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Synthesis and Reactivity of Nickel an Palladium Fluoride Complexes with PCP Pincer Ligands. A NMR-Based Assessment of Electron-Donating Properties of Fluoride and Other Monoanionic Ligands

 

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Opened Access Synthesis and Reactivity of Nickel an Palladium Fluoride Complexes with PCP Pincer Ligands. A NMR-Based Assessment of Electron-Donating Properties of Fluoride and Other Monoanionic Ligands
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Author: Martínez Prieto, Luis Miguel
Melero Jiménez, Cristóbal
Rio Díaz-Jara, Diego del
Cámpora Pérez, Juan
Álvarez González, Eleuterio
Date: 2012
Published in: Organometallics, 31 (4), 1425-1438.
Document type: Article
Abstract: A series of complexes of the type [(iPrPCP)M-L] (M = Ni, Pd), containing the 2,6-bis(diisopropylphosphinomethyl)phenyl (iPrPCP) pincer ligand and simple monoanionic ligands L (F, Cl, Br, H, Me, Ph, NO3, and OTf), have been synthesized and characteri...
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Cite: Martínez Prieto, L.M., Melero Jiménez, C., Rio Díaz-Jara, D.d., Cámpora Pérez, J. y Álvarez González, E. (2012). Synthesis and Reactivity of Nickel an Palladium Fluoride Complexes with PCP Pincer Ligands. A NMR-Based Assessment of Electron-Donating Properties of Fluoride and Other Monoanionic Ligands. Organometallics, 31 (4), 1425-1438.
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URI: https://hdl.handle.net/11441/79354

DOI: 10.1021/om2009793

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