dc.creator | Sandoval, John J. | es |
dc.creator | Palma Ramírez, María del Pilar | es |
dc.creator | Álvarez González, Eleuterio | es |
dc.creator | Rodríguez Delgado, Antonio | es |
dc.creator | Cámpora Pérez, Juan | es |
dc.date.accessioned | 2018-10-17T14:36:53Z | |
dc.date.available | 2018-10-17T14:36:53Z | |
dc.date.issued | 2013 | |
dc.identifier.citation | Sandoval, J.J., Palma Ramírez, M.d.P., Álvarez González, E., Rodríguez Delgado, A. y Cámpora Pérez, J. (2013). Dibenzyl and diallyl 2,6-bisiminopyridinezinc (ii) complexes: Selective alkyl migration to the pyridine ring leads to remarkably stable dihydropyridinates. Chemical Communications, 49, 6791-6793. | |
dc.identifier.issn | 1359-7345 (impreso) | es |
dc.identifier.issn | 1364-548X (electrónico) | es |
dc.identifier.uri | https://hdl.handle.net/11441/79520 | |
dc.description.abstract | Diorganozinc compounds (ZnR2) with R = CH2Ph or CH2CH[double bond, length as m-dash]CH2 react with 2,6-bisiminopyridines (iPrBIP) to afford thermally stable dihydropyridinate(−1) complexes, and do not react if R = CH2SiMe3 or CH2CMe2Ph. NMR studies reveal that dibenzylzinc binds iPrBIP at −80 °C, yielding the unstable complex [Zn(CH2Ph)2(iPrBIP)]. Above −20 °C, this undergoes selective alkyl migration to the remote 4 position of the central pyridine ring. | es |
dc.description.sponsorship | Junta de Andalucía CTQ2012-30962, FQM5074 | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Royal Society of Chemistry | es |
dc.relation.ispartof | Chemical Communications, 49, 6791-6793. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Dibenzyl and diallyl 2,6-bisiminopyridinezinc (ii) complexes: Selective alkyl migration to the pyridine ring leads to remarkably stable dihydropyridinates | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/acceptedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.relation.projectID | CTQ2012-30962 | es |
dc.relation.projectID | FQM5074 | es |
dc.relation.publisherversion | http://dx.doi.org/10.1039/c3cc42798f | es |
dc.identifier.doi | 10.1039/c3cc42798f | es |
idus.format.extent | 10 p. | es |
dc.journaltitle | Chemical Communications | es |
dc.publication.volumen | 49 | es |
dc.publication.initialPage | 6791 | es |
dc.publication.endPage | 6793 | es |
dc.contributor.funder | Junta de Andalucía | |