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Different coordination modes of an aryl-substituted hydrotris(pyrazolyl) borate ligand in rhodium and iridium complexes

 

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Opened Access Different coordination modes of an aryl-substituted hydrotris(pyrazolyl) borate ligand in rhodium and iridium complexes
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Author: Conejero Iglesias, Salvador
Esqueda Oliva, Ana Cristina
Valpuesta, José Enrique V.
Álvarez González, Eleuterio
Maya Díaz, Celia María
Carmona Guzmán, Ernesto
Department: Universidad de Sevilla. Departamento de Química Inorgánica
Date: 2011
Published in: Inorganica Chimica Acta, 369 (1), 165-172.
Document type: Article
Abstract: Complexes TptolRh(C2H4)2 (1a) and TptolRh(CH2C(Me)C(Me)CH2) (1b) have been prepared by reaction of KTptol with the appropriate [RhCl(olefin)2]2 dimer (Tptol means hydrotris(3-p-tolylpyrazol-1-yl)borate). The two complexes show a dynamic behaviour th...
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Cite: Conejero Iglesias, S., Esqueda Oliva, A.C., Valpuesta, J.E.V., Álvarez González, E., Maya Díaz, C.M. y Carmona Guzmán, E. (2011). Different coordination modes of an aryl-substituted hydrotris(pyrazolyl) borate ligand in rhodium and iridium complexes. Inorganica Chimica Acta, 369 (1), 165-172.
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URI: https://hdl.handle.net/11441/87933

DOI: 10.1016/j.ica.2010.12.031

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