015)
A new approach for understanding PrOx reaction over gold catalysts is proposed in this work. The competition between H2 ...
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Boosting the activity of a Au/CeO2/Al2O3 catalyst for the WGS reaction

Centeno Gallego, Miguel Ángel; Odriozola Gordón, José Antonio; Ivanova, Svetlana; Ramírez Reina, Tomás (Elsevier, 2015)
Herein a strategy to design highly efficient Au/CeO2/Al2O3 based WGS catalysts is proposed. The inclusion of transition ...
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Ni-CeO2/C Catalysts with Enhanced OSC for the WGS Reaction

Pastor Pérez, Laura; Ramírez Reina, Tomás; Ivanova, Svetlana; Centeno Gallego, Miguel Ángel; Odriozola Gordón, José Antonio; Sepúlveda Escribano, Antonio (MDPI AG, 2015)
In this work, the WGS performance of a conventional Ni/CeO2 bulk catalyst is compared to that of a carbon-supported Ni-CeO2 ...
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Mono and bimetallic Cu-Ni structured catalysts for the water gas shift reaction

Arbeláez, O.; Ramírez Reina, Tomás; Ivanova, Svetlana; Bustamante, F.; Villa, A. L.; Centeno Gallego, Miguel Ángel; Odriozola Gordón, José Antonio (Elsevier, 2015)
The water-gas shift (WGS) reaction over structured Cu, Ni, and bimetallic Cu-Ni supported on active carbon (AC) catalysts ...
PhD Thesis
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Diseño y caracterización de catalizadores en oro para la reacción de water gas shift reaction

Ramírez Reina, Tomás; Odriozola Gordón, José Antonio; Ivanova, Svetlana (2014)
1. Introducción y Objetivo La protección del medio ambiente es uno de los principales problemas a los que se enfrenta el ...
Patent. Invention
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Catalizadores de oro y uso del mismo para la reacción de desplazamiento del gas del agua

Odriozola Gordón, José Antonio; Ramírez Reina, Tomás; Centeno Gallego, Miguel Ángel; Yubomirova Ivanova, , Svetlana; Danailov Idakiev, Vasko; Todorova Tabakova,Tatyana (Oficina Española de Patentes y Marcas (OEPM), 2014)
La presente invención tiene por objeto un soporte para catalizador de oro, de fórmula CeO2 MOx/Al2O3, donde el soporte comprende ...
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Pt vs. Au in water-gas shift reaction

González Castaño, Míriam; Ramírez Reina, Tomás; Ivanova, Svetlana; Centeno Gallego, Miguel Ángel; Odriozola Gordón, José Antonio (Elsevier, 2014)
This work presents a comparison of the gold- and platinum-based catalysts behavior in the water-gas shift (WGS) reaction. ...
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Could an efficient WGS catalyst be useful in the CO-PrOx reaction?

Ramírez Reina, Tomás; Papadopoulos, E.; Palma del Valle, Sandra; Ivanova, Svetlana; Centeno Gallego, Miguel Ángel; Ioannides, T.; Odriozola Gordón, José Antonio (Elsevier, 2014)
This work presents an evaluation of a high performance series of water gas shift (WGS) catalysts in the preferential CO ...
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Low-temperature CO oxidation on multicomponent gold based catalysts

Ramírez Reina, Tomás; Ivanova, Svetlana; Centeno Gallego, Miguel Ángel; Odriozola Gordón, José Antonio (Frontiers Media S.A, 2013)
In this work the development of gold catalysts, essentially based on γ-alumina with small superficial fraction of Ce-Fe ...
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Sub-ambient CO oxidation over Au/MO x/CeO 2-Al 2O 3 (M = Zn or Fe)

Ramírez Reina, Tomás; Ivanova, Svetlana; Centeno Gallego, Miguel Ángel; Odriozola Gordón, José Antonio (Elsevier, 2012)
A series of ZnO and Fe 2O 3 modified ceria/alumina supports and their corresponding gold catalyst were prepared and studied ...
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Influence of Vanadium or Cobalt Oxides on the CO Oxidation Behavior of Au/MO x/CeO 2-Al 2O 3 Systems

Ramírez Reina, Tomás; Álvarez Moreno, Andrea; Ivanova, Svetlana; Odriozola Gordón, José Antonio; Centeno Gallego, Miguel Ángel (John Wiley & Sons, 2012)
A series of V 2O 5- and Co 3O 4-modified ceria/alumina supports and their corresponding gold catalysts were synthesized ...
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Editorial: Catalytic materials and processes for a low-carbon future

Gandara Loe, Jesús; Ramírez Reina, Tomás; Pastor Pérez, Laura (Frontiers Media, 2002)