Instituto de Investigaciones Químicas (IIQ) – CIC Cartuja: Envíos recientes
Mostrando ítems 41-60 de 278
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Synthesis and characterization of enantiopure chiral NH2/SO palladium complexes
(Royal Society of Chemistry, 2023)A series of enantiopure chiral NH2/SO palladium complexes have been synthesised with high yields by treating the corresponding ...
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A dicoordinate gold(i)–ethylene complex
(Royal Society of Chemistry, 2021)The use of the exceptionally bulky tris-2-(4,40 -di-tert-butylbiphenylyl) phosphine ligand allows the isolation and ...
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Bonding Situation of σ-E−H Complexes in Transition Metal and Main Group Compounds
(Wiley-Blackwell, 2022)The ambiguous bonding situation of σ-E−H (E=Si, B) complexes in transition metal compounds has been rationalized by means ...
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Activation of Si-H and B-H bonds by Lewis acidic transition metals and p-block elements: same, but different
(Royal Society of Chemistry, 2022)In this Perspective we discuss the ability of transition metal complexes to activate and cleave the Si–H and B–H bonds of ...
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Sacrificial Ligand Route to Hybrid Polythiophene-silver Nanoparticles for Sinter-free Conductive Inks
(Royal Society of Chemistry, 2023)We report the synthesis of AgNP@PEDOT:PSS hybrid conductive particles with silver cores and polythiophene shells that can ...
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Serine-/Cysteine-based sp2-Iminoglycolipids as novel TLR4 agonists: evaluation of their adjuvancy and immunotherapeutic properties in a murine model of asthma
(American Chemical Society, 2023)Glycolipids with TLR4 agonistic properties can serve either as therapeutic agents or as vaccine adjuvants by stimulating ...
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Fluoro-labelled sp2-iminoglycolipids with immunomodulatory properties
(Elsevier, 2023)The unique electronic properties of the fluorine atom make its strategic incorporation into a bioactive compound a very ...
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Enhanced Stability of Perovskite Solar Cells Incorporating Dopant-Free Crystalline Spiro-OMeTAD Layers by Vacuum Sublimation
(Wiley-Blackwell, 2020)The main handicap still hindering the eventual exploitation of organometal halide perovskite-based solar cells is their ...
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Dialkylterphenyl Phosphine-Based Palladium Precatalysts for Efficient Aryl Amination of N-Nucleophiles
(Wiley-Blackwell, 2020)A series of 2-aminobiphenyl palladacycles supported by dialkylterphenyl phosphines, PR2Ar′ (R=Me, Et, iPr, Cyp (cyclopentyl), ...
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Palladium-mediated Intramolecular Dearomatization of Ligated Dialkylterphenyl Phosphines
(Royal Society of Chemistry, 2019)Aryl-Pd(ii) chlorides stabilized by dialkylterphenyl phosphine ligands undergo a thermal isomerization process, leading ...
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N-substituted Aminobiphenyl Palladacycles Stabilized by Dialkylterphenyl Phosphanes: Preparation and Applications in C[sbnd]N Cross-coupling Reactions
(Elsevier, 2021)Neutral and cationic N-methyl- and N-phenyl-2-aminobiphenyl methanesulfonate palladacycles stabilized with dialkylterphenyl ...
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Zero-valent ML2complexes of Group 10 Metals Supported by Terphenyl Phosphanes
(Royal Society of Chemistry, 2021)Bulky terphenyl phosphane ligands PMe2Ar′ (Ar′ = terphenyl group) facilitate the isolation of zero-valent bis-phosphane ...
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LPdCl2(amine) Complexes Supported by Terphenyl Phosphanes: Applications in Aryl Amination Reactions
(Royal Society of Chemistry, 2022)Despite the excellent catalytic properties display by NHC-Pd-PEPPSI complexes in cross-coupling, phosphane analogs have ...
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Metalated Ir–CNP Complexes Containing Imidazolin-2-ylidene and Imidazolidin-2-ylidene Donors – Synthesis, Structure, Luminescence, and Metal–Ligand Cooperative Reactivity
(Wiley-Blackwell, 2020)The iridium complex 1 based on a metalated CNP ligand containing an imidazolin-2-ylidene fragment has been prepared by ...
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Synthesis of β-galactosylamides as ligands of the peanut lectin. Insights into the recognition process
(Elsevier, 2017)The synthesis of mono and divalent β-galactosylamides linked to a hydroxylated chain having a C2 symmetry axis derived ...
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Dinuclear Cu(I) Halides with Terphenyl Phosphines: Synthesis, Photophysical Studies, and Catalytic Applications in CuAAC Reactions
(American Chemical Society, 2020)Several dinuclear terphenyl phosphine copper(I) halide complexes of composition [CuX(PR2Ar′)]2 (X = Cl, Br, I; R = ...
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Tuning Activity and Selectivity during Alkyne Activation by Gold(I)/Platinum(0) Frustrated Lewis Pairs
(American Chemical Society, 2020)Introducing transition metals into frustrated Lewis pair systems has attracted considerable attention in recent years. ...
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Evaluating stereoelectronic properties of bulky dialkylterphenyl phosphine ligands
(Elsevier, 2019)The stereoelectronic properties of a series of sterically hindered phosphines containing a terphenyl substituent, PR2Ar’ ...
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Nickel and Palladium Complexes with Reactive σ-Metal-Oxygen Covalent Bonds
(Wiley-Blackwell, 2020)This article reviews the chemistry of nickel and palladium complexes with terminally bound hydroxide and alkoxide ligands. ...
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Ensuring image integrity in the digital age
(Wiley-Blackwell, 2022)FEBS Open Bio and our fellow FEBS Press journals have a strong commitment to maintaining the integrity of the scientific ...