Artículo
Palladium-mediated Intramolecular Dearomatization of Ligated Dialkylterphenyl Phosphines
Autor/es | Jiménez Rama, Raquel
Maya Díaz, Celia María Nicasio Jaramillo, María del Carmen |
Departamento | Universidad de Sevilla. Departamento de Química Inorgánica |
Fecha de publicación | 2019 |
Fecha de depósito | 2023-03-06 |
Publicado en |
|
Resumen | Aryl-Pd(ii) chlorides stabilized by dialkylterphenyl phosphine ligands undergo a thermal isomerization process, leading to the formation of allyl-Pd(ii)-chloride species. The transformation involves the intramolecular ... Aryl-Pd(ii) chlorides stabilized by dialkylterphenyl phosphine ligands undergo a thermal isomerization process, leading to the formation of allyl-Pd(ii)-chloride species. The transformation involves the intramolecular functionalization of a C-H bond of the terphenyl group mediated by the Pd(ii) center. |
Agencias financiadoras | Ministerio de Ciencia, Innovación y Universidades (MICINN). España |
Identificador del proyecto | CTQ2017-82893-C2-2-R |
Cita | Jiménez Rama, R., Maya Díaz, C.M. y Nicasio Jaramillo, M.d.C. (2019). Palladium-mediated Intramolecular Dearomatization of Ligated Dialkylterphenyl Phosphines. Dalton Transactions, 48 (39), 14575-14579. https://doi.org/10.1039/c9dt03201k. |
Ficheros | Tamaño | Formato | Ver | Descripción |
---|---|---|---|---|
Palladium-Mediated Intramolecu ... | 937.9Kb | [PDF] | Ver/ | |