Browsing Artículos (Instituto de Investigaciones Químicas (IIQ) – CIC Cartuja) by Funding agency "Junta de Andalucía"
Now showing items 1-20 of 120
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Article
3-(Piperidin-1-ium-1-yl)-6-azoniaspiro[5.5]undecane dibromide monohydrate
(International Union of Crystallography, 2011)The title compound, C15H30N2 2+·2Br−·H2O, was synthesized by reaction of 4-piperidinopiperidine with dibromopentane. The ...
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Article
A betaine adduct of N-heterocyclic carbene and carbodiimide, an efficient ligand to produce ultra-small ruthenium nanoparticles
(Royal Society of Chemistry, 2015)The betaine adduct of N-heterocyclic carbene and carbodiimide (ICy·(p-tol)NCN) was found to be a very efficient ligand to ...
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Article
A Diels–Alder Reaction Triggered by a [4 + 3] Metallacycloaddition
(American Chemical Society, 2015)The TpMe2Ir(III) complex 1-OH2 (TpMe2 = hydrotris(3,5-dimethylpyrazolyl)borate), which contains a labile molecule of water ...
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A Dynamic Kinetic C-P Cross-Coupling for the Asymmetric Synthesis of Axially Chiral P,N Ligands
(American Chemical Society, 2016)The Pd-catalyzed enantioselective C-P cross-coupling between racemic, configurationally stable heterobiaryl triflates and ...
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Article
A putative RNA binding protein from Plasmodium vivax apicoplast
(Wiley, 2018)Malaria is caused by Apicomplexa protozoans from the Plasmodium genus entering the bloodstream of humans and animals through ...
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A splice-altering homozygous variant in COX18 causes severe sensory-motor neuropathy with oculofacial apraxia
(Elsevier B.V., 2024-10)Cytochrome-c oxidase (COX) is part of the mitochondrial complex IV (CIV). COX deficiency is usually associated with tRNA ...
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Activation of Si-H and B-H bonds by Lewis acidic transition metals and p-block elements: same, but different
(Royal Society of Chemistry, 2022)In this Perspective we discuss the ability of transition metal complexes to activate and cleave the Si–H and B–H bonds of ...
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Article
Alkane Metathesis over Immobilized Pincer-ligated Iridium Complexes: Effect of Support Nature
(Elsevier, 2023)In this work, catalytic alkane metathesis has been evaluated as a suitable approach to upcycle hydrocarbons (polyolefins) ...
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Alkoxyamine-cyanoborane adducts: Efficient cyanoborane transfer agents
(Royal Society of Chemistry, 2011)We report the synthesis of the hitherto unknown zwitterionic alkoxyamino cyanoboranes by reduction of O-alkyloximes with ...
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Article
ARL15 modulates magnesium homeostasis through N-glycosylation of CNNMs
(Springer, 2021)Cyclin M (CNNM1-4) proteins maintain cellular and body magnesium (Mg2+) homeostasis. Using various biochemical approaches, ...
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Article
Asymmetric organocatalytic Strecker-type reactions of aliphatic N,N-dialkylhydrazones
(Royal Society of Chemistry (Great Britain), 2013)The enantioselective organocatalytic Strecker-type reaction of aliphatic N,N-dialkylhydrazones is presented. Using ...
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Asymmetric Organocatalytic Synthesis of Fluorinated β-Hydroxy Diazenes
(Wiley-Blackwell, 2019)The nucleophilic addition of formaldehyde tert-butyl hydrazone to fluoromethyl ketones provides a valuable tool for the ...
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Article
Atroposelective Synthesis of 2-(Quinolin-8-yl)benzyl Alcohols by Biocatalytic Dynamic Kinetic Resolutions
(Wiley, 2023-12-22)A highly enantioselective biocatalytic dynamic kinetic resolution (DKR) of 2-(quinoline-8-yl) 3-methylbenzaldehydes and ...
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Article
AuI-Catalyzed Haloalkynylation of Alkenes
(Wiley-Blackwell, 2020)The formal insertion of alkenes into aromatic chloro- and bromoalkynes takes place under cationic gold catalysis. This ...
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AuI-Catalyzed Hydroalkynylation of Haloalkynes
(American Chemical Society, 2020)The AuI-catalyzed reaction between terminal alkynes and aromatic haloalkynes proceeds through divergent pathways depending ...
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Article
Axially Chiral Triazoloisoquinolin-3-ylidene Ligands in Gold(I)-catalyzed Asymmetric Intermolecular (4 + 2) Cycloadditions of Allenamides and Dienes
(American Chemical Society, 2012)The first highly enantioselective intermolecular (4 + 2) cycloaddition between allenes and dienes is reported. The reaction ...
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Article
Bifunctional Squaramide Organocatalysts for the Asymmetric Addition of Formaldehyde tert-Butylhydrazone to Simple Aldehydes
(Wiley-Blackwell, 2018)The nucleophilic addition of formaldehyde tert-butylhydrazone to simple aldehydes (a formal hetero-carbonyl–ene reaction) ...
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Bonding Situation of σ-E−H Complexes in Transition Metal and Main Group Compounds
(Wiley-Blackwell, 2022)The ambiguous bonding situation of σ-E−H (E=Si, B) complexes in transition metal compounds has been rationalized by means ...
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Article
Catalytic amine-borane dehydrogenation by a PCP-pincer palladium complex: A combined experimental and DFT analysis of the reaction mechanism
(Royal Society of Chemistry (Great Britain), 2013)Catalytic dehydrogenation of ammonia-borane (NH3·BH 3, AB) and dimethylamine borane (NHMe2·BH 3, DMAB) by the PdII complex ...
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Article
Catalytic Nitrous Oxide Reduction with H2 Mediated by Pincer Ir Complexes
(American Chemical Society, 2022)Reduction of nitrous oxide (N2O) with H2 to N2 and water is an attractive process for the decomposition of this greenhouse ...