Article
Palladium-mediated Intramolecular Dearomatization of Ligated Dialkylterphenyl Phosphines
Author/s | Jiménez Rama, Raquel
Maya Díaz, Celia María Nicasio Jaramillo, María del Carmen |
Department | Universidad de Sevilla. Departamento de Química Inorgánica |
Publication Date | 2019 |
Deposit Date | 2023-03-06 |
Published in |
|
Abstract | Aryl-Pd(ii) chlorides stabilized by dialkylterphenyl phosphine ligands undergo a thermal isomerization process, leading to the formation of allyl-Pd(ii)-chloride species. The transformation involves the intramolecular ... Aryl-Pd(ii) chlorides stabilized by dialkylterphenyl phosphine ligands undergo a thermal isomerization process, leading to the formation of allyl-Pd(ii)-chloride species. The transformation involves the intramolecular functionalization of a C-H bond of the terphenyl group mediated by the Pd(ii) center. |
Funding agencies | Ministerio de Ciencia, Innovación y Universidades (MICINN). España |
Project ID. | CTQ2017-82893-C2-2-R |
Citation | Jiménez Rama, R., Maya Díaz, C.M. y Nicasio Jaramillo, M.d.C. (2019). Palladium-mediated Intramolecular Dearomatization of Ligated Dialkylterphenyl Phosphines. Dalton Transactions, 48 (39), 14575-14579. https://doi.org/10.1039/c9dt03201k. |
Files | Size | Format | View | Description |
---|---|---|---|---|
Palladium-Mediated Intramolecu ... | 937.9Kb | [PDF] | View/ | |