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Tuning the Inorganic Core of a reduced Ni2Ge2 Cluster
(Wiley, 2024-04)
Tetranuclear cores (M−E)2 of transition metals (M) and tetrylenes (EII=Si, Ge, Sn) are key motifs in homogeneous and heterogeneous catalysis. They exhibit a continuum of M−M and E−E bonding within the inorganic core that ...
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A generalized interface reaction kinetic model for describing heterogeneous processes driven by contracting mechanisms
(Springer, 2024-01-30)
The correct determination of the kinetic model and the kinetic parameters that describe a heterogeneous process is key to accurately predicting its progress within a wide range of conditions, which is one of the main ...
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Ba3(PO4)2 Photocatalyst for Efficient Photocatalytic Application
(Wiley-V C H Verlag GMBH, 2023-12-07)
Barium phosphate (Ba3(PO4)2) is a class of material that has attracted significant attention thanks to its chemical stability and versatility. However, the use of Ba3(PO4)2 as a photocatalyst is scarcely reported, and ...
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Boosting Low-Temperature CO2 Hydrogenation over Ni-based Catalysts by Tuning Strong Metal-Support Interactions.
(Wiley-V C H Verlag GMBH, 2023-11-30)
Rational design of low-cost and efficient transition-metal catalysts for low-temperature CO2 activation is significant and poses great challenges. Herein, a strategy via regulating the local electron density of active sites ...
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Ca-based materials derived from calcined cigarette butts for CO2 capture and thermochemical energy storage
(Science Press, 2023-07-27)
Cigarette butts (CBs) are one of the most common types of litter in the world. Due to the toxic substances they contain, the waste generated poses a harmful risk to the environment, and therefore there is an urgent need ...
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CO2 Conversion via Low-Temperature RWGS Enabled by Multicomponent Catalysts: Could Transition Metals Outperform Pt?
(Springer, 2024-02-26)
In the context of CO2 valorisation, the reverse water–gas shift reaction (RWGS) is gathering momentum since it represents a direct route for CO2 reduction to CO. The endothermic nature of the reaction posses a challenge ...
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Chemo-selective Stille-type coupling of acyl-chlorides upon phosphine-borane Au(i) catalysis
(Royal Society of Chemistry, 2023-11-17)
Phosphine-boranes do not promote oxidative addition of acyl chlorides to gold, but the phosphine-borane gold triflimide complex [i Pr2P(o-C6H4)BCy2]AuNTf2 was found to catalyze the coupling of acyl chlorides and aryl ...
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Efficient toluene degradation using Bacillus subtilis biofilm-supported Mn–Ce/zeolite catalysts
(2024-01-24)
This study investigated a new approach for synthesizing Bacillus subtilis biofilm-supported Mn–Ce/zeolite catalysts for the degradation of gaseous toluene. Four different metal oxide nano-catalysts (ZMn, ZMnCe-10%, ZMnCe20%, ...
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Flash Joule Heating-Boro/Carbothermal Reduction (FJH-BCTR): An approach for the instantaneous synthesis of transition metal diborides
(Elsevier, 2024-01-09)
Transition metal diborides (TMB2), such as ZrB2 and HfB2, are a class of ultra-high-temperature ceramics (UHTCs) that have attracted considerable attention due to their performance in extreme environments. Their implementation ...
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Investigating the room- and cryo-milling impact in lignocellulosic biomass and its consequence over pyrolysis and oxidative treatments
(Elsevier, 2024-01-12)
The lignocellulosic biomass recalcitrance is the uppermost factor for the utilization of this renewable resource. The development of new pre-treatments, addressed to enhance performance in lignocellulosic biomass conversion ...