Browsing Instituto de Investigaciones Químicas (IIQ) – CIC Cartuja by Title
Now showing items 199-218 of 276
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Article
Reactivity of [Pt(PtBu3)2] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn–Zn Bond Cleavage, and Cooperative Reactivity
(American Chemical Society, 2021)Metal-only Lewis pairs (MOLPs) based on zinc electrophiles are particularly interesting due to their relevance to Negishi ...
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Article
Reactivity of a gold(i)/platinum(0) frustrated Lewis pair with germanium and tin dihalides
(Royal Society of Chemistry, 2019)The reactivity of germanium and tin dichlorides with a transition metal-only frustrated Lewis pair based on Au(i) and Pt(0) ...
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Article
Reactivity of TpMe2-containing hydride-iridafurans with alkenes, alkynes, and H2
(American Chemical Society, 2014)The TpMe2-containing hydride-iridafurans 2a,b (TpMe2 = hydrotris(3,5-dimethylpyrazolyl)borate) cleanly reacted with ethylene ...
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Red-Emitting Tetracoordinate Organoboron Chelates: Synthesis, Photophysical Properties, and Fluorescence Microscopy
(American Chemical Society, 2016)Seven tetracoordinate organoboron fluorophores with heterobiaryl N,O- or N,N-chelate ligands were prepared and photophysically ...
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Reduction of N2O with hydrosilanes catalysed by RuSNS nanoparticles
(Royal Society of Chemistry, 2022)A series of RuSNS nanoparticles, prepared by decomposition of Ru(COD)(COT) with H2 in the presence of an SNS ligand, have been found to catalyse the reduction of the greenhouse gas N2O to N2 employing different hydrosilanes.
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Article
Regulation of TIA-1 Condensates: Zn2+ and RGG Motifs Promote Nucleic Acid Driven LLPS and Inhibit Irreversible Aggregation
(Frontiers Media S.A., 2022)Stress granules are non-membrane bound RNA-protein granules essential for survival during acute cellular stress. TIA-1 is ...
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Article
Reversible Light-Induced Dimerization of Secondary Face Azobenzene-Functionalized β-Cyclodextrin Derivatives
(American Chemical Society, 2023)β-cyclodextrin (βCyD) derivatives equipped with aromatic appendages at the secondary face exhibit tailorable self-assembling ...
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Rhodium and Iridium Complexes of Bulky Tertiary Phosphine Ligands. Searching for Isolable Cationic M(III) Alkylidenes
(American Chemical Society, 2015)Cyclometalated chloride complexes of rhodium and iridium based on (5-C5Me5)M(III) fragments that result from the metalation ...
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Rhodium phosphine-phosphite catalysts in the hydrogenation of challenging N-(3,4-dihydronaphthalen-2-yl) amide derivatives
(American Chemical Society, 2013)The enantioselective catalytic hydrogenation of N-(3,4-dihydronaphthalen-2- yl) amides (1) with rhodium catalysts bearing ...
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Article
RNA Binding Protein Regulation and Cross-Talk in the Control of AU-rich mRNA Fate
(Frontiers Media, 2017)mRNA metabolism is tightly orchestrated by highly-regulated RNA Binding Proteins (RBPs) that determine mRNA fate, thereby ...
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Ruthenium Nanoparticles Stabilized by 1,2,3-Triazolylidene Ligands in the Hydrogen Isotope Exchange of E-H Bonds (E = B, Si, Ge, Sn) Using Deuterium Gas
(Royal Society of Chemistry, 2023)A series of ruthenium nanoparticles (Ru·MIC) stabilized with different mesoionic 1,2,3-triazolylidene (MIC) ligands were ...
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Ruthenium(II) Complexes Containing Lutidine-derived Pincer CNC Ligands: Synthesis, Structure and Catalytic Hydrogenation of C=N bonds
(Wiley-Blackwell, 2015)A series of Ru complexes containing lutidine‐derived pincer CNC ligands have been prepared by transmetalation with the ...
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Article
Sacrificial Ligand Route to Hybrid Polythiophene-silver Nanoparticles for Sinter-free Conductive Inks
(Royal Society of Chemistry, 2023)We report the synthesis of AgNP@PEDOT:PSS hybrid conductive particles with silver cores and polythiophene shells that can ...
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Selective carbohydrate-lectin interactions in covalent graphene- and SWCNT-based molecular recognition systems
(Royal Society of Chemistry, 2013)Two new protein recognition systems have been prepared by covalent functionalization of few-layer graphene and SWCNTs with ...
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Article
Selective catalytic synthesis of amino-silanes at part-per million catalyst loadings
(Royal Society of Chemistry, 2018)Platinum(II) complex [Pt(It Bu0 )(It Bu)][BArF 4] (1a) is a highly active and selective catalyst in the dehydrocoupling ...
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Selective reduction of carbon dioxide to bis(silyl)acetal catalyzed by a PBP-supported nickel complex
(American Chemical Society, 2016)Selective reduction of CO2 to the formaldehyde level remains an important challenge and to date only a few catalysts have ...
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Article
Self-association of a naphthalene-capped-β-cyclodextrin through cooperative strong hydrophobic interactions
(Elsevier, 2011-09-05)NMR, circular dichroism and fluorescence techniques were used to study the structure in solution of a new β-cyclodextrin ...
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Article
Sequential reduction and alkyl exchange reactions of bis(imino)pyridine dialkyliron(II) with trimethylaluminum
(American Chemical Society, 2014)The sequence of reactions ensuing when the 2,6-bis(imino)pyridine Fe(II) dialkyl complexes [Fe(CH2SiMe3)2(BIP)] react with ...
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Serine-/Cysteine-based sp2-Iminoglycolipids as novel TLR4 agonists: evaluation of their adjuvancy and immunotherapeutic properties in a murine model of asthma
(American Chemical Society, 2023)Glycolipids with TLR4 agonistic properties can serve either as therapeutic agents or as vaccine adjuvants by stimulating ...
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Article
Silver-free gold-catalyzed heterocyclizations through intermolecular H-bonding activation.
(AMER Chemical Soc, 2023-01-27)Modulable monosulfonyl squaramides have been shown to exert activation of gold(I) chloride complexes through H-bonding in ...