Listar Artículos (Instituto de Investigaciones Químicas (IIQ) – CIC Cartuja) por título
Mostrando ítems 141-160 de 284
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Large-scale preparation and labelling reactions of deuterated silanes
(John Wiley & Sons, 2012)A catalytic synthesis of deuterated silanes SiEt3D, SiMe2PhD and SiPh2D2 is reported that allows their facile generation ...
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Ligand and metal-centred reactivity in 2,6-bis(imino)-1,4-dihydropyridinate Zn(ii) alkyls: the dual behaviour of an intriguing type of complex
(Royal Society of Chemistry, 2023)Dihydropyridines, either free or metal-coordinated, are organic hydride transfer reductants that perform on the same ...
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Ligand Postsynthetic Functionalization with Fluorinated Boranes and Implications in Hydrogenation Catalysis
(American Chemical Society, 2023)The incorporation of boron functionalities into transition-metal catalysts has become a promising strategy to improve ...
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Lithium Di-‐ and Trimethyl Dimolybdenum(II) Complexes with Mo-‐Mo Quadruple Bonds and Bridging Methyl Groups
(American Chemical Society, 2015)New dimolybdenum complexes of composition [Mo2{μ-Me}2Li(S)}(μ- X)(μ-N^N)2] (3a−3c), where S = THF or Et2O and N^N represents ...
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Long distance electron transfer through the aqueous solution between redox partner proteins
(Nature Research, 2018)Despite the importance of electron transfer between redox proteins in photosynthesis and respiration, the inter-protein ...
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LPdCl2(amine) Complexes Supported by Terphenyl Phosphanes: Applications in Aryl Amination Reactions
(Royal Society of Chemistry, 2022)Despite the excellent catalytic properties display by NHC-Pd-PEPPSI complexes in cross-coupling, phosphane analogs have ...
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LPS promotes Th2 dependent sensitisation leading to anaphylaxis in a Pru p 3 mouse model
(Nature Publishing Group, 2017-01-13)Pru p 3 is the major peach allergen in the Mediterranean area. It frequently elicits severe reactions, limiting its study ...
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Lysosomes: multifunctional compartments ruled by a complex regulatory network
(Wiley, 2022)More than 50 years have passed since Nobel laureate Cristian de Duve described for the first time the presence of tiny ...
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Mannosyl-coated nanocomplexes from amphiphilic cyclodextrins and pDNA for site-specific gene delivery
(Elsevier, 2011-10)Fully homogeneous facial amphiphiles consisting in a cyclodextrin (CD) platform onto which a polycationic cluster and a ...
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Mechanism of Alkyl Migration in Diorganomagnesium 2,6-Bis(imino)pyridine Complexes: Formation of Grignard-Type Complexes with Square-Planar Mg(II) Centers
(American Chemical Society, 2016)Dialkylmagnesium compounds [MgR2L2] (R = n-Bu, L = none or R = Bn, L = THF) react with 2,6-bis(imino)pyridines (BIP) to ...
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Mechanism of Dihydrogen Splitting by An Apparent Bimetallic Frustrated Lewis Pair based on Ir(III)/Pt(0)
(Wiley-Blackwell, 2023)The incorporation of transition metals into frustrated Lewis pairs (FLPs) offers multiple opportunities for bond activation ...
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Mechanistic Investigations on Hydrogenation, Isomerization and Hydrosilylation Reactions Mediated by a Germyl-Rhodium System
(Wiley, 2022)We recently disclosed a dehydrogenative double C−H bond activation reaction in the unusual pincer-type rhodium-germyl ...
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Mechanistic Studies on the Selective Reduction of CO2 to the Aldehyde Level by a PBP-Supported Nickel Complex
(American Chemical Society, 2016)This work describes a thorough investigation of the mechanism of a highly selective hydrosilylation of CO2 to the formaldehyde ...
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Mechanocatalytic Depolymerization of Cellulose With Perfluorinated Sulfonic Acid Ionomers
(Frontiers Media, 2018)Here, we investigated that the mechanocatalytic depolymerization of cellulose in the presence of Aquivion, a sulfonated ...
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Membraneless organelles: a smart design for metabolic control
(Wiley Online Library, 2021)While most organelles are surrounded by membranes, cells also contain membraneless organelles, which remain separated in ...
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Metal-only Lewis Pairs of Rhodium with s, p and d-Block Metals
(Wiley, 2020)Metal-only Lewis pairs (MOLPs) in which the two metal fragments are solely connected by a dative M→M bond represent ...
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Metalated Ir–CNP Complexes Containing Imidazolin-2-ylidene and Imidazolidin-2-ylidene Donors – Synthesis, Structure, Luminescence, and Metal–Ligand Cooperative Reactivity
(Wiley-Blackwell, 2020)The iridium complex 1 based on a metalated CNP ligand containing an imidazolin-2-ylidene fragment has been prepared by ...
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Methyl Complexes of the Transition Metals
(John Wiley & Sons, 2016)Organometallic chemistry can be considered as a wide area of knowledge that combines concepts of classic organic chemistry, ...
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Migratory insertion reactions of nickel and palladium σ-alkyl complexes with a phosphinito-imine ligand†‡
(Royal Society of Chemistry (Great Britain), 2012)Ligand exchange reactions have been used for the synthesis of metallacyclic complexes of Ni and Pd of the type [M[upper ...
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Mitochondrial cytochrome c shot towards histone chaperone condensates in the nucleus
(Wiley-Blackwell, 2021)Despite mitochondria being key for the control of cell homeostasis and fate, their role in DNA damage response is usually ...