dc.creator | Carmona Guzmán, Ernesto | es |
dc.creator | Cámpora Pérez, Juan | es |
dc.creator | Muñoz, Miguel Ángel | es |
dc.creator | Paneque Sosa, Margarita | es |
dc.creator | López Poveda, Manuel | es |
dc.date.accessioned | 2019-09-10T08:33:05Z | |
dc.date.available | 2019-09-10T08:33:05Z | |
dc.date.issued | 1989 | |
dc.identifier.citation | Carmona Guzmán, E., Cámpora Pérez, J., Muñoz, M.Á., Paneque Sosa, M. y López Poveda, M. (1989). Electron-rich metal complexes for C02 and CS2 incorporation. Pure and Applied Chemistry, 61 (10), 1701-1706. | |
dc.identifier.issn | 0033-4545 | es |
dc.identifier.uri | https://hdl.handle.net/11441/89078 | |
dc.description.abstract | The dihapto coordination of two molecules of carbon dioxide to a square-planar MoP2(P-P) fragment (P=monodentate-, P-P=bidentate phosphi- ne ligands) can occur in several ways giving rise to different conformers. Compounds of this type have been prepared and their spectroscopic proper- ties investigated by variable temperature 'H and 31P NMR studies. The for- mation of ethylene complexes related to Mo(C2H4)2(PMe3)4, 6, and the study of their reactivity towards carbon dioxide and carbon disulphide is also described. In particular, compound 6 induces a head-to-tail dimerization of carbon disulphide with formation of a Mo(II)-C$4 linkage, which, in the presence of carbon monoxide, undergoes a symmetric, oxidative rupture, which produces a Mo(0) complex and two molecules of carbon disulphide. The insertion reactions of carbon dioxide and other unsaturated molecules into the nickel-carbon bonds of the nickelacyclopentene complexes 9 have been investigated and different organic products isolated by means of simple or sequential insertion reactions. | es |
dc.description.sponsorship | Ministerio de Educación y Ciencia | es |
dc.description.sponsorship | Agencia Nacional de Evaluación y Prospectiva | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Walter de Gruyter GmbH | es |
dc.relation.ispartof | Pure and Applied Chemistry, 61 (10), 1701-1706. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Electron-rich metal complexes for C02 and CS2 incorporation | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.publisherversion | http://www.old.iupac.org/publications/pac/1989/pdf/6110x1701.pdf | es |
idus.format.extent | 7 p. | es |
dc.journaltitle | Pure and Applied Chemistry | es |
dc.publication.volumen | 61 | es |
dc.publication.issue | 10 | es |
dc.publication.initialPage | 1701 | es |
dc.publication.endPage | 1706 | es |
dc.identifier.sisius | 20535714 | es |