dc.creator | Arribas Nieto, Inmaculada | es |
dc.creator | Álvarez González, Eleuterio | es |
dc.creator | Pizzano Mancera, Antonio | es |
dc.date.accessioned | 2018-10-03T09:21:17Z | |
dc.date.available | 2018-10-03T09:21:17Z | |
dc.date.issued | 2013 | |
dc.identifier.citation | Arribas Nieto, I., Álvarez González, E. y Pizzano Mancera, A. (2013). Novel bis (1,3,2-diazaphospholidine) ligands for asymmetric catalysis. Organometallics, 32, 2497-2500. | |
dc.identifier.issn | 0276-7333 (impreso) | es |
dc.identifier.issn | 1520-6041 (electrónico) | es |
dc.identifier.uri | https://hdl.handle.net/11441/79045 | |
dc.description.abstract | A family of modularly designed chiral bis(1,3,2-diazaphospholidines) with N-aryl substituents (NP-PN) is reported. These compounds have been prepared in two steps from readily available (R,R)-1,2-diaminocyclohexane and tetrachlorodiphosphines. Examples in the set differ in the backbone and the aryl substituents, aiming at their application in asymmetric catalysis. Thus, [Rh(NBD)(NP-PN)]BF4 complexes lead to active catalysts in the hydrogenation of methyl α-acetamidoacrylate, which provide enantioselectivities up to 96% ee. In addition, NP-PN ligands also generate active catalysts in the hydroformylation of vinyl acetate, leading to high regioselectivities (iso:n ratio higher than 99:1) and enantioselectivities up to 65% ee. © 2013 American Chemical Society. | es |
dc.description.sponsorship | Ministerio de Ciencia e Innovación CTQ2009-11867, CONSOLIDER-INGENIO CSD 2007- 00006 | es |
dc.description.sponsorship | Junta de Andalucía 2008/ FQM-3830, 2009/FQM-4832 | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | American Chemical Society | es |
dc.relation.ispartof | Organometallics, 32, 2497-2500. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Novel bis (1,3,2-diazaphospholidine) ligands for asymmetric catalysis | es |
dc.type | info:eu-repo/semantics/article | es |
dc.type.version | info:eu-repo/semantics/submittedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.relation.projectID | CTQ2009-11867 | es |
dc.relation.projectID | CONSOLIDER-INGENIO CSD 2007- 00006 | es |
dc.relation.projectID | 2008/ FQM-3830 | es |
dc.relation.projectID | 2009/FQM-4832 | es |
dc.relation.publisherversion | http://dx.doi.org/10.1021/om400185q | es |
dc.identifier.doi | 10.1021/om400185q | es |
idus.format.extent | 15 | es |
dc.journaltitle | Organometallics | es |
dc.publication.volumen | 32 | es |
dc.publication.initialPage | 2497 | es |
dc.publication.endPage | 2500 | es |
dc.contributor.funder | Ministerio de Ciencia e Innovación (MICIN). España | |
dc.contributor.funder | Junta de Andalucía | |