Article
Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2, 2 ':6 ', 2''-terpyridine
Author/s | Paneque Sosa, Margarita
López Poveda, Manuel Vattier Lagarrigue, María Florencia ![]() ![]() ![]() ![]() ![]() Álvarez González, Eleuterio Carmona Guzmán, Ernesto |
Department | Universidad de Sevilla. Departamento de Química Inorgánica |
Date | 2009 |
Published in |
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Abstract | Thermal activation of terpyridine in the presence of an
unsaturated Ir(III) fragment stabilized by a hydrotris(pyrazolyl)
borate ligand gives rise to mononuclear complex 2 and binuclear
3, in which the polypyridine ... Thermal activation of terpyridine in the presence of an unsaturated Ir(III) fragment stabilized by a hydrotris(pyrazolyl) borate ligand gives rise to mononuclear complex 2 and binuclear 3, in which the polypyridine behaves, respectively, as a mono- or a bi-dentate N-heterocyclic carbene. |
Citation | Paneque Sosa, M., López Poveda, M., Vattier Lagarrigue, M.F., Álvarez González, E. y Carmona Guzmán, E. (2009). Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2, 2 ':6 ', 2''-terpyridine. Chemical Communications, 5561, 1-3. https://doi.org/10.1039/B909837B. |
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