dc.creator | Odriozola Gordón, José Antonio | es |
dc.creator | Centeno Gallego, Miguel Ángel | es |
dc.date.accessioned | 2022-09-27T11:53:15Z | |
dc.date.available | 2022-09-27T11:53:15Z | |
dc.date.issued | 2019 | |
dc.identifier.citation | Odriozola Gordon, J.A. y Centeno Gallego, M.Á. (2019). Effect of starch as binder in carbon aerogel and carbon xerogel preparation. Journal of Non-Crystalline Solids, 522, 119554. | |
dc.identifier.issn | 0022-3093 | es |
dc.identifier.issn | 1873-4812 | es |
dc.identifier.uri | https://hdl.handle.net/11441/137397 | |
dc.description.abstract | Carbon aerogels and carbon xerogels were synthesized through resorcinol – formaldehyde polycondensation
using Na2CO3 as catalyst. The effect of soluble starch introduction in the organic gel preparation on the porous
surface properties of these materials was studied. The role of the drying process of the organic gels on the
changes in the surface and structural properties of these materials after the addition of soluble starch is dis-
cussed. The presence of starch in the prepared carbon xerogels results in the development of microporosity while
maintaining the characteristic mesoporosity of carbon xerogels. The Brunauer – Emmett -Teller (BET) surface
area increases from 309 m2/g in carbon xerogel without soluble starch until 685 m2/g when 10% of soluble
starch is added. The R- value and average crystallite lattice parameters, inter-layer spacing, crystallite height,
crystallite diameter and the average number of aromatic layers per carbon crystallite are discussed in function of
drying step and presence of soluble starch. The surface properties were also studied by Raman and DRIFT
spectroscopies | es |
dc.description.sponsorship | Ministerio de Educación y Competitividad de España (MINECO) y Fondos FEDER de la Unión Europea-ENE2013-47880-C3-2-R y ENE2017-82451-C3-3-R | es |
dc.format | application/pdf | es |
dc.format.extent | 9 p. | es |
dc.language.iso | eng | es |
dc.publisher | Elsevier | es |
dc.relation.ispartof | Journal of Non-Crystalline Solids, 522, 119554. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Carbon xerogel | es |
dc.subject | Carbon aerogel | es |
dc.subject | Starch | es |
dc.subject | Resorcinol-formaldehyde | es |
dc.subject | Raman fitting | es |
dc.title | Effect of starch as binder in carbon aerogel and carbon xerogel preparation | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/acceptedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | ENE2013-47880-C3-2-R | es |
dc.relation.projectID | ENE2017-82451-C3-3-R | es |
dc.relation.publisherversion | https://doi.org/10.1016/j.jnoncrysol.2019.119554 | es |
dc.identifier.doi | 10.1016/j.jnoncrysol.2019.119554 | es |
dc.journaltitle | Journal of Non-Crystalline Solids | es |
dc.publication.volumen | 522 | es |
dc.publication.initialPage | 119554 | es |
dc.identifier.sisius | 21911913 | es |
dc.contributor.funder | Ministerio de Economía y Competitividad (MINECO). España | es |
dc.contributor.funder | European Commission (EC). Fondo Europeo de Desarrollo Regional (FEDER) | es |