dc.creator | Bobadilla Baladrón, Luis Francisco | es |
dc.creator | Azancot Luque, Lola de las Aguas | es |
dc.creator | Ivanova, Svetlana | es |
dc.creator | Delgado, Juan J. | es |
dc.creator | Romero Sarria, Francisca | es |
dc.creator | Centeno Gallego, Miguel Ángel | es |
dc.creator | Roger, Anne Cécile | es |
dc.creator | Odriozola Gordón, José Antonio | es |
dc.date.accessioned | 2022-01-12T16:53:49Z | |
dc.date.available | 2022-01-12T16:53:49Z | |
dc.date.issued | 2021 | |
dc.identifier.citation | Bobadilla Baladrón, L.F., Azancot Luque, L.d.l.A., Ivanova, S., Delgado, J.J., Romero Sarria, F., Centeno Gallego, M.Á.,...,Odriozola Gordón, J.A. (2021). In situ DRIFTS-MS methanol adsorption study onto supported NiSn nanoparticles: Mechanistic implications in methanol steam reforming. Nanomaterials, 11 (12), 3234. https://doi.org/10.3390/nano11123234. | |
dc.identifier.issn | 2079-4991 | es |
dc.identifier.uri | https://hdl.handle.net/11441/128800 | |
dc.description.abstract | Methanol adsorption over both supported NiSn Nps and analogous NiSn catalyst prepared by impregnation was studied by in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) to gain insights into the basis of hydrogen production from methanol steam reforming. Different intermediate species such as methoxides with different geometry (bridge and monodentate) and formate species were identified after methanol adsorption and thermal desorption. It is proposed that these species are the most involved in the methanol steam reforming reaction and the major presence of metal-support interface sites in supported NiSn Nps leads to higher production of hydrogen. On the basis of these results, a plausible reaction mechanism was elucidated through the correlation between the thermal stability of these species and the evolution of the effluent gas released. In addition, it was demonstrated that DME is a secondary product generated by condensation of methoxides over the acid sites of alumina support in an acid-catalyzed reaction. | es |
dc.description.sponsorship | Junta de Andalucía POG-TEP01965 | es |
dc.format | application/pdf | es |
dc.format.extent | 16 p. | es |
dc.language.iso | eng | es |
dc.publisher | Multidisciplinary Digital Publishing Institute (MDPI) | es |
dc.relation.ispartof | Nanomaterials, 11 (12), 3234. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | In situ DRIFTS-MS | es |
dc.subject | Mechanism | es |
dc.subject | Methanol steam reforming | es |
dc.subject | NiSn nanoparticles | es |
dc.title | In situ DRIFTS-MS methanol adsorption study onto supported NiSn nanoparticles: Mechanistic implications in methanol steam reforming | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | POG-TEP01965 | es |
dc.relation.publisherversion | https://doi.org/10.3390/nano11123234 | es |
dc.identifier.doi | 10.3390/nano11123234 | es |
dc.journaltitle | Nanomaterials | es |
dc.publication.volumen | 11 | es |
dc.publication.issue | 12 | es |
dc.publication.initialPage | 3234 | es |