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Coinage metal complexes bearing fluorinated N-Heterocyclic carbene ligands

dc.creatorDelgado Rebollo, Manuelaes
dc.creatorGarcía Morales, Cristinaes
dc.creatorMaya Díaz, Celia Maríaes
dc.creatorPrieto Cárdenas, María Auxiliadoraes
dc.creatorEchavarren, Antonio M.es
dc.creatorPérez, Pedro J.es
dc.date.accessioned2023-01-30T18:28:58Z
dc.date.available2023-01-30T18:28:58Z
dc.date.issued2019
dc.identifier.citationDelgado Rebollo, M., García Morales, C., Maya Díaz, C.M., Prieto Cárdenas, M.A., Echavarren, A.M. y Pérez, P.J. (2019). Coinage metal complexes bearing fluorinated N-Heterocyclic carbene ligands. Journal of Organometallic Chemistry, 898, 120856. https://doi.org/10.1016/j.jorganchem.2019.07.007.
dc.identifier.issn0022-328Xes
dc.identifier.urihttps://hdl.handle.net/11441/142172
dc.description.abstractThe synthesis of novel fluorinated symmetrical and unsymmetrical imidazolium salts as well as their corresponding coinage metal complexes is described. The silver derivatives were prepared using Ag2O as the metal source and the subsequent (NHC)AgX complexes were successfully employed in the preparation of the corresponding Cu(I) and Au(I) complexes through transmetallation reactions. Halide extrusion from (NHC)AuCl complexes in the presence of labile ligands also allowed the isolation of Au(I) cationic complexes [(NHC)Au(L)]X. The molecular structures of relevant examples of the neutral and ionic complexes have been unambiguously determined by X-ray studies.es
dc.description.sponsorshipAgencia Estatal de Investigación CTQ2017-82893-C2-1-R, CTQ2016- 75960-P, CTQ2016-81923-REDCes
dc.description.sponsorshipAgencia de Gestión de Ayudas Universitarias y de Investigación 2017 SGR 1257es
dc.formatapplication/pdfes
dc.format.extent13 p.es
dc.language.isoenges
dc.publisherElsevieres
dc.relation.ispartofJournal of Organometallic Chemistry, 898, 120856.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectCopper carbenees
dc.subjectFluorinated N-Heterocyclic carbeneses
dc.subjectGold carbenees
dc.subjectNeutral and cationic complexeses
dc.subjectSilver carbenees
dc.titleCoinage metal complexes bearing fluorinated N-Heterocyclic carbene ligandses
dc.typeinfo:eu-repo/semantics/articlees
dcterms.identifierhttps://ror.org/03yxnpp24
dc.type.versioninfo:eu-repo/semantics/acceptedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Química Inorgánicaes
dc.relation.projectIDCTQ2017-82893-C2-1-Res
dc.relation.projectIDCTQ2016- 75960-Pes
dc.relation.projectIDCTQ2016-81923-REDCes
dc.relation.projectID2017 SGR 1257es
dc.relation.publisherversionhttps://doi.org/10.1016/j.jorganchem.2019.07.007es
dc.identifier.doi10.1016/j.jorganchem.2019.07.007es
dc.journaltitleJournal of Organometallic Chemistryes
dc.publication.volumen898es
dc.publication.initialPage120856es
dc.contributor.funderAgencia Estatal de Investigación. Españaes
dc.contributor.funderAgencia de Gestión de Ayudas Universitarias y de Investigaciónes

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